Round robin on structure analysis from 3D electron diffraction data Mauro Gemmi, Lukáš Palatinus, Philippe Boullay, Jan Pieter Abrahams, Amatassalâm Ben Meriem, Erica Cordero-Oyonarte, Vincentia Emerson Agbemeh, Hrushikesh Chintakindi, Moussa Diame Faye Diouf, Pavel Filipcik, Laura Gemmrich Hernandéz, Eric van Genderen, Joke Hadermann, Amirhossein Hajizadeh, Branislav Jeriga, Ute Kolb, Senik Matinyan, Sara Passuti, Marco Santucci, Ashwin Suresh, Olivier Pérez, Cheuk-Wai Tai, Angelina Vypritskaia, Lei Wang, Hongyi Xu, Xiaodong Zou Iucrj, 2026 3D electron diffraction (3D ED) has undergone impressive development in the last decade. However, its accuracy and reproducibility have never been tested, up to now, in different laboratories on the same batch of samples. This paper reports a round robin on three test structures, two inorganic and one organic, solved and refined with 3D ED in seven different laboratories employing different transmission electron microscopes, with different acceleration voltages, different methodologies and different detectors. The results of the round robin show a remarkable accuracy of the technique that, in the case of kinematical refinement, is around 0.05 Å error on atomic positions for the inorganic samples and 0.15 Å for the beam-sensitive organic crystal. Dynamical refinement further improves the accuracy. The analysis of diverse samples and numerous data sets again confirms that dynamical refinement is a well established procedure, significantly reducing the refinement R factors, improving the accuracy of the structure models in most cases, and providing fine structural details, such as hydrogen-atom positions and the absolute structure, for both inorganic and organic samples.
Charge Ordering and Incommensurate Modulations in the Metamagnetic Layered Manganese Oxysulfide Sr2MnO2Cu3.5S3 Lemuel E. Crentsil, Oliver J. Rutt, David G. Free, Murray J. David, Robert D. Smyth, Catherine F. Smura, David A. Keen, Andrew N. Fitch, Joke Hadermann, Simon J. Clarke Journal of the American Chemical Society, 2026 High Resolution Image Download MS PowerPoint Slide Sr 2 MnO 2 Cu 3.5 S 3 contains mixed-valent Mn ions Mn 2+/3+ in axially elongated MnO 4 S 2 octahedra connected via apical sulfide anions to copper-deficient antifluorite-type Cu 4-δ S 3 layers where δ ∼ 0.5. Copper deficiency is charge-compensated by oxidation of Mn 3d states resulting in mixed-valency. The compound is tetragonal in P 4/ mmm at ambient temperatures ( a = 4.016345(1) Å, c = 11.40708(5) Å). Below 190 K, superlattice reflections in diffraction data and an increase in resistivity, signal checkerboard charge-ordering of Mn 2+ and Mn 3+ . The superstructure approximates to a √2 a × √2 a × 2 c expansion of the room temperature cell in space group P 4 2 / nmc . However, satellite reflections signal a (3 + 2)D incommensurate modulation of Cu site occupancies in the Cu-deficient sulfide layers coupled with displacements of the sulfur positions; overall the superstructure below 190 K requires description in superspace group P 4 2 / nmc ( a,0,0)0000(0, a,0)00s0. Analysis of total scattering measurements along with pair distribution functions supports the charge-ordered low temperature model and reveals local order of distinct Mn sites within the higher-temperature charge-disordered regime. Below T N = 27 K, long-range magnetic ordering is A-type antiferromagnetic with distinct moments for Mn 2+ and Mn 3+ ions directed perpendicular to the MnO 2 planes and ordered ferromagnetically. Long-range antiferromagnetic order results from interlayer antiferromagnetic coupling. A metamagnetic transition at 1.1 T corresponds to a change to long-range interlayer ferromagnetic ordering via a spin-reorientation of magnetic moments and is associated with a slight decrease in the charge separation between the Mn sublattices, consistent with observations on mixed-valent perovskite and Ruddlesden–Popper-type oxide manganites.
Electrocatalytic CO2 reduction to produce efficient and controlled syngas on highly dispersed NiFe on N-doped ordered porous carbonaceous support Ruben Palacio, Daniela Jaramillo, Elías Rodríguez-Jara, Ryosuke Nakazato, Matthias Quintelier, Keeko Matsumoto, Joke Hadermann, Kiyoharu Tadanaga, Nataly Carolina Rosero-Navarro Chemical Engineering Journal, 2026 The electrocatalytic reduction of CO 2 to CO to produce syngas (CO + H 2 ) is of outmost scientific and technological significance to reduce the CO 2 concentration in the atmosphere and produce high-added valued chemicals. The atomic-level dispersion of Ni, Fe, and Zn species on an N-doped, ordered porous carbon support revealed that conductivity, Faradaic efficiency toward CO, and the CO/H 2 molar ratio are strongly influenced by the electrocatalyst's metal composition, the surface atomic ratios among the metals, and the textural and structural characteristics of the carbon support. The simultaneous dispersion of Ni and Fe resulted in a more efficient electrocatalyst than the monometallic Ni or the combination of Ni and Zn, in a high concentrated 1.0 M KHCO 3 electrolyte, relevant for industrial applications. In bimetallic Ni Fe catalysts, the surface atomic ratio played a critical role in catalytic activity. Specifically, a higher Ni-to-Fe surface ratio of 0.69:0.24 in the Fe 3 Ni 7 NCMK-3 electrocatalyst resulted in Ni 2+ surface enrichment across diverse chemical environments, including Ni 2+ species with lower electronic density. At a potential of −1.2 V vs. RHE, this composition achieved a high FE CO of 85 % and a low FE H 2 of 9 %, with a CO production rate of 6.85 × 10 −1 μmol CO s −1 m −2 per surface Ni 2+ site. Remarkably, even at a lower potential of −0.8 V vs. RHE, it maintained a high FE CO of 70 %. Furthermore, the CO/H 2 molar ratio could be tuned from 2:1 at −0.6 V to 9:1 at −1.2 V vs. RHE. • Tailored NiFe catalyst on N-doped mesoporous carbon enables tunable CO/H₂ syngas ratios up to 9:1. • Advanced characterization (HRTEM, HAADF-STEM, XPS) reveals well-dispersed bimetallic sites and electronic modulation by Fe. • Catalyst achieves high Faradaic efficiency and CO₂RR selectivity using earth-abundant, scalable materials. • Comparative benchmarking demonstrates superior performance versus state-of-the-art syngas electrocatalysts.
Accelerating electrochemical CO2-to-CO conversion with Zn–Al layered double hydroxide amorphized by grinding treatment Ryosuke Nakazato, Keeko Matsumoto, Matthias Quintelier, Joke Hadermann, Margherita Cavallo, Valentina Crocellà, Francesca Bonino, Nataly Carolina Rosero-Navarro, Yuta Fujii, Akira Miura, Kiyoharu Tadanaga Journal of the Ceramic Society of Japan, 2026 Carbon dioxide (CO2) electrolysis is one of the promising technologies to convert CO2 into value-added chemical compounds and has attracted attention in recent years from the perspective of energy crisis and carbon neutrality. For efficient CO2 electrolysis, numerous attempts have been made to develop superior electrocatalysts that accelerate the CO2 reduction reaction (CO2RR), and their performance has been enhanced by controlling structure, morphology, and elemental composition. However, the effect of grinding treatment of catalysts on their structure, morphology, and CO2RR activity is frequently underestimated, which is performed for grain refining of catalyst particles to achieve optimum activity in general. In the present paper, we focused on Zn–Al layered double hydroxide (LDH) as an electrocatalyst which has CO2RR activity for carbon monoxide (CO) evolution. Zn–Al LDH and its ground samples for 10, 20, 30, and 60 min (Gx-LDHs, x = 0, 10, 20, 30, and 60, respectively) were prepared using a facile co-precipitation method and simple grinding with a mortar and pestle. Remarkably, Gx-LDHs exhibited superior activity for CO2-to-CO conversion as grinding proceeded. In particular, the growth rate in partial current density of CO was 3.2-fold and 1.6-fold from G0-LDH (as-prepared) to G10-LDH and from G10-LDH to G60-LDH, respectively. XRD and TEM analysis showed that the crystal structure of Zn–Al LDH collapsed due to amorphization as grinding proceeded. XAFS analysis indicated that Zn sites in the amorphous phase are mainly in the low-valent Zn state (Znδ+, 0 < δ < 2), which is a favorable state for CO2-to-CO conversion. Our results highlighted that grinding treatment clearly affected the structural and morphological properties of Zn–Al LDH, enhancing its CO2RR activity.
Fully Textured Monolithic Sb2S3/Silicon Tandem for Unbiased and Stable Solar-Driven Water Splitting Paired with Iodide Oxidation Reaction Jihong Min, Irene Dei Tos, Sepideh Rahimisheikh, Beatriz de la Fuente, Devika Rajagopal, Jan D'Haen, David Cornil, Tom Hauffman, Tom Aernouts, David Beljonne, Joke Hadermann, Byungha Shin, Bart Vermang, Sudhanshu Shukla Advanced Science, 2026 Solar‐driven photoelectrochemical (PEC) production of chemical fuels such as hydrogen is a viable solution to address climate neutrality objectives. Development of a monolithic tandem PEC device consisting of ideal bandgap absorbers is of paramount importance to realize efficient artificial photosynthesis systems. Herein, we report monolithic integration of Sb 2 S 3 on textured silicon to realize a completely inorganic and fully vacuum processed multilayer PEC device with Ag/Indium Tin Oxide (ITO)/Heterojunction with Intrinsic Thin layer (HIT) Si/ITO/Au/Sb 2 S 3 /NiO x architecture. Photoelectron spectroscopy and computational analysis show a staggered band alignment between Si and Sb 2 S 3 , emulating Z‐scheme charge transfer mechanism. We demonstrate a high performing and stable Sb 2 S 3 ‐Si monolithic tandem for PEC hydrogen evolution reaction (HER) coupled to iodide oxidation reaction (IOR). Under AM 1.5G illumination, the Sb 2 S 3 ‐Si monolithic tandem device achieves unassisted photocurrent density of 4.38 mA cm − 2 with faradaic efficiency of 97% for hydrogen, while maintaining ∼90% of its initial performance after 10 h of continuous operation. These results set a new benchmark for all inorganic monolithic tandems for efficient and sustainable solar‐to‐chemical conversion. This work unlocks the pathway for artificial photosynthesis systems comprising ideal bandgap photo absorbers.
Dimensionally Tunable Rod-Shaped Zirconia Particles via Bottom-Up Assembly Zhenhong Xue, Chenmin Yao, Junhui Zhang, Matthias Quintelier, Joke Hadermann, Jozef Vleugels, Bart Van Meerbeek, Fei Zhang Inorganic Chemistry, 2025 O in water/ethanol cosolvent systems exhibits tunable lengths ranging from 82 ± 0.6 to 929 ± 13.8 nm and aspect ratios from 1.3 to 3.8. Additionally, the developed method enables scalable synthesis with a high production yield of 98.8%, producing well-crystallized rod-like monoclinic zirconia particles with an aspect ratio of approximately 2.5.
MDT: A simple tool to facilitate dropcasting on in situ TEM MEMS chips Matthias Quintelier, Joke Hadermann Hardwarex, 2025 ) windows and the risk of leaks and contamination during dropcasting. This results in failed experiments and increases experimental costs. This paper introduces the MEMS Dropcasting Tool (MDT), a cost-effective, in-house 3D-printable solution that confines the droplet to a specific area, preventing particle migration under the O-ring and reducing contamination risks at the inlet and outlet ports of closed cell chip holders.
Optoelectronic Properties of Atomic Layer Deposited and Sputtered MoS2Films Crystal Alicia Nattoo, Tara Peña, Koosha Nassiri Nazif, Xiangjin Wu, Sepideh Rahimisheikh, Giulio D’Acunto, Stacey F. Bent, Joke Hadermann, Eric Pop ACS Applied Materials and Interfaces, 2025 Large-area growth techniques are needed to bring transition metal dichalcogenide (TMD) films into future applications, but some of these methods have not been sufficiently studied. Here, we evaluate and compare few-layer MoS 2 films (<3 nm thick) grown by atomic layer deposition (ALD) and radio frequency (RF) sputtering, using optical, topographical, X-ray spectroscopy, transmission electron microscopy, and electrical device characterization. The electron mobility of ALD films improves 3-fold with rapid thermal annealing, and these improvements are correlated with changes in their Raman spectra, such as a decrease in both the shoulder-to-E 2g and LA(M)-to-A 1g intensity ratios. On the other hand, the sputtered films had lower mobility and lower transistor current on/off ratio than the ALD samples, and the thermal annealing worsened both their surface roughness and electrical behavior. This work illustrates the utility of nondestructive materials characterization (e.g., Raman, with complementary techniques) to obtain a better picture of material quality before performing time-consuming device fabrication and electrical testing on emerging TMD films.
Polytypism in mcalpineite: A study of natural and synthetic Cu3TeO6 Owen P. Missen, Stuart J. Mills, Stefano Canossa, Joke Hadermann, Gwilherm Nénert, Matthias Weil, Eugen Libowitzky, Robert M. Housley, Werner Artner, Anthony R. Kampf, Michael S. Rumsey, John Spratt, Koichi Momma, Maja A. Dunstan Acta Crystallographica Section B Structural Science Crystal Engineering and Materials, 2022
AIR CARBON RECYCLING FOR AVIATION FUEL TECHNOLOGY Proceedings of Whec 2022 23rd World Hydrogen Energy Conference Bridging Continents by H2, 2022
Topochemical Deintercalation of Li from Layered LiNiB: toward 2D MBene Gourab Bhaskar, Volodymyr Gvozdetskyi, Maria Batuk, Kamila M. Wiaderek, Yang Sun, Renhai Wang, Chao Zhang, Scott L. Carnahan, Xun Wu, Raquel A. Ribeiro, Sergey L. Bud’ko, Paul C. Canfield, Wenyu Huang, Aaron J. Rossini, Cai-Zhuang Wang, Kai-Ming Ho, Joke Hadermann, Julia V. Zaikina Journal of the American Chemical Society, 2021
Atomic and Electronic Structure of a Multidomain GeTe Crystal Alexander S. Frolov, Jaime Sánchez-Barriga, Carolien Callaert, Joke Hadermann, Alexander V. Fedorov, Dmitry Yu. Usachov, Alexander N. Chaika, Brian C. Walls, Kuanysh Zhussupbekov, Igor V. Shvets, Matthias Muntwiler, Matteo Amati, Luca Gregoratti, Andrei Yu. Varykhalov, Oliver Rader, Lada V. Yashina ACS Nano, 2020
Sub-ppm H2S sensing by tubular ZnO-Co3O4 nanofibers M.N. Rumyantseva, S.A. Vladimirova, V.B. Platonov, A.S. Chizhov, M. Batuk, J. Hadermann, N.O. Khmelevsky, A.M. Gaskov Sensors and Actuators B Chemical, 2020
Computationally Driven Discovery of a Family of Layered LiNiB Polymorphs Volodymyr Gvozdetskyi, Gourab Bhaskar, Maria Batuk, Xin Zhao, Renhai Wang, Scott L. Carnahan, Michael P. Hanrahan, Raquel A. Ribeiro, Paul C. Canfield, Aaron J. Rossini, Cai‐Zhuang Wang, Kai‐Ming Ho, Joke Hadermann, Julia V. Zaikina Angewandte Chemie International Edition, 2019
MnFe 0.5 Ru 0.5 O 3 : An above-room-temperature antiferromagnetic semiconductor Xiaoyan Tan, Emma E. McCabe, Fabio Orlandi, Pascal Manuel, Maria Batuk, Joke Hadermann, Zheng Deng, Changqing Jin, Israel Nowik, Rolfe Herber, Carlo U. Segre, Sizhan Liu, Mark Croft, Chang-Jong Kang, Saul Lapidus, Corey E. Frank, Haricharan Padmanabhan, Venkatraman Gopalan, Meixia Wu, Man-Rong Li, Gabriel Kotliar, David Walker, Martha Greenblatt Journal of Materials Chemistry C, 2019
Wide band gap kesterite absorbers for thin film solar cells: Potential and challenges for their deployment in tandem devices Bart Vermang, Guy Brammertz, Marc Meuris, Thomas Schnabel, Erik Ahlswede, Leo Choubrac, Sylvie Harel, Christophe Cardinaud, Ludovic Arzel, Nicolas Barreau, Joop van Deelen, Pieter-Jan Bolt, Patrice Bras, Yi Ren, Eric Jaremalm, Samira Khelifi, Sheng Yang, Johan Lauwaert, Maria Batuk, Joke Hadermann, Xeniya Kozina, Evelyn Handick, Claudia Hartmann, Dominic Gerlach, Asahiko Matsuda, Shigenori Ueda, Toyohiro Chikyow, Roberto Félix, Yufeng Zhang, Regan G. Wilks, Marcus Bär Sustainable Energy and Fuels, 2019
Surface Passivation of CIGS Solar Cells Using Gallium Oxide Siddhartha Garud, Nikhil Gampa, Thomas G. Allen, Ratan Kotipalli, Denis Flandre, Maria Batuk, Joke Hadermann, Marc Meuris, Jef Poortmans, Arno Smets, Bart Vermang Physica Status Solidi A Applications and Materials Science, 2018
New Solid Electrolyte Na9Al(MoO4)6: Structure and Na+ Ion Conductivity Aleksandra A. Savina, Vladimir A. Morozov, Anton L. Buzlukov, Irina Yu. Arapova, Sergey Yu. Stefanovich, Yana V. Baklanova, Tatiana A. Denisova, Nadezhda I. Medvedeva, Michel Bardet, Joke Hadermann, Bogdan I. Lazoryak, Elena G. Khaikina Chemistry of Materials, 2017
Synthesis of MAX Phases in the Zr-Ti-Al-C System Bensu Tunca, Thomas Lapauw, Olesia M. Karakulina, Maria Batuk, Thierry Cabioc’h, Joke Hadermann, Rémi Delville, Konstantina Lambrinou, Jozef Vleugels Inorganic Chemistry, 2017
Process variability in Cu2ZnSnSe4 solar cell devices: Electrical and structural investigations Guy Brammertz, Marie Buffiere, Christophe Verbist, Souhaib Oueslati, Jonas Bekaert, Hossam ElAnzeery, Khaled Ben Messaoud, Sylvester Sahayaraj, Maria Batuk, Joke Hadermann, Christine Koble, Marc Meuris, Jozef Poortmans 2015 IEEE 42nd Photovoltaic Specialist Conference Pvsc 2015, 2015
KEu(MoO4)2: Polymorphism, Structures, and Luminescent Properties Vladimir A. Morozov, Alla V. Arakcheeva, Philip Pattison, Katrien W. Meert, Philippe F. Smet, Dirk Poelman, Nicolas Gauquelin, Johan Verbeeck, Artem M. Abakumov, Joke Hadermann Chemistry of Materials, 2015
KCN Chemical Etch for Interface Engineering in Cu2ZnSnSe4 Solar Cells Marie Buffière, Guy Brammertz, Sylvester Sahayaraj, Maria Batuk, Samira Khelifi, Denis Mangin, Abdel-Aziz El Mel, Ludovic Arzel, Joke Hadermann, Marc Meuris, Jef Poortmans ACS Applied Materials and Interfaces, 2015
Mn2FeWO6: A New Ni3TeO6-Type Polar and Magnetic Oxide Man‐Rong Li, Mark Croft, Peter W. Stephens, Meng Ye, David Vanderbilt, Maria Retuerto, Zheng Deng, Christoph P. Grams, Joachim Hemberger, Joke Hadermann, Wen‐Min Li, Chang‐Qing Jin, Felix O. Saouma, Joon I. Jang, Hirofumi Akamatsu, Venkatraman Gopalan, David Walker, Martha Greenblatt Advanced Materials, 2015
Hole doping and structural transformation in CsTl1- xHgxCl3 Maria Retuerto, Zhiping Yin, Thomas J. Emge, Peter W. Stephens, Man-Rong Li, Tapati Sarkar, Mark C. Croft, Alexander Ignatov, Z. Yuan, S. J. Zhang, Changqing Jin, Robert Paria Sena, Joke Hadermann, Gabriel Kotliar, Martha Greenblatt Inorganic Chemistry, 2015
Polar and magnetic Mn2FeMO6 (M=Nb, Ta) with LiNbO3-type structure: High-pressure synthesis Man‐Rong Li, David Walker, Maria Retuerto, Tapati Sarkar, Joke Hadermann, Peter W. Stephens, Mark Croft, Alexander Ignatov, Christoph P. Grams, Joachim Hemberger, Israel Nowik, P. Shiv Halasyamani, T. Thao Tran, Swarnakamal Mukherjee, Tanusri Saha Dasgupta, Martha Greenblatt Angewandte Chemie International Edition, 2013
BiMnFe2O6, a polysynthetically twinned hcp MO structure Tao Yang, Artem M. Abakumov, Joke Hadermann, Gustaaf Van Tendeloo, Israel Nowik, Peter W. Stephens, Joachim Hemberger, Alexander A. Tsirlin, Kandalam V. Ramanujachary, Samuel Lofland, Mark Croft, Alexander Ignatov, Junliang Sun, Martha Greenblatt Chemical Science, 2010
New perovskite-based manganite Pb2Mn2O5 Joke Hadermann, Artem M. Abakumov, Tyché Perkisas, Hans D’Hondt, Haiyan Tan, Johan Verbeeck, Vladimir P. Filonenko, Evgeny V. Antipov, Gustaaf Van Tendeloo Journal of Solid State Chemistry, 2010
Crystal structure and phase transitions in Sr3WO6 Graham King, Artem M. Abakumov, J. Hadermann, Anastasiya M. Alekseeva, Marina G. Rozova, Tyche Perkisas, Patrick M. Woodward, Gustaaf Van Tendeloo, Evgeny V. Antipov Inorganic Chemistry, 2010
New germanates RCrGeO5 (R=Nd-Er, Y): Synthesis, structure, and properties Roman V. Shpanchenko, Alexander A. Tsirlin, Ekaterina S. Kondakova, Evgeny V. Antipov, Catherine Bougerol, Joke Hadermann, Gustaaf van Tendeloo, Hiroya Sakurai, Eiji Takayama-Muromachi Journal of Solid State Chemistry, 2008
Spin ladder compound Pb0.55 Cd0.45 V2 O5: Synthesis and investigation Alexander A. Tsirlin, Roman V. Shpanchenko, Evgeny V. Antipov, Catherine Bougerol, Joke Hadermann, Gustaaf Van Tendeloo, Walter Schnelle, Helge Rosner Physical Review B Condensed Matter and Materials Physics, 2007
Synthesis and crystal structure of the Sr2Al1.07Mn0.93O5 brownmillerite Joke Hadermann, Artem M. Abakumov, Hans D'Hondt, Anna S. Kalyuzhnaya, Marina G. Rozova, Maria M. Markina, Mikhail G. Mikheev, Natalia Tristan, Rüdiger Klingeler, Bernd Büchner, Evgeny V. Antipov Journal of Materials Chemistry, 2007
Mg1-xRhB - A new boridometallide with 2D polyanion A. M. Alekseeva, A. M. Abakumov, A. Leithe‐Jasper, W. Schnelle, Yu. Prots, J. Hadermann, G. Van Tendeloo, E. V. Antipov, Yuri Grin Zeitschrift Fur Anorganische Und Allgemeine Chemie, 2005
Fluorinated rba2cu3o6+δ (r = dy, ho, and tm) phases: synthesis and structure Zhurnal Neorganicheskoj Khimii, 2001
Crystal structure and magnetic properties of the novel oxide Pb2V5O12 R. V. Shpanchenko, V. V. Chernaya, A. M. Abakumov, E. V. Antipov, J. Hadermann, G. Van Tendeloo, E. E. Kaul, C. Geibel, D. Sheptyakov, A. M. Balagurov Zeitschrift Fur Anorganische Und Allgemeine Chemie, 2001
Structural Transformations in the Fluorinated T* Phase J. Hadermann, A.M. Abakumov, O.I. Lebedev, G. Van Tendeloo, M.G. Rozova, R.V. Shpanchenko, B.Ph. Pavljuk, E.M. Kopnin, E.V. Antipov Journal of Solid State Chemistry, 1999
Anion Ordering in Fluorinated La2CuO4 A.M. Abakumov, J. Hadermann, G. Van Tendeloo, R.V. Shpanchenko, P.N. Oleinikov, E.V. Antipov Journal of Solid State Chemistry, 1999
RECENT SCHOLAR PUBLICATIONS
Accelerating electrochemical CO2-to-CO conversion with Zn–Al layered double hydroxide amorphized by grinding treatment R Nakazato, K Matsumoto, M Quintelier, J Hadermann, M Cavallo, ... Journal of the Ceramic Society of Japan 134 (4), 316-324 , 2026 2026
Round robin on structure analysis from 3D electron diffraction data M Gemmi, L Palatinus, P Boullay, JP Abrahams, A Ben Meriem, ... IUCrJ 13 (2) , 2026 2026 Citations: 3
A 4D-STEM Tomographic Framework Assisted by Object Tracking for Nanoparticle Structure Solution S Gholam, A Annys, I Skvortsova, EC Oyonarte, A Hajizadeh, P Boullay, ... arXiv preprint arXiv:2602.09768 , 2026 2026
Charge Ordering and Incommensurate Modulations in the Metamagnetic Layered Manganese Oxysulfide Sr 2 MnO 2 Cu 3.5 S 3 LE Crentsil, OJ Rutt, DG Free, MJ David, RD Smyth, CF Smura, DA Keen, ... Journal of the American Chemical Society , 2026 2026
Structure and magnetism of mixed-valent iron oxysulfides Sr 3 Fe 4 O 6 S 2 (Sr 3 (Fe 3+) 2 O 5 (Fe 2+) 2 OS 2) and Sr 4 Fe 4 O 7 S 2 (Sr 4 (Fe 3+) 2 O 6 (Fe 2+) 2 OS 2) AN Gillette, AR Lyon, S Savvin, I Puente-Orench, S Rahimisheikh, ... Chemical Communications 62 (18), 5237-5240 , 2026 2026
Electrocatalytic CO2 reduction to produce efficient and controlled syngas on highly dispersed NiFe on N-doped ordered porous carbonaceous support R Palacio, D Jaramillo, E Rodríguez-Jara, R Nakazato, M Quintelier, ... Chemical Engineering Journal, 172327 , 2025 2025
Charge Transport and Microstructural Evolution in Solvent-Vs. Water-Based Li-S Battery Electrodes S Yari, L Bird, S Rahimisheikh, AC Reis, M Mohammad, J Hadermann, ... 248th ECS Meeting (October 12-16, 2025) , 2025 2025
Dimensionally Tunable Rod-Shaped Zirconia Particles via Bottom-Up Assembly Z Xue, C Yao, J Zhang, M Quintelier, J Hadermann, J Vleugels, ... Inorganic Chemistry 64 (40), 19998-20012 , 2025 2025
MDT: A simple tool to facilitate dropcasting on in situ TEM MEMS chips M Quintelier, J Hadermann HardwareX 23, e00666 , 2025 2025
Optoelectronic Properties of Atomic Layer Deposited and Sputtered MoS 2 Films CA Nattoo, T Peña, K Nassiri Nazif, X Wu, S Rahimisheikh, G D’Acunto, ... ACS Applied Materials & Interfaces 17 (33), 47347-47354 , 2025 2025 Citations: 2
Removing constraints of 4D-STEM with a framework for event-driven acquisition and processing A Annys, HLL Robert, S Gholam, J Hadermann, J Verbeeck Ultramicroscopy, 114206 , 2025 2025 Citations: 6
Charge–Discharge Mechanisms in O3–Na x Fe 0.5 Mn 0.5 O 2 Na-Ion Battery Electrodes─Unraveling the Structure of the X-Phase AØ Drejer, M Schou Hansen, M Johansen, J Dunker, R Poppe, ... Chemistry of Materials 37 (14), 5234-5248 , 2025 2025 Citations: 3
A New Framework for Acquisition and Processing of Event-driven 4D STEM A Annys, HLL Robert, S Gholam, J Hadermann, J Verbeeck Microscopy and Microanalysis 31 (Supplement_1), ozaf048. 080 , 2025 2025
Influence of Atmospheric Conditions on the Structural Evolution upon Heating of the ZnAl-Layered Double Hydroxide: A Comprehensive In Situ Transmission … M Quintelier, A Zintler, R Nakazato, NC Rosero-Navarro, K Tadanaga, ... ACS Applied Materials & Interfaces 17 (26), 38587-38596 , 2025 2025 Citations: 2
CO2 electrochemical reduction by Zn-based layered double hydroxides: The role of structural trivalent metal ions R Nakazato, K Matsumoto, M Quintelier, J Hadermann, ... Open Ceramics 22, 100788 , 2025 2025 Citations: 2
3D Electron diffraction on nanoparticles: minimal size and associated dynamical effects E Cordero Oyonarte, L Rebecchi, S Gholam, MD Faye Diouf, E Bigard, ... ACS nano 19 (22), 20599-20612 , 2025 2025 Citations: 10
Li 21 Ge 8 P 3 S 34 : New Lithium Superionic Conductor with Unprecedented Structural Type J Roh, S Gholam, N Do, A Manjón‐Sanz, J Hadermann, ST Hong Angewandte Chemie 137 (22), e202500732 , 2025 2025 Citations: 3
A low-temperature, one-step synthesis for monazite can transform monazite into a readily usable advanced nuclear waste form Y Zhoujin, HB Tisdale, N Keerthisinghe, G Morrison, MD Smith, ... Science Advances 11 (12), eadt3518 , 2025 2025 Citations: 13
Zinc oxides by thermal decomposition synthesis and parameters affecting electrocatalyst activity for CO2 reduction reaction E Rodríguez-Jara, M Cavallo, R Nakazato, M Quintelier, K Matsumoto, ... Open Ceramics 21, 100733 , 2025 2025 Citations: 1
Lithium-rich, oxygen-deficient spinel obtained through low-temperature decomposition of heterometallic molecular precursor Y Zhang, Z Wei, M Batuk, J Hadermann, AS Filatov, J Chang, H Han, ... Energy Materials 5 (7) , 2025 2025 Citations: 1
MOST CITED SCHOLAR PUBLICATIONS
Strength, toughness and aging stability of highly-translucent Y-TZP ceramics for dental restorations F Zhang, M Inokoshi, M Batuk, J Hadermann, I Naert, B Van Meerbeek, ... Dental Materials 32 (12), e327-e337 , 2016 2016 Citations: 557
A chemical approach to raise cell voltage and suppress phase transition in O3 sodium layered oxide electrodes M Sathiya, Q Jacquet, ML Doublet, OM Karakulina, J Hadermann, ... Advanced Energy Materials 8 (11), 1702599 , 2018 2018 Citations: 234
Highly-translucent, strong and aging-resistant 3Y-TZP ceramics for dental restoration by grain boundary segregation F Zhang, K Vanmeensel, M Batuk, J Hadermann, M Inokoshi, ... Acta biomaterialia 16, 215-222 , 2015 2015 Citations: 214
Structural requirements in lithium cobalt oxides for the catalytic oxidation of water GP Gardner, YB Go, DM Robinson, PF Smith, J Hadermann, A Abakumov, ... Angewandte Chemie International Edition 51 (7), 1616-1619 , 2012 2012 Citations: 188
La 1.5 Sr 0.5 NiMn 0.5 Ru 0.5 O 6 Double Perovskite with Enhanced ORR/OER Bifunctional Catalytic Activity M Retuerto, F Calle-Vallejo, L Pascual, G Lumbeeck, MT Fernandez-Diaz, ... ACS Applied Materials & Interfaces 11 (24), 21454-21464 , 2019 2019 Citations: 187
AVPO 4 F (A = Li, K): A 4 V Cathode Material for High-Power Rechargeable Batteries SS Fedotov, NR Khasanova, AS Samarin, OA Drozhzhin, D Batuk, ... Chemistry of Materials 28 (2), 411-415 , 2016 2016 Citations: 173
3Y-TZP ceramics with improved hydrothermal degradation resistance and fracture toughness F Zhang, K Vanmeensel, M Inokoshi, M Batuk, J Hadermann, ... Journal of the European Ceramic Society 34 (10), 2453-2463 , 2014 2014 Citations: 150
Critical influence of alumina content on the low temperature degradation of 2–3 mol% yttria-stabilized TZP for dental restorations F Zhang, K Vanmeensel, M Inokoshi, M Batuk, J Hadermann, ... Journal of the European Ceramic Society 35 (2), 741-750 , 2015 2015 Citations: 147
Giant Magnetoresistance in the Half‐Metallic Double‐Perovskite Ferrimagnet Mn 2 FeReO 6 MR Li, M Retuerto, Z Deng, PW Stephens, M Croft, Q Huang, H Wu, ... Angewandte Chemie International Edition 54 (41), 12069-12073 , 2015 2015 Citations: 145
Tetrahedral Chain Order in the Sr 2 Fe 2 O 5 Brownmillerite H D’Hondt, AM Abakumov, J Hadermann, AS Kalyuzhnaya, MG Rozova, ... Chemistry of Materials 20 (22), 7188-7194 , 2008 2008 Citations: 141
Synthesis and Structural Characterization of La 1− x A x MnO 2.5 (A = Ba, Sr, Ca) Phases: Mapping the Variants of the Brownmillerite Structure TG Parsons, H D’Hondt, J Hadermann, MA Hayward Chemistry of Materials 21 (22), 5527-5538 , 2009 2009 Citations: 140
Effect of cation dopant radius on the hydrothermal stability of tetragonal zirconia: Grain boundary segregation and oxygen vacancy annihilation F Zhang, M Batuk, J Hadermann, G Manfredi, A Mariën, K Vanmeensel, ... Acta Materialia 106, 48-58 , 2016 2016 Citations: 124
Revealing pH-dependent activities and surface instabilities for Ni-based electrocatalysts during the oxygen evolution reaction C Yang, M Batuk, Q Jacquet, G Rousse, W Yin, L Zhang, J Hadermann, ... ACS Energy Letters 3 (12), 2884-2890 , 2018 2018 Citations: 118
Energy transfer in Eu^ 3+ doped scheelites: use as thermographic phosphor KW Meert, VA Morozov, AM Abakumov, J Hadermann, D Poelman, ... Optics express 22 (S3), A961-A972 , 2014 2014 Citations: 110
Bulk Magnetic Order in a Two-Dimensional ( ) Nickelate, Isoelectronic <?format ?>with Superconducting Cuprates VV Poltavets, KA Lokshin, AH Nevidomskyy, M Croft, TA Tyson, ... Physical review letters 104 (20), 206403 , 2010 2010 Citations: 109
Incommensurate Modulation and Luminescence in the CaGd 2(1– x ) Eu 2 x (MoO 4 ) 4(1– y ) (WO 4 ) 4 y (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) Red Phosphors VA Morozov, A Bertha, KW Meert, S Van Rompaey, D Batuk, GT Martinez, ... Chemistry of Materials 25 (21), 4387-4395 , 2013 2013 Citations: 104
Insight into the mechanisms of high activity and stability of iridium supported on antimony-doped tin oxide aerogel for anodes of proton exchange membrane water electrolyzers VA Saveleva, L Wang, O Kasian, M Batuk, J Hadermann, JJ Gallet, ... ACS Catalysis 10 (4), 2508-2516 , 2020 2020 Citations: 102
In situ electron diffraction tomography using a liquid-electrochemical transmission electron microscopy cell for crystal structure determination of cathode materials for Li-ion … OM Karakulina, A Demortière, W Dachraoui, AM Abakumov, ... Nano letters 18 (10), 6286-6291 , 2018 2018 Citations: 101
Synthesis of MAX phases in the Zr-Ti-Al-C system B Tunca, T Lapauw, OM Karakulina, M Batuk, T Cabioc’h, J Hadermann, ... Inorganic Chemistry 56 (6), 3489-3498 , 2017 2017 Citations: 98
Structure and Magnetic Properties of BiFe 0.75 Mn 0.25 O 3 Perovskite Prepared at Ambient and High Pressure AA Belik, AM Abakumov, AA Tsirlin, J Hadermann, J Kim, G Van Tendeloo, ... Chemistry of Materials 23 (20), 4505-4514 , 2011 2011 Citations: 98
