Dr. Rajesh Kumar has been awarded prestigious international awards/ fellowships, as Friedrich Wilhelm Bessel Research Award-2024, GERMANY; JSPS Invitational Fellow (Long-term) (2025) JAPAN; JSPS postdoctoral Fellow (Standard) (2018), JAPAN; FAPESP (Sao Paulo Research Foundation) (2017), BRAZIL and Brain Korea-21 (BK-21+) (2014), SOUTH KOREA. He has worked in Toyohashi University of Technology (TUT), Toyohashi, JAPAN as JSPS Fellow (2018-2020). He has also worked in BRAZIL (University of Campinas (UNICAMP) (2015–2017; CNPq postdoctoral fellow/ visiting scientist), Campinas & State University of Sao Paulo (UNESP) (2018; FAPESP postdoctoral fellow), Presidente Prudente) and SOUTH KOREA (Korea Advanced Institute of Science and Technology (KAIST) (2012–2014; postdoctoral researcher), Daejeon &, Yonsei University (2014; Brain Korea: BK 21+ Research Professor), Seoul at different scientific positions.
Dual-doped graphene-based electrode materials for energy devices Rajesh Kumar, Sumanta Sahoo, Ednan Joanni, J.M.C. da Silva Filho, Raluca Savu, Wai Kian Tan, Go Kawamura, Anke Weidenkaff, Ralf Riedel, Atsunori Matsuda Carbon, 2026 Heteroatom co-doping of graphene-based materials has become an effective and powerful approach to develop advanced two-dimensional (2D) layered electrodes by engineering the electronic structure, defect chemistry, and surface functionality for electrochemical energy storage and conversion. Compared with single-atom doping, co-doping enables synergistic modulation of charge redistribution, adsorption energetics, and ion transport behavior through complementary electronic and structural effects. Co-doping enables enhanced ion adsorption, charge transfer, and catalytic activity by introducing specific electronic and structural modifications that increase electrical conductivity, generate numerous active sites, and improve surface wettability. This review article systematically outlines the advantages of co-doped 2D graphene-based materials, and summarizes the synthesis techniques for nitrogen-sulfur (N,S), boron-nitrogen (B,N), nitrogen-phosphorus (N,P), and nitrogen-fluorine (N,F) co-doped 2D graphene-based materials, covering high-temperature annealing, thermal heating, hydrothermal, solvothermal, and liquid-phase methods for dual-heteroatom insertion in the carbon skeleton of these materials. The effectiveness of co-doped 2D graphene-based composite electrodes has been demonstrated in supercapacitors (SCs), batteries, fuel cells, solar cells, and water-splitting applications, highlighting the significance of synergistic heteroatom interactions for improving electrochemical performance. In addition to comparisons between single-doped and co-doped 2D graphene-based materials, analytical insights into electron/ion transport, adsorption energy optimization, and structural stability are discussed. The article provides an outlook for further research, highlighting potential uses and new developments in co-doped graphene-based 2D materials for energy applications. Important issues like scalable synthesis, reproducibility, and long-term cycling stability are also addressed, with suggestions for the systematic design of next-generation graphene-based materials and devices. • Synergistic dual-doping effectively modulates graphene electronic structure • Dual-doping enhances defect chemistry and surface reactivity of graphene • Design principles govern synergistic effects in dual-doped graphene materials • Mechanistic insights explain performance gains in energy storage and conversion • Dual-doped graphene is promising for batteries, supercapacitors and energy devices
MXene-Reinforced 3D-Printed Biomatrices: Synthesis, Characterization, and Intelligent Theragenerative Applications Vinod Kumar, Rajesh Kumar, Dipali Patel, Sanjay Kumar Rawat, Sai Prashitha B, Divya Bhatnagar, Sudheesh K. Shukla, G. Taru Sharma ACS Applied Materials and Interfaces, 2026 Increasing prevalence of organ and tissue damage underscores the need for a simultaneous therapeutic and regenerative strategy, referred to as 'therageneration.' In recent years, three-dimensional (3D) bioprinting has emerged as a promising tool in theragenerative medicine. Despite significant progress, the lack of efficient theragenerative biomatrices has remained a key challenge with the strategy. The convergence of nanotechnology and 3D bioprinting has demonstrated enormous potential for creating responsive and efficient theragenerative biomatrices. Nanomaterial additives exhibit dimension-dependent characteristics that not only enhance the physical, chemical, and biological properties of conventional bioinks but also bestow them with trigger-reactive functionalities. Recent innovations in two-dimensional (2D) MXene nanomaterials have led to the development of highly responsive and multipurpose biocomposite inks for the printing of theragenerative biomatrices or scaffolds. These MXene biomatrices are being utilized to address a spectrum of unmet therapeutic and regenerative challenges in complex diseases such as skin and bone diseases, cardiac problems, and so on. The present review articulates the recent innovations in 3D-printed novel MXene biomatrices or scaffolds for various intelligent theragenerative applications. Additionally, the review presents an in-depth analysis of the necessity of MXenes in 3D printing, detailing MXene bioink formulation strategies and the benefits they offer compared to other 2D materials. The review also covers the biosafety issues, the other challenges encountered, and the prospects for MXene-derived theragenerative biomatrices, with a focus on advancing their clinical applications.
Recent advances in nanostructured carbon-based SERS: From zero-to two-dimensional materials for detection of toxic environmental pollutants and health concerns Saloni Sharma, Rajesh Kumar, Ram Manohar Yadav Carbon, 2026 The effective use of carbon nanomaterials as versatile substrates for surface-enhanced Raman spectroscopy (SERS) offers significant advance in the development of unique methods for analysis. Carbon nanomaterials, which include carbon quantum dots (CQDs), carbon nanotubes (CNTs), and graphene-based materials, have special qualities that make them good choices for chemically amplifying SERS signals. The use of carbon nanomaterials in the field of SERS is well-known for their extraordinary chemical stability, high surface area, and good electrical conductivity, all of which work together to provide superior performance in various applications. This review focuses on the details of synthesizing, functionalizing, and integrating carbon nanomaterials into SERS substrates. It described mechanisms by which carbon nanomaterials amplify Raman signals, opening up new possibilities for sensitive and precise detection techniques. It highlights carbon-based materials use in critical domains such as disease, food safety, environmental monitoring, and biosensing, in addition to examining their fundamental features. Moreover, it offers details on the transformative potential of carbon nanomaterials and related hybrid compounds in the field of SERS-based analytical substrates by an in-depth investigation of recent developments and existing challenges. The article highlights recent achievements in carbon nanomaterial-based SERS substrates, emphasizing on integrating carbon materials with substrates to improve Raman signals.
Recent advances in graphene-semiconductor based composites for water splitting and environmental remediation L Duong, R Kumar, WK Tan, Z Lockman, A Matsuda, G Kawamura Coordination Chemistry Reviews 565, 218124 , 2026 2026
Dual doped graphene-based electrode materials for energy devices R Kumar, S Sahoo, E Joanni, JM C. Filho, R Savu, WK Tan, G Kawamura, ... Carbon 256, 121669 , 2026 2026
Recent advances in TiO2 nanotube arrays-based composite for photoelectrochemical water splitting and environmental remediation L Duong, R Kumar, WK Tan, A Matsuda, G Kawamura Journal of Photochemistry & Photobiology, C: Photochemistry Reviews 67, 100757 , 2026 2026
BiVO4-graphene nanocomposites: Recent progress toward photocatalytic environmental remediation of pollutants J Rafi, R Kumar, WK Tan, A Matsuda, G Kawamura Journal of Environmental Chemical Engineering 14, 122107 , 2026 2026 Citations: 3
MXene Reinforced 3D Printed Biomatrices: Synthesis, Characterization and Intelligent Theragenerative Applications V Kumar, R Kumar, D Patel, SK Rawat, S Prashitha B, D Bhatnagar ACS Applied Materials & Interfaces 18, 22587−22620 , 2026 2026
Recent advances in carbon-based materials for supercapacitors: synthesis, electrochemical properties, and impact of machine learning A Sahoo, S Sahoo, R Kumar Journal of Materials Chemistry A 14, 10569-10598 , 2026 2026
Emerging trends in rare-earth doped luminescent nanophosphors: Synthesis, advances and applications H Thakur, NK Mishra, RK Singh, BP Singh, R Kumar, AK Gathania Materials Research Bulletin 197, 113997 , 2026 2026 Citations: 1
Recent advances in nanostructured carbon-based SERS: From zero- to two-dimensional materials for detection of toxic environmental pollutants and health concerns S Sharma, R Kumar, RM Yadav Carbon 248, 121156 , 2026 2026
Recent advancements in rare-earth elements-based oxides, sulfides, selenides, tellurides, and related composites for supercapacitor applications S Sahoo, SK Tiwari, A Bhat, RN Bulakhe, R Kumar, SS Han Journal of Energy Storage 134, 118125 , 2025 2025 Citations: 11
Low-value biomass-derived carbon composites for electromagnetic wave absorption and shielding: A review S Sahoo, R Kumar, SS Han New Carbon Materials 40 (2), 293-316 , 2025 2025
Advancements in fabrication, polymorph diversity, heterostructure excitation dynamics, and multifunctional applications of leading 2D TMDs A Dhingra, R Kumar, OP Thakur, R Pandey Journal of Industrial and Engineering Chemistry 146 , 2025 2025 Citations: 6
Recent development of MXenes and their composites in electrochemical energy storage: Current status, challenges and future prospects N Devi, R Kumar, RK Singh, SA Moshkalev Journal of Power Sources 636, 236538 , 2025 2025 Citations: 16
Advancements in hexaferrite composite materials for electromagnetic interference shielding solutions A Dhingra, R Kumar, OP Thakur, R Pandey Sustainable Materials and Technologies 43, e01333 , 2025 2025 Citations: 18
Exploring a solid polymorphism and phase transitions in 4-cyano-4'-pentylbiphenyl (5CB) and rGO-doped 5CB using temperature dependent Raman spectroscopy K Ummar, CB Patel, P Tripathi, R Kumar, S Mishra, RK Singh, K Vikram Journal of Molecular Liquids 423, 127006 , 2025 2025 Citations: 4
Rapid in-situ fabrication of MnSnO3 perovskite-based nanocomposites via microwave-assisted approach for supercapacitor devices S Sahoo, A Sood, R Kumar, A Milton, HM Kim, I Hussain, SS Han Journal of Energy Storage 110, 115368 , 2025 2025 Citations: 26
Microwave irradiation-induced palladium nanoparticle-mediated perforation and decoration of reduced graphene oxide nanosheets composite for electrode in supercapacitors R Kumar, S Sahoo, M Elfiky, R Pandey, RM Yadav, WK Tan, G Kawamura, ... Diamond & Related Materials 152, 111924 , 2025 2025 Citations: 9
Electromagnetic irradiation-assisted synthesis, exfoliation and modification of graphene-based materials for energy storage and sensing applications R Kumar, S Sahoo, R Pandey, E Joanni, RM Yadav Materials Science & Engineering R 161, 100860 , 2024 2024 Citations: 35
Heteroatom doping in 2D MXenes for energy storage and conversion applications S Sahoo, R Kumar, I Hussain, K Zhang Advanced Powder Materials 3 (6), 100246 , 2024 2024 Citations: 61
Laser-induced and catalyst-free formation of graphene materials for energy storage and sensing applications R Kumar, R Pandey, E Joanni, R Savu Chemical Engineering Journal 497, 154968 , 2024 2024 Citations: 51
Non-Ti MXene: An emerging class of 2D materials for non-Li batteries S Sahoo, R Kumar, I Hussain, T Kaewmaraya, T Hussian, SS Han Carbon 229, 119537 , 2024 2024 Citations: 25
MOST CITED SCHOLAR PUBLICATIONS
Graphene oxide: Strategies for synthesis, reduction and frontier applications RK Singh, R Kumar, DP Singh RSC Advances 6 (68), 64993–65011 , 2016 2016 Citations: 777
Heteroatom doped graphene engineering for energy storage and conversion R Kumar, S Sahoo, E Joanni, RK Singh, K Maegawa, WK Tan, ... Materials Today 39, 47-65 , 2020 2020 Citations: 671
Recent progress in the synthesis of graphene and derived materials for next generation electrodes of high performance lithium ion batteries R Kumar, S Sahoo, E J, RK Singh, WK Tan, A Matsuda Progress in Energy and Combustion Science 75, 100786 , 2019 2019 Citations: 583
Recent progress on carbon-based composite materials for microwave electromagnetic interference shielding R Kumar, S Sahoo, E Joanni, RK Singh, WK Tan, A Matsuda Carbon 177, 304-331 , 2021 2021 Citations: 456
A review on synthesis of graphene, h-BN and MoS2 for energy storage applications: Recent progress and perspectives R Kumar, S Sahoo, E Joanni, RK Singh, RM Yadav, RK Verma, DP Singh, ... Nano Research 12 (11), 2655–2694 , 2019 2019 Citations: 403
Recent advances in the synthesis and modification of carbon-based 2D materials for application in energy conversion and storage R Kumar, E Joanni, RK Singh, DP Singh, SA Moshkalev Progress in Energy and Combustion Science 67, 115-157 , 2018 2018 Citations: 397
Graphene oxide: An Efficient Material and Recent Approach for Biotechnological and Biomedical Applications DP Singh, CE Herrera, RK Singh, R Kumar Materials Science and Engineering: C 86, 173-197 , 2018 2018 Citations: 361
Self-Assembled and One-Step Synthesis of Interconnected 3D Network of Fe3O4/Reduced Graphene Oxide Nanosheets Hybrid for High Performance Supercapacitor Electrode R Kumar, RK Singh, AR Vaz, R Savu, SA Moshkalev ACS Applied Materials & Interfaces (Feature Article in Brazalian Materials … , 2017 2017 Citations: 335
Laser-assisted synthesis, reduction and micro-patterning of graphene: Recent progress and applications R Kumar, RK Singh, DP Singh, E Joanni, R Yadav, SA Moshkalev Coordination Chemistry Reviews 342, 34-79 , 2017 2017 Citations: 323
Advances in pseudocapacitive and battery-like electrode materials for high performance supercapacitors S Sahoo, R Kumar, E Joanni, RK Singh, JJ Shim Journal of Materials Chemistry A 10 (25), 13190-13240 , 2022 2022 Citations: 312
An overview of recent progress in nanostructured carbon-based supercapacitor electrodes: From zero to bi-dimensional materials R Kumar, E Joanni, S Sahoo, JJ Shim, TW Kian, A Matsuda, RK Singh Carbon 193, 298-338 , 2022 2022 Citations: 307
Progress in microwave-assisted synthesis of quantum dots (graphene/carbon/semiconducting) for bioapplications: A review RK Singh, R Kumar, DP Singh, R Savu, SA Moshlalev Materials Today Chemistry 12, 282-314 , 2019 2019 Citations: 302
Natural and waste hydrocarbon precursors for the synthesis of carbon based nanomaterials: Graphene and CNTs R Kumar, RK Singh, DP Singh Renewable and Sustainable Energy Reviews 58, 976-1006 , 2016 2016 Citations: 270
Laser processing of graphene and related materials for energy storage: State of the art and future prospects R Kumar, AP del Pino, S Sahoo, RK Singh, WK Tan, A Matsuda, E Joanni Progress in Energy and Combustion Science 91, 100981 , 2022 2022 Citations: 265
A review on the current research on microwave processing techniques applied to graphene-based supercapacitor electrodes: An emerging approach beyond conventional heating R Kumar, S Sahoo, E Joanni, RK Singh Journal of Energy Chemistry 74, 252-282 , 2022 2022 Citations: 243
Microwave-assisted thin reduced graphene oxide-cobalt oxide nanoparticles as hybrids for electrode materials in supercapacitor R Kumar, S Sahoo, WK Tan, G Kawamura, A Matsuda Journal of Energy Storage 40, 102724 , 2021 2021 Citations: 229
Graphene-wrapped and cobalt oxide-intercalated hybrid for extremely durable super-capacitor with ultrahigh energy and power densities R Kumar, HJ Kim, IK Oh Carbon 79, 192-202 , 2014 2014 Citations: 214
Review of microwave-assisted synthesis of carbon nanomaterials, metal oxide/hydroxide and its composites for energy storage applications N Devi, S Sahoo, R Kumar, RK Singh Nanoscale 13, 11679-11711 , 2021 2021 Citations: 202
Cutting edge development on graphene derivatives modified by liquid crystal and CdS/TiO2 hybrid matrix: optoelectronics and biotechnological aspects A SI, K Pal, G Sayyad, M Elkodous, R Kumar, A Batal, S Kralj, S Thomas Critical Reviews in Solid State and Materials Sciences 46 (5), 385-449 , 2021 2021 Citations: 202
Microwave as a Tool for Synthesis of Carbon-Based Electrodes for Energy Storage R Kumar, S Sahoo, E Joanni, RK Singh ACS Applied Materials & Interfaces 14 (18), 20306-20325 , 2022 2022 Citations: 198