Carlos Henriques

Scopus Publications

Operando IR of catalytic reactions under microwaves at 5.8 GHz
Frédéric Thibault-Starzyk, Ana Neto, Sébastien Thomas, Carlos Henriques, Gary Bond
Catalysis Today, 2026
Correction: Thermal and Plasma-Assisted CO2 Methanation over Ru/Zeolite: A Mechanistic Study Using In-Situ Operando FTIR (Catalysts, (2023), 13, 3, (481), 10.3390/catal13030481)
Domenico Aceto, Maria Carmen Bacariza, Arnaud Travert, Carlos Henriques, Federico Azzolina-Jury
Catalysts, 2026
The Editorial Office and Editorial Board are announcing the finished post-publication review process, as well as an update to the original publication [...]
Ultra-Microporous Fe-MOF with Prolonged NO Delivery in Biological Media for Therapeutic Application
Rosana V. Pinto, Chen‐Chen Cao, Pengbo Lyu, Iurii Dovgaliuk, William Shepard, et al.
Small, 2024
Nitric oxide (NO), a key element in the regulation of essential biological mechanisms, presents huge potential as therapeutic agent in the treatment and prevention of chronic diseases. Metal‐organic frameworks (MOFs) with open metal sites are promising carriers for NO therapies but delivering it over an extended period in biological media remains a great challenge due to i) a fast degradation of the material in body fluids and/or ii) a rapid replacement of NO by water molecules onto the Lewis acid sites. Here, a new ultra‐narrow pores Fe bisphosphonate MOF, denoted MIP‐210(Fe) or Fe(H2O)(Hmbpa) (H4mbpa = p‐xylenediphosphonic acid) is described that adsorbs NO due to an unprecedented sorption mechanism: coordination of NO through the Fe(III) sites is unusually preferred, replacing bound water, and creating a stable interaction with the free H2O and P‐OH groups delimiting the ultra‐narrow pores. This, associated with the high chemical stability of the MOF in body fluids, enables an unprecedented slow replacement of NO by water molecules in biological media, achieving an extraordinarily extended NO delivery time over at least 70 h, exceeding by far the NO kinetics release reported with others porous materials, paving the way for the development of safe and successful gas therapies.
A Mini-Review on Recent Developments and Improvements in CO2 Catalytic Conversion to Methanol: Prospects for the Cement Plant Industry
Luísa Marques, Maria Vieira, José Condeço, Carlos Henriques, Maria Mateus
Energies, 2024
The cement industry significantly impacts the environment due to natural resource extraction and fossil fuel combustion, with carbon dioxide (CO2) emissions being a major concern. The industry emits 0.6 tons of CO2 per ton of cement, accounting for about 8% of global CO2 emissions. To meet the 13th United Nations Sustainable Development Goal, cement plants aim for carbon neutrality by 2050 through reducing CO2 emissions and adopting Carbon Capture and Utilization (CCU) technologies. A promising approach is converting CO2 into valuable chemicals and fuels, such as methanol (MeOH), using Power-to-Liquid (PtL) technologies. This process involves capturing CO2 from cement plant flue gas and using hydrogen from renewable sources to produce renewable methanol (e-MeOH). Advancing the development of novel, efficient catalysts for direct CO2 hydrogenation is crucial. This comprehensive mini-review presents a holistic view of recent advancements in CO2 catalytic conversion to MeOH, focusing on catalyst performance, selectivity, and stability. It outlines a long-term strategy for utilizing captured CO2 emissions from cement plants to produce MeOH, offering an experimental roadmap for the decarbonization of the cement industry.
Review of Power-to-Liquid (PtL) Technology for Renewable Methanol (e-MeOH): Recent Developments, Emerging Trends and Prospects for the Cement Plant Industry
Luísa Marques, Maria Vieira, José Condeço, Henrique Sousa, Carlos Henriques, et al.
Energies, 2024
The cement industry is a significant contributor (around 8%) to CO2 global emissions. About 60% of the industry’s emissions come from limestone calcination, which is essential for clinker production, while 40% are the result of fuel combustion. Reducing these emissions is challenging due to limestone’s role as the primary raw material for cement. Cement plants are required to achieve carbon neutrality by 2050, as outlined in the 13th United Nations Sustainable Goals. One strategy to achieve this goal, involves Carbon Capture and utilization (CCU). Among the options for CO2 utilization, the Power-to-Liquid (PtL) strategy offers a means to mitigate CO2 emissions. In PtL, the CO2 captured from cement industrial flue gas is combined with the hydrogen generated by renewable electrolysis (green hydrogen) and is catalytically converted into renewable methanol (e-MeOH). In this sense, this review provides a comprehensive overview of the worldwide existing pilot and demonstration units and projects funded by the EU across several industries. It specifically focuses on PtL technology worldwide within cement plants. This work covers 18 locations worldwide, detailing technology existent at plants of different capacities, location, and project partners. Finally, the review analyses techno-economic assessments related to e-MeOH production processes, highlighting the potential impact on achieving carbon neutrality in the cement industry.
CO2 methanation under more realistic conditions: Influence of O2 and H2O on Ni-based catalysts’ performance
Daniela Spataru, Gilda Carvalho, Adrián Quindimil, José M. Lopes, Carlos Henriques, et al.
Chemical Engineering Journal, 2024
Doping Ni/USY zeolite catalysts with transition metals for CO2 methanation
Daniela Spataru, Diogo Canastreiro, Katarzyna Świrk Da Costa, Adrián Quindimil, José M. Lopes, et al.
International Journal of Hydrogen Energy, 2024
Sustainable Technologies in CO2 Utilization: The Production of Synthetic Natural Gas
Catalysis for A Sustainable Environment Reactions Processes and Applied Technologies Volume 1 3, 2024
Meta-analysis of CO2 conversion, energy efficiency, and other performance data of plasma-catalysis reactors with the open access PIONEER database
Antoine Salden, Maik Budde, Carolina A. Garcia-Soto, Omar Biondo, Jairo Barauna, et al.
Journal of Energy Chemistry, 2023
CO2Methanation on Ni Catalysts Supported over Activated Carbons Derived from Cork Waste
Filipe Mateus, Paula Teixeira, José M. Lopes, Carlos Henriques, Carmen Bacariza
Energy and Fuels, 2023
Thermal and Plasma-Assisted CO2 Methanation over Ru/Zeolite: A Mechanistic Study Using In-Situ Operando FTIR
Domenico Aceto, Maria Carmen Bacariza, Arnaud Travert, Carlos Henriques, Federico Azzolina-Jury
Catalysts, 2023
IoT Based Automatic Diagnosis for Continuous Improvement
Rita Martinho, Jéssica Lopes, Diogo Jorge, Luís Caldas de Oliveira, Carlos Henriques, et al.
Sustainability Switzerland, 2022
Carbon Dioxide Reforming of Methane over Nickel-Supported Zeolites: A Screening Study
Carmen Bacariza, Leila Karam, Nissrine El Hassan, José M. Lopes, Carlos Henriques
Processes, 2022
On the effect of cobalt promotion over ni/ceo2 catalyst for co2 thermal and plasma assisted methanation
Golshid Hasrack, Maria Carmen Bacariza, Carlos Henriques, Patrick Da Costa
Catalysts, 2022
Ni-based catalysts for plasma-assisted CO2 methanation
Patrick Da Costa, Goshid Hasrack, Jérôme Bonnety, Carlos Henriques
Current Opinion in Green and Sustainable Chemistry, 2021
Enhancing the CO2 methanation activity of γ-Al2O3 supported mono- and bi-metallic catalysts prepared by glycerol assisted impregnation
Adrián Quindimil, M. Carmen Bacariza, José A. González-Marcos, Carlos Henriques, Juan R. González-Velasco
Applied Catalysis B Environmental, 2021
Alkali and alkali-earth metals incorporation to ni/usy catalysts for co2 methanation: The effect of the metal nature
M. Carmen Bacariza, Cláudia Grilo, Paula Teixeira, José M. Lopes, Carlos Henriques
Processes, 2021
Mesoporous nickel-alumina catalysts derived from MIL-53(Al) metal-organic framework: A new promising path for synthesizing CO2 methanation catalysts
Leila Karam, Maria C. Bacariza, José M. Lopes, Carlos Henriques, Julien Reboul, et al.
Journal of Co2 Utilization, 2021
Improved therapeutic nitric oxide delivery by microporous Cu-bearing titanosilicate
Zhi Lin, Rosana V. Pinto, Carlos Henriques, Fernando Antunes, João Pires, et al.
Microporous and Mesoporous Materials, 2021
Promising catalytic systems for CO2 hydrogenation into CH4: A review of recent studies
M. Carmen Bacariza, Daniela Spataru, Leila Karam, José M. Lopes, Carlos Henriques
Processes, 2020
Boosting Ni Dispersion on Zeolite-Supported Catalysts for CO2Methanation: The Influence of the Impregnation Solvent
Maria C. Bacariza, Salman Amjad, Paula Teixeira, José M. Lopes, Carlos Henriques
Energy and Fuels, 2020
Assessing the potential of xNi-yMg-Al2O3 catalysts prepared by EISA-one-pot synthesis towards CO2 methanation: An overall study
Leila Karam, M. Carmen Bacariza, José M. Lopes, Carlos Henriques, Pascale Massiani, et al.
International Journal of Hydrogen Energy, 2020
Catalysts based on carbon xerogels with high catalytic activity for the reduction of NOx at low temperatures
Esther Bailón-García, Ewelina Drwal, Teresa Grzybek, Carlos Henriques, M. Filipa Ribeiro
Catalysis Today, 2020
Reduction of NO with new vanadium-carbon xerogel composites. Effect of the oxidation state of vanadium species
Esther Bailón-García, Abdelhakim Elmouwahidi, Filipa Ribeiro, Carlos Henriques, Agustín F. Pérez-Cadenas, et al.
Carbon, 2020
Optimizing Washcoating Conditions for the Preparation of Zeolite-Based Cordierite Monoliths for NOx CH4-SCR: A Required Step for Real Application
M. Carmen Bacariza, Acácio Nobre Mendes, Cansu Ozhan, Patrick Da Costa, Carlos Henriques
Industrial and Engineering Chemistry Research, 2019
Tuning Zeolite Properties towards CO 2 Methanation: An Overview
M. Carmen Bacariza, Inês Graça, José M. Lopes, Carlos Henriques
Chemcatchem, 2019
Power-to-methane over Ni/zeolites: Influence of the framework type
M.C. Bacariza, M. Maleval, I. Graça, J.M. Lopes, C. Henriques
Microporous and Mesoporous Materials, 2019
Enhanced activity of CO2 hydrogenation to CH4 over Ni based zeolites through the optimization of the Si/Al ratio
M.C. Bacariza, I. Graça, J.M. Lopes, C. Henriques
Microporous and Mesoporous Materials, 2018
Ni-Ce/Zeolites for CO2 Hydrogenation to CH4: Effect of the Metal Incorporation Order
M. Carmen Bacariza, Inês Graça, José M. Lopes, Carlos Henriques
Chemcatchem, 2018
DBD plasma-assisted CO2 methanation using zeolite-based catalysts: Structure composition-reactivity approach and effect of Ce as promoter
M.C. Bacariza, M. Biset-Peiró, I. Graça, J. Guilera, J. Morante, et al.
Journal of Co2 Utilization, 2018
Micro- and mesoporous supports for CO2 methanation catalysts: A comparison between SBA-15, MCM-41 and USY zeolite
M.C. Bacariza, I. Graça, S.S. Bebiano, J.M. Lopes, C. Henriques
Chemical Engineering Science, 2018
Chemical engineering aspects of plasma-assisted CO2 hydrogenation over nickel zeolites under partial vacuum
Federico Azzolina-Jury, Diogo Bento, Carlos Henriques, Frédéric Thibault-Starzyk
Journal of Co2 Utilization, 2017
The effect of the compensating cation on the catalytic performances of Ni/USY zeolites towards CO2 methanation
M.C. Bacariza, R. Bértolo, I. Graça, J.M. Lopes, C. Henriques
Journal of Co2 Utilization, 2017
Magnesium as Promoter of CO2 Methanation on Ni-Based USY Zeolites
Maria C. Bacariza, Inês Graça, Suse S. Bebiano, José M. Lopes, Carlos Henriques
Energy and Fuels, 2017
Controlled Photocatalytic Oxidation of Methane to Methanol through Surface Modification of Beta Zeolites
Sebastián Murcia-López, María C. Bacariza, Katherine Villa, José M. Lopes, Carlos Henriques, et al.
ACS Catalysis, 2017
Monitoring cobalt ions siting in BEA and FER zeolites by in-situ UV–Vis spectroscopy: A DRS study
S. Castilho, A. Borrego, C. Henriques, M.F. Ribeiro, A. Fernandes
Inorganica Chimica Acta, 2017
The promoting effect of Ce in the CO2methanation performances on NiUSY zeolite: A FTIR In Situ/Operando study
A. Westermann, B. Azambre, M.C. Bacariza, I. Graça, M.F. Ribeiro, et al.
Catalysis Today, 2017
On the enhancing effect of Ce in Pd-MOR catalysts for NOx CH4-SCR: A structure-reactivity study
Acácio Nobre Mendes, Vladimir L. Zholobenko, Frédéric Thibault-Starzyk, Patrick Da Costa, Carlos Henriques
Applied Catalysis B Environmental, 2016
Application of PdCe-HMOR Catalyst as NOx CH4-SCR System for Heavy-Duty Vehicles Moved by Natural Gas
A. Nobre Mendes, V. Lauga, S. Capela, M. F. Ribeiro, P. Da Costa, et al.
Topics in Catalysis, 2016
Dewatering of brewer’s spent grain using an integrated membrane filter press with vacuum drying capabilities
Remígio M. Machado, Ricardo A. D. Rodrigues, Carlos M. C. Henriques, M. Lurdes F. Gameiro, M. Rosinda C. Ismael, et al.
Separation Science and Technology Philadelphia, 2016
CO2 Hydrogenation over Ni-Based Zeolites: Effect of Catalysts Preparation and Pre-reduction Conditions on Methanation Performance
M. C. Bacariza, I. Graça, A. Westermann, M. F. Ribeiro, J. M. Lopes, et al.
Topics in Catalysis, 2016
NO:X SCR with decane using Ag-MFI catalysts: On the effect of silver content and co-cation presence
Rui Bartolomeu, Acácio Nobre Mendes, Auguste Fernandes, Carlos Henriques, Patrick da Costa, et al.
Catalysis Science and Technology, 2016
On the effect of preparation methods of PdCe-MOR catalysts as NOx CH4-SCR system for natural gas vehicles application
Acácio Mendes, Maria Ribeiro, Carlos Henriques, Patrick Da Costa
Catalysts, 2015
Potential synergic effect between MOR and BEA zeolites in NOx SCR with methane: A dual bed design approach
Acácio Nobre Mendes, Alexis Matynia, Alain Toullec, Sandra Capela, M.Filipa Ribeiro, et al.
Applied Catalysis A General, 2015
Insight into CO2 methanation mechanism over NiUSY zeolites: An operando IR study
A. Westermann, B. Azambre, M.C. Bacariza, I. Graça, M.F. Ribeiro, et al.
Applied Catalysis B Environmental, 2015
Investigation of the nature of silver species on different Ag-containing NOx reduction catalysts: On the effect of the support
Rui Bartolomeu, Bruno Azambre, Alexandre Westermann, Auguste Fernandes, Raquel Bértolo, et al.
Applied Catalysis B Environmental, 2014
The oil shale transformation in the presence of an acidic BEA zeolite under microwave irradiation
Ana Neto, Sébastien Thomas, Gary Bond, Frédéric Thibault-Starzyk, Filipa Ribeiro, et al.
Energy and Fuels, 2014
CO2 hydrogenation into CH4 on NiHNaUSY zeolites
I. Graça, L.V. González, M.C. Bacariza, A. Fernandes, C. Henriques, et al.
Applied Catalysis B Environmental, 2014
Vanadium phosphate catalysts for biodiesel production from acid industrial by-products
Carina Domingues, M. Joana Neiva Correia, Renato Carvalho, Carlos Henriques, João Bordado, et al.
Journal of Biotechnology, 2013
Particular characteristics of silver species on Ag-exchanged LTL zeolite in K and H form
Rui Bartolomeu, Raquel Bértolo, Sandra Casale, Auguste Fernandes, Carlos Henriques, et al.
Microporous and Mesoporous Materials, 2013
DeNOx over Ag/H-ZSM-5: Study of NO2 interaction with ethanol
Rui Bartolomeu, Carlos Henriques, Patrick da Costa, Filipa Ribeiro
Catalysis Today, 2011
Fluidized bed plasma for pre-treatment of Co-ferrierite catalysts: An approach to NOx abatement
R. Bartolomeu, M. Foix, A. Fernandes, M. Tatoulian, M.F. Ribeiro, et al.
Catalysis Today, 2011
Reduction of NO with metal-doped carbon aerogels
R.A. Catalão, F.J. Maldonado-Hódar, A. Fernandes, C. Henriques, M.F. Ribeiro
Applied Catalysis B Environmental, 2009
Infrared and microwaves at 5.8 GHz in a catalytic reactor
Etienne Séguin, Sébastien Thomas, Philippe Bazin, Gary Bond, Carlos Henriques, et al.
Physical Chemistry Chemical Physics, 2009
Metallic active species for deNOx SCR by methane with Co and Pd/Co HFER catalysts
Studies in Surface Science and Catalysis, 2008
Methanol interaction with NO2: An attempt to identify intermediate compounds in CH4-SCR of NO with Co/Pd-HFER catalyst
S. Capela, R. Catalão, M.F. Ribeiro, P. Da Costa, G. Djéga-Mariadassou, et al.
Catalysis Today, 2008
Selective catalytic reduction of NOx over zeolite-coated cordierite-based ceramic foams: Water deactivation
Materials Science Forum, 2008
CH4-SCR of NO over Co and Pd ferrierite catalysts: Effect of preparation on catalytic performance
A.P. Ferreira, S. Capela, P. Da Costa, C. Henriques, M.F. Ribeiro, et al.
Catalysis Today, 2007
Al-containing MCM-41 type materials prepared by different synthesis methods: Hydrothermal stability and catalytic properties
J.P. Lourenço, A. Fernandes, C. Henriques, M.F. Ribeiro
Microporous and Mesoporous Materials, 2006
SCR of NO with methane over Co-HBEA and PdCo-HBEA catalysts: The promoting effect of steaming over bimetallic catalyst
A.P. Ferreira, C. Henriques, M.F. Ribeiro, F.R. Ribeiro
Catalysis Today, 2005
Influence of rare earth elements La, Nd and Yb on the acidity of H-MCM-22 and H-Beta zeolites
Angela Martins, João M. Silva, Carlos Henriques, Fernando Ramôa Ribeiro, M. Filipa Ribeiro
Catalysis Today, 2005
NO2 disproportionation for the IR characterisation of basic zeolites
Olivier Marie, Nicolas Malicki, Catherine Pommier, Pascale Massiani, Ann VosPostdoctoral Fellow of the Fund, et al.
Chemical Communications, 2005
NO+: Infrared probe for basic zeolites
F. Thibault-Starzyk, O. Marie, N. Malicki, A. Vos, R. Schoonheydt, et al.
Studies in Surface Science and Catalysis, 2005
Structural state and redox behavior of framework Co(II) in CoIST-2: A novel cobalt-substituted aluminophosphate with AEN topology
C. Borges, M. F. Ribeiro, C. Henriques, J. P. Lourenço, D. M. Murphy, et al.
Journal of Physical Chemistry B, 2004
Selective catalytic reduction of NO on copper-exchanged zeolites: The role of the structure of the zeolite in the nature of copper-active sites
C Torre-Abreu, C Henriques, F.R Ribeiro, G Delahay, M.F Ribeiro
Catalysis Today, 1999
An FT-IR study of NO adsorption over Cu-exchanged MFI catalysts: Effect of Si/Al ratio, copper loading and catalyst pre-treatment
C. Henriques, M.F. Ribeiro, C. Abreu, D.M. Murphy, F. Poignant, et al.
Applied Catalysis B Environmental, 1998
NO TPD and H2-TPR studies for characterisation of CuMOR catalysts. The role of Si/Al ratio, copper content and cocation
C. Torre-Abreu, M.F. Ribeiro, C. Henriques, G. Delahay
Applied Catalysis B Environmental, 1997
Copper-exchanged mordenites as active catalysts for NO selective catalytic reduction by propene under oxidising conditions: Effect of Si/Al ratio, copper content and Bronsted acidity
C. Torre-Abreu, M.F. Ribeiro, C. Henriques, F.R. Ribeiro
Applied Catalysis B Environmental, 1997
Characterisation of CuMFI catalysts by temperature programmed desorption of NO and temperature programmed reduction. Effect of the zeolite Si/Al ratio and copper loading
C. Torre-Abreu, M.F. Ribeiro, C. Henriques, G. Delahay
Applied Catalysis B Environmental, 1997
Selective catalytic reduction of NO with propene over CuMFI zeolites: Dependence on Si/Al ratio and copper loading
C. Torre-Abreu, M.F. Ribeiro, C. Henriques, F.R. Ribeiro
Applied Catalysis B Environmental, 1997
Influence of cocation on catalytic activity of CuMOR catalysts for NO SCR by propene. Effect of water presence
C. Torre-Abreu, M.F. Ribeiro, C. Henriques, F.R. Ribeiro
Catalysis Letters, 1997
Deactivation of CuMFI catalysts under NO selective catalytic reduction by propene: Influence of zeolite form, Si/Al ratio and copper content
C. Torre-Abreu, M.F. Ribeiro, C. Henriques, F.R. Ribeiro, G. Delahay
Catalysis Letters, 1997
Structure-activity relationship in zeolites
F.Ram oa^Ribeiro, F. Alvarez, C. Henriques, F. Lemos, J.M. Lopes, et al.
Journal of Molecular Catalysis A Chemical, 1995
A temperature programmed surface reaction study of the catalytic epoxidation and total oxidation of ethylene on silver
Studies in Surface Science and Catalysis, 1994
A comparison between epoxidation and degradation of ethylene and propylene over silver
Studies in Surface Science and Catalysis, 1993
Catalytic epoxidation and degradation of propylene by dioxygen over silver
M. Farinha Portela, C. Henriques, Maria João Pires, L. Ferreira, M. Baerns
Catalysis Today, 1987
ZEOLITES: SOME CATALYTIC APPLICATIONS.
NATO Asi Series Series E Applied Sciences, 1986
Influence of tin on the stability of Sn/Pd Hy zeolites in the hydrocracking and hydroisomerization of n-heptane
C. Henriques, P. Dufresne, C. Marcilly, F. Ramoˆa Ribeiro
Applied Catalysis, 1986

Carlos Henriques

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Scopus Publications