Mikhailov Ilya

Scopus Publications

Synthesis, Structure, and Magnetic Properties of the Binuclear Cobalt Complex [Co2(μ‑O2PPh2)2(Bpy)4](BF4)2
A. A. Kagilev, Z. N. Gafurov, I. K. Mikhailov, I. F. Sakhapov, A. O. Kantyukov, A. B. Dobrynin, V. I. Morozov, R. B. Zaripov, A. S. Bogomyakov, O. B. Babaeva, O. G. Sinyashin, D. G. Yakhvarov
Russian Journal of Coordination Chemistry Koordinatsionnaya Khimiya, 2025
Abstract The reaction of cobalt tetrafluoroborate hexahydrate with 2,2'-bipyridine (Bpy) and diphenylphosphinic acid (Ph2P(O)OH) gave a new binuclear cobalt(II) complex [Co2(µ-O2PPh2)2(Bpy)4](BF4)2 featuring a sterically demanding bridging ligand. The complex was characterized by various physicochemical methods, and the crystal structure of the complex was determined by X-ray diffraction. Analysis of the X-ray diffraction structure of the complex showed that the cobalt ions have a distorted octahedral coordination and are linked by bridges through two {µ-O2PPh2} moieties. The data of ESR spectroscopy and magnetochemical measurements indicate the presence of a weak antiferromagnetic interaction between the cobalt ions in the molecule.
Group 10 metal complexes with redox-active pincer ligands: electronic structure and reactivity
I. K. Mikhailov, Z. N. Gafurov, A. V. Sukhov, A. A. Kagilev, A. A. Zagidullin, D. G. Yakhvarov
Russian Chemical Bulletin, 2025
Design of an Asymmetric PCN Pincer Nickel(II) Complex Based on 2,3,4,5-Tetraphenyl-1-monophosphole
I. K. Mikhailov, Z. N. Gafurov, A. A. Kagilev, A. O. Kantyukov, I. F. Sakhapov, E. M. Zueva, A. A. Zagidullin, O. G. Sinyashin, D. G. Yakhvarov
Russian Journal of Coordination Chemistry Koordinatsionnaya Khimiya, 2025
A new asymmetric PCN pincer ligand, N-ethyl-N-[3-((2,3,4,5-tetraphenyl-1H-phosphol-1-yl)methyl)benzyl]ethanamine, combining different donor groups (amino and phosphole), has been synthesized. The ligand was obtained in four steps with a good overall yield (49%) from commercially available reagents. Based on this ligand, the design of an asymmetric nickel(II) pincer complex was proposed. Quantum chemical calculations of the molecular structure of the complex indicate the formation of weak Ni–P bonds and reveal a weak trans influence of the phosphole group relative to the amino group, which distinguishes this complex from its analogs, PCN complexes based on dialkylphosphines.
Electrocatalytic proton reduction by nickel(II) diarylamido/bis(phosphine) PNP ionic pincer complex
Zufar N. Gafurov, Ilya K. Mikhailov, Alexey A. Kagilev, Aidar M. Kuchkaev, Il’yas F. Sakhapov, Artyom O. Kantyukov, Igor A. Litvinov, Evgenii I. Gutsul, Vasilisa A. Kulikova, Vladislava A. Kirkina, Elena S. Shubina, Natalia V. Belkova, Oleg G. Sinyashin, Dmitry G. Yakhvarov
Inorganica Chimica Acta, 2025
Synthesis, structure and noncovalent interactions of mesityl(phenyl)phosphine oxide glycolate based hydrogen-bonded nanosized organic framework
A.A. Kagilev, I.F. Sakhapov, Z.N. Gafurov, A.O. Kantyukov, I.K. Mikhailov, D.R. Islamov, A.V. Gerasimov, O.A. Filippov, A.T. Gubaidullin, O.S. Soficheva, O.G. Sinyashin, D.G. Yakhvarov
Nanosystems Physics Chemistry Mathematics, 2025
Electrochemical behavior of a nickel(ii) complex with an N-heterocyclic carbene bisphenolate pincer ligand
Z. N. Gafurov, I. K. Mikhailov, A. A. Kagilev, I. F. Sakhapov, A. O. Kantyukov, V. I. Morozov, D. A. Kulikov, E. M. Zueva, A. B. Dobrynin, A. A. Trifonov, D. G. Yakhvarov
Russian Chemical Bulletin, 2024
Nickel(II) Complex with the Bis(phenolate) Pincer N-Heterocyclic Carbene Ligand: Synthesis, Structure, and Properties
Z. N. Gafurov, I. K. Mikhailov, A. A. Kagilev, I. F. Sakhapov, A. O. Kantyukov, E. M. Zueva, A. B. Dobrynin, A. A. Trifonov, D. G. Yakhvarov
Russian Journal of Coordination Chemistry Koordinatsionnaya Khimiya, 2024
Abstract The nickel(II) complex Ni(L)Py (I) (L is 1,3-bis(3,5-di-tert-butyl-2-phenolato)-5,5-dimethyl-(4,6-dihydropyrimidin-2-ylidene)) containing the dianionic bonded N-heterocyclic carbene (NHC) bis(phenolate) ligand is synthesized. In the presence of a stronger base (4-dimethylaminopyridine (DMAP)), the exchange reaction occurs with the replacement of pyridine in complex I by the DMAP molecule to form complex Ni(L)(DMAP) (II), the crystal structure of which is determined by XRD. The synthesized compounds are characterized by elemental analysis, mass spectrometry, and NMR spectroscopy. The spectral characteristics of the compounds are studied.
Electrocatalytic Radical Degradation of 2-Aminoethanol by Nickel, Palladium and Platinum Complexes Bearing Non-Innocent Diarylamido/bis(Phosphine) Pincer Ligand
Ilya K. Mikhailov, Zufar N. Gafurov, Alexey A. Kagilev, Il’yas F. Sakhapov, Vladimir I. Morozov, Gumar R. Ganeev, Khasan R. Khayarov, Vasilisa A. Kulikova, Vladislava A. Kirkina, Evgenii I. Gutsul, Elena S. Shubina, Natalia V. Belkova, Oleg G. Sinyashin, Dmitry G. Yakhvarov
Applied Magnetic Resonance, 2024
The power of in situ spectroelectrochemistry for redox study of organometallic and coordination compounds
Alexey A. Kagilev, Zufar N. Gafurov, Artyom O. Kantyukov, Ilya K. Mikhailov, Dmitry G. Yakhvarov
Journal of Solid State Electrochemistry, 2024
Electrochemical generation and in situ EPR- and UV–vis- observation of aminyl-radical diarylamido/bis(phosphine) pincer complexes of Ni, Pd and Pt
Alexey A. Kagilev, Zufar N. Gafurov, Il'yas F. Sakhapov, Vladimir I. Morozov, Artyom O. Kantyukov, Ruslan B. Zaripov, Ekaterina M. Zueva, Ilya K. Mikhailov, Alexey B. Dobrynin, Vasilisa A. Kulikova, Vladislava A. Kirkina, Evgenii I. Gutsul, Elena S. Shubina, Natalia V. Belkova, Oleg G. Sinyashin, Dmitry G. Yakhvarov
Journal of Electroanalytical Chemistry, 2024
Erratum to: Specific Behavior of the Electrochemically Generated Organonickel Sigma-Complex [NiBr(Tcpp)(bpy)], where Tcpp is 2,4,6-Tricyclopentylphenyl, bpy is 2,2'-Bipyridine (Russian Journal of Electrochemistry, (2022), 58, 12, (1074-1082), 10.1134/S1023193522120060)
I. F. Sakhapov, Z. N. Gafurov, A. O. Kantyukov, A. A. Kagilev, I. K. Mikhailov, E. M. Zueva, D. N. Buzyurova, V. M. Babaev, S. A. Shteingolts, R. R. Fayzullin, G. E. Bekmukhamedov, D. G. Yakhvarov
Russian Journal of Electrochemistry, 2024
Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate
I. F. Sakhapov, A. A. Kagilev, A. O. Kantyukov, I. K. Mikhailov, O. S. Sof’icheva, D. R. Islamov, Z. N. Gafurov, D. G. Yakhvarov
Russian Journal of Inorganic Chemistry, 2023
Erratum to: SYNTHESIS, STRUCTURE, AND PROPERTIES OF THE ORGANONICKEL σ-COMPLEX [NiBr(Pmp)(bpy)], WHERE Pmp IS 2,3,4,5,6- PENTAMETHYLPHENYL, bpy IS 2,2′-BIPYRIDINE (Journal of Structural Chemistry, (2023), 64, 1, (121-130), 10.1134/S0022476623010080)
Z. N. Gafurov, I. F. Sakhapov, A. A. Kagilev, A. O. Kantyukov, I. K. Mikhailov, G. R. Ganeev, R. R. Faizullin, K. R. Khayarov, A. V. Gerasimov, D. G. Yakhvarov
Journal of Structural Chemistry, 2023
Redox Chemistry of Pt(II) Complex with Non-Innocent NHC Bis(Phenolate) Pincer Ligand: Electrochemical, Spectroscopic, and Computational Aspects
Ilya K. Mikhailov, Zufar N. Gafurov, Alexey A. Kagilev, Vladimir I. Morozov, Artyom O. Kantyukov, Ekaterina M. Zueva, Gumar R. Ganeev, Ilyas F. Sakhapov, Asiya V. Toropchina, Igor A. Litvinov, Galina A. Gurina, Alexander A. Trifonov, Oleg G. Sinyashin, Dmitry G. Yakhvarov
Catalysts, 2023
SYNTHESIS, STRUCTURE, AND PROPERTIES OF THE ORGANONICKEL σ-COMPLEX [NiBr(Pmp)(bpy)], WHERE Pmp IS 2,3,4,5,6- PENTAMETHYLPHENYL, bpy IS 2,2′-BIPYRIDINE
Z. N. Gafurov, I. F. Sakhapov, A. A. Kagilev, A. O. Kantyukov, I. K. Mikhailov, G. R. Ganeev, R. R. Faizullin, K. R. Khayarov, A. V. Gerasimov, D. G. Yakhvarov
Journal of Structural Chemistry, 2023
Crystal Structure of the Organonickel Sigma Complex [NiBr(Tcpp)(bpy)]
A. A. Kagilev, Z. N. Gafurov, I. F. Sakhapov, D. R. Islamov, A. O. Kantyukov, I. K. Mikhailov, D. G. Yakhvarov
Russian Journal of General Chemistry, 2022
Specific Behavior of the Electrochemically Generated Organonickel Sigma-Complex [NiBr(Tcpp)(bpy)], where Tcpp is 2,4,6-Tricyclopentylphenyl, bpy is 2,2'-Bipyridine
I. F. Sakhapov, Z. N. Gafurov, A. O. Kantyukov, A. A. Kagilev, I. K. Mikhailov, E. M. Zueva, D. N. Buzyurova, V. M. Babaev, S. A. Shteingolts, R. R. Faizullin, G. E. Bekmukhamedov, D. G. Yakhvarov
Russian Journal of Electrochemistry, 2022
Electrochemical behaviour of 2,2′-bibenzimidazoles: Voltammetric, in situ UV–vis- and EPR-spectroelectrochemical and computational studies
Alexey A. Kagilev, Vladimir I. Morozov, Ekaterina M. Zueva, Zufar N. Gafurov, Ilya K. Mikhailov, Artyom O. Kantyukov, Il'yas F. Sakhapov, Nataliya A. Zhukova, Milyausha S. Kadyrova, Vakhid A. Mamedov, Dmitry G. Yakhvarov
Journal of Electroanalytical Chemistry, 2022
Benzothiazole- vs. pyrazole-based unsymmetrical (PCN) pincer complexes of nickel(II) as homogeneous catalysts in ethylene oligomerization
Zufar N. Gafurov, Ekaterina M. Zueva, Giyjaz E. Bekmukhamedov, Alexey A. Kagilev, Artyom O. Kantyukov, Ilya K. Mikhailov, Khasan R. Khayarov, Maria M. Petrova, Alexey P. Dovzhenko, Andrea Rossin, Giuliano Giambastiani, Dmitry G. Yakhvarov
Journal of Organometallic Chemistry, 2021
Recent advances in chemistry of unsymmetrical phosphorus-based pincer nickel complexes: From design to catalytic applications
Zufar N. Gafurov, Artyom O. Kantyukov, Alexey A. Kagilev, Alina A. Kagileva, Il’yas F. Sakhapov, Ilya K. Mikhailov, Dmitry G. Yakhvarov
Molecules, 2021
Unsymmetrical pyrazole-based PCN pincer NiII halides: Reactivity and catalytic activity in ethylene oligomerization
Zufar N. Gafurov, Giyjaz E. Bekmukhamedov, Alexey A. Kagilev, Artyom O. Kantyukov, Il’yas F. Sakhapov, Ilya K. Mikhailov, Khasan R. Khayarov, Ruslan B. Zaripov, Daut R. Islamov, Konstantin S. Usachev, Lapo Luconi, Andrea Rossin, Giuliano Giambastiani, Dmitry G. Yakhvarov
Journal of Organometallic Chemistry, 2020

Mikhailov Ilya

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Scopus Publications