Electrochemical investigation of a rotationally flexible bibenzimidazole di-iron complex Markus Nilsson, Pablo G. Porta, Dieter Sorsche, Elisabet Ahlberg, Michael Busch Electrochimica Acta, 2026 Ligand systems used for electrochemical reductions commonly comprise single metal centres. This is opposed to complexes with two or more adjacent metals for which are significantly less studied. In order to fill this gap a Fe dimer embedded into the 1,1’,5,5’,6,6’-hexamethyl-4,4’-bis(picolinimino)-2,2’-bibenzimidazole ( Me bpbbi ) ligand system is studied in the present work with focus on electrochemical properties in acetonitrile solution. A combination of cyclic voltammetry and density functional theory (DFT) reveals that the complex is present at least as an open, non-bridged, and a closed, (µ-Cl) 2 bridged complex. Both forms possess very different redox properties and ligand exchange energetics. The presence of a stable reversible electron transfer couple for the non-bridged complex is promising for electrocatalytic reactions. Surprisingly, our calculations demonstrate that the iron ions essentially maintain their charge while the ligand accommodates the charges involved in the different redox steps.
Hot-Carrier Injection and Millisecond Charge Separation from a Robust Heteroleptic Iron(II) Chromophore Immobilized on TiO2 Thomas Whittemore, Marvin Schmalle, Evgenia Ryndin, Mark Spitler, Elias H. P. Brohmer, Sven Rau, Linda Zedler, Evgeny O. Danilov, Felix N. Castellano, Stephan Kupfer, Gerald Meyer, Dieter Sorsche Journal of the American Chemical Society, 2026 High Resolution Image Download MS PowerPoint Slide The synthesis, spectroscopic characterization, computational analysis, and photoelectrochemical behavior of a new iron-based chromophore, [(Cpy) 2 Fe(deeb)](PF 6 ) 2 (Fe(Cpy) 2 (deeb)), where Cpy is 1-methyl-3-(2-pyridyl)imidazole and deeb is 4,4’-(CO 2 CH 2 CH 3 ) 2 -2,2’-bipyridine, is reported. Electrochemically reversible waves assigned to a metal-centered E o (Fe III/II ) = +0.48 and a ligand-centered E o (Fe 2+/+ ) = −1.47 V vs Fc +/0 reduction were evident in cyclic voltammetry measurements. The combination of a strong σ-donor and a π-acceptor lowered the energy of the metal-to-ligand charge-transfer (MLCT) excited state relative to the metal-centered state. Two MLCT transitions appear in the visible region at 424 and 580 nm. TDDFT calculations revealed that the lower-energy band was well formulated as Fe(II)→deeb, and the higher-energy transition was charge transfer to both the deeb and Cpy ligands. Resonance Raman spectroscopy supports these findings showing enhanced deeb vibrational modes with 532 nm excitation, both deeb and Cpy modes with 473 nm excitation, and exclusively Cpy with 405 nm excitation. Ultrafast spectroscopy reveals a short-lived (∼2 ps) MLCT excited state and a longer-lived (∼20 ps) metal-centered state. Efficient methods to deprotect the ester groups and anchor the complex to mesoporous TiO 2 (anatase) thin films in high surface coverages, Fe(Cpy) 2 (dcb)|TiO 2 σ = 3 × 10 –8 mol/cm 2, were established. Pulsed light excitation of Fe(Cpy) 2 (dcb)|TiO 2 resulted in rapid excited state injection ( k inj > 10 8 s –1 ) and formation of a charge-separated state, Fe III (Cpy) 2 (dcb)|TiO 2 (e), which persists on the millisecond time scale before returning cleanly to the ground state with second-order kinetics. Injection yields measured 50 ns after light excitation were found to double from Φ = 0.15 with green (532 nm) light to 0.30 with blue (457 nm) light excitation. Incident photon-to-current efficiency (% IPCE) measurements as a function of excitation wavelength in a 0.5 M LiI/I 2 /CH 3 CN electrolyte provide clear evidence for band-selective “hot carrier” injection from the remote Cpy-localized excited state. Collectively, the spectroscopic and photoelectrochemical data indicate that a semiconductor can intercept hot electrons from iron chromophores even when the excited-state dipole is oriented away from the surface-anchoring ligand.
Local Environmental Effects on Light-Driven CO2Reduction in Liposomes Amir Abbas, Richard Jacobi, Ingrid Merker, Riccarda Müller, Nathaniel R. Ritz, Nitish Kumar, Hani M. Elbeheiry, Dieter Sorsche, Kerstin Leopold, Leticia González, Andrea Pannwitz ACS Catalysis, 2026 High Resolution Image Download MS PowerPoint Slide We report the governing principles that regulate the activity of light-driven CO 2 reduction by a molecular photosensitizer bis(2,2′-bipyridine)-(4,4′-dinonyl-2,2′-bipyridine)-ruthenium(II) ( RuC 9 ) and a molecular catalyst (5,10,15,20-tetra(4-methylphenyl)porphinato)cobalt(II) ( CoTTP ) in supramolecular assembly within the lipid bilayers of liposomes suspended in water. We tested six different lipids with membranes in either the gel phase, fluid phase, or at the transition between both states, as well as zwitterionic or negatively charged headgroups. The correlation of the membrane rigidity with light-driven catalysis performance is not conclusive for the investigated set of lipid membranes, but molecular dynamics simulations elucidate how catalyst efficiency increases with the distance from the membrane center as well as their calculated vertical reduction energies. Luminescence quenching studies revealed that mainly dynamic quenching was observed with the highest quenching efficiency found with 1,2-dimyristoyl- sn -glycero-3-phosphocholine (DMPC) and 1,2-dipalmitoyl- sn -glycero-3-phospho-(1′-rac-glycerol)(sodium salt) (DPPG)-based liposomes, in agreement with the results of the best performance in photocatalysis and the computational insights. A variation of cations did not show any significant influence on the performance, as opposed to electrochemical studies. The overall mechanistic findings of this study provide design principles for light-driven CO 2 reduction by molecular components in liposomes.
Photoinduced Electron Transfer Across Phospholipid Bilayers in Anaerobic and Aerobic Atmospheres Novitasari Sinambela, Richard Jacobi, Dieter Sorsche, Leticia González, Andrea Pannwitz Angewandte Chemie International Edition, 2025 In natural photosynthesis, light‐driven electron transfer across the thylakoid membrane enables efficient charge separation and the confinement of reaction spaces for generating NADPH and CO2 and oxidation of water. These reactions are complementary redox reactions and require different reaction conditions for optimal performance. However, current artificial photosynthesis studies only take place in the bulk and are sensitive toward oxygen and air, which limits their applicability under aerated and water‐splitting conditions. Herein, we report light‐driven electron transfer across a lipid bilayer membrane of liposome vesicles via a rigid oligoaromatic molecular wire that allows to electronically connect an oxidation and reduction reaction which are spatially separated by the membrane. The molecular wire has a simple, symmetric, easy‐to‐synthesize design based on benzothiadiazole and fluorene units and absorbs in the visible spectrum which makes it suitable for solar energy conversion. The model reactions in this study are light‐driven NADH oxidation on one side of the membrane and light‐driven reduction of an organic water‐soluble dye in the bulk phase of liposomes. Additionally, the system is active in both aerobic and anaerobic atmospheres, rendering it ideal for aerobic conditions or reactions that produce oxygen such as solar‐driven water splitting and artificial photosynthesis applications.
Shifting the MLCT of d6 metal complexes to the red and NIR Dieter Sorsche, Marco A.L. Lima, Nicolas Meitinger, Krishna Prasad, Subrata Mandal, Ksenija D. Glusac, Sven Rau, Andrea Pannwitz Coordination Chemistry Reviews, 2025 Light-active d 6 -coordination compounds hold great promise for light energy conversion, sensors and therapeutic applications. However, the activity in the red-to-NIR spectral region is highly desirable to convert solar light more efficiently, use low-cost red-light sources and activate these chromophores in biological tissue environment. Due to their versatility, tunability and broad intense absorption, d 6 -coordination compounds with metal-to-ligand charge transfer (MLCT) transitions are especially interesting. This review article offers a comprehensive collection of strategies to tune MLCT excited states in d 6 metal complexes and gives insights on group 6 to group 9 transition metals and their respective state-of-the-art MLCT engineering towards red-shifted absorption and emission properties with long-lived excited states. Strategies comprise lowering the π* level of the ligands, destabilizing and mixing of the metal-based HOMO, switching within a group of transition metals, matrix effects and insights into dealing with excited state deactivation in the context of the energy gap law. • Strong sigma donor ligands destabilize the HOMO and lead to a red-shift. • Extension of the ligand's π-system can result in a stabilized LUMO leading to a red-shift. • The HOMO of d 6 MLCT complexes of Co, Ir and Rh, often mix with ligand's, leading to Metal-Ligand to Ligand Charge Transfer. • The energy gap law is the biggest challenge for NIR and red excited states.
Beyond the First Coordination Sphere─Manipulating the Excited-State Landscape in Iron(II) Chromophores with Protons Kamil Witas, Shruthi Santhosh Nair, Tamar Maisuradze, Linda Zedler, Heiner Schmidt, Pablo Garcia-Porta, Alexandra Stefanie Jessica Rein, Tim Bolter, Sven Rau, Stephan Kupfer, Benjamin Dietzek-Ivanšić, Dieter U. Sorsche Journal of the American Chemical Society, 2024 Molecular transition metal chromophores play a central role in light harvesting and energy conversion. Recently, earth-abundant transition-metal-based chromophores have begun to challenge the dominance of platinum group metal complexes in this area. However, the development of new chromophores with optimized photophysical properties is still limited by a lack of synthetic methods, especially with respect to heteroleptic complexes with functional ligands. Here, we demonstrate a facile and efficient method for the combination of strong-field carbenes with the functional 2,2′-bibenzimidazole ligand in a heteroleptic iron(II) chromophore complex. Our approach yields two isomers that differ predominantly in their excited-state lifetimes based on the symmetry of the ligand field. Deprotonation of both isomers leads to a significant red-shift of the metal-to-ligand charge transfer (MLCT) absorption and a shortening of excited-state lifetimes. Femtosecond transient absorption spectroscopy in combination with quantum chemical simulations and resonance Raman spectroscopy reveals the complex relationship between protonation and photophysical properties. Protonation is found to tip the balance between MLCT and metal-centered (MC) excited states in favor of the former. This study showcases the first example of fine-tuning of the excited-state landscape in an iron(II) chromophore through second-sphere manipulations and provides a new perspective to the challenge of excited-state optimizations in 3d transition metal chromophores.
Stabilizing Decavanadate Cluster as Electrode Material in Sodium and Lithium-ion Batteries Meena Ghosh, Dieter Sorsche, Rezwana Binte Ahmed, Montaha Anjass Chemsuschem, 2023 Decavanadate ([V10O28]6−, {V10}) clusters are a potential electrode material for lithium and post‐lithium batteries; however, their low stability due to the solubility in liquid organic electrolytes has been challenging. These molecular clusters are also prone to transform into solid‐state oxides at a moderate temperature needed in the typical electrode fabrication process. Hence, controlling the solubility and improving the thermal stability of compounds are essential to make them more viable options for use as battery electrodes. This study shows a crystal engineering approach to stabilize the cluster with organic guanidinium (Gdm+) cation through the hydrogen‐bonding interactions between the amino groups of the cation and the anion. The comparison of solubility and thermal stability of the Gdm{V10} with another cluster bearing tetrabutylammonium (Tba+) cation reveals the better stability of cation‐anion assembly in the former than the latter. As a result, the Gdm{V10} delivers better rate capability and cycling stability than Tba{V10} when tested as anode material in a half‐cell configuration of a sodium‐ion battery. Finally, the performance of the Gdm{V10} anode is also investigated in a lithium‐ion battery full cell with LiFePO4 cathode.
Kristalle züchten: zwischen Alchemie und Wissenschaft Marius Müßler, Andrea Pannwitz, Dieter Sorsche Nachrichten Aus Der Chemie, 2023 „Nur während der ruhigen Zeit zwischen den Jahren, wenn niemand im Labor ist, können die Kristalle schön wachsen“, heißt es, oder „Bestimmte Kristalle wachsen nur im Winter im dunklen, kalten Kühlschrank“. Manche verlassen sich auf Fliegenbeine als Kristallisationskeime oder stellen Kristallansätze offen auf die Fensterbank. Tipps und Tricks, um Kristalle herzustellen.
Coupled reaction equilibria enable the light-driven formation of metal-functionalized molecular vanadium oxides Stefan Repp, Moritz Remmers, Alexandra Stefanie Jessica Rein, Dieter Sorsche, Dandan Gao, Montaha Anjass, Mihail Mondeshki, Luca M. Carrella, Eva Rentschler, Carsten Streb Nature Communications, 2023 The introduction of metal sites into molecular metal oxides, so-called polyoxometalates, is key for tuning their structure and reactivity. The complex mechanisms which govern metal-functionalization of polyoxometalates are still poorly understood. Here, we report a coupled set of light-dependent and light-independent reaction equilibria controlling the mono- and di-metal-functionalization of a prototype molecular vanadium oxide cluster. Comprehensive mechanistic analyses show that coordination of a Mg2+ ion to the species {(NMe2H2)2[VV12O32Cl]}3- results in formation of the mono-functionalized {(NMe2H2)[(MgCl)VV12O32Cl]}3- with simultaneous release of a NMe2H2+ placeholder cation. Irradiation of this species with visible light results in one-electron reduction of the vanadate, exchange of the second NMe2H2+ with Mg2+, and formation/crystallization of the di-metal-functionalized [(MgCl)2VIVVV11O32Cl]4-. Mechanistic studies show how stimuli such as light or competing cations affect the coupled equilibria. Transfer of this synthetic concept to other metal cations is also demonstrated, highlighting the versatility of the approach.
Blickpunkt Anorganik: Die Eisenzeit der Photochemie beginnt Andrea Pannwitz, Dieter Sorsche Nachrichten Aus Der Chemie, 2023 Photochemische Prozesse finden in Synthese, Oleds und katalytischen Prozessen statt. 3d‐Übergangsmetalle wie Eisen können die Farbstoffe und Photosensibilisatoren aus Schwermetallen ablösen.
Silica Supported Organometallic IrI Complexes Enable Efficient Catalytic Methane Borylation Orion Staples, Magali S. Ferrandon, Guillaume P. Laurent, Uddhav Kanbur, A. Jeremy Kropf, Michael R. Gau, Patrick J. Carroll, Katherine McCullough, Dieter Sorsche, Frédéric A. Perras, Massimiliano Delferro, David M. Kaphan, Daniel J. Mindiola Journal of the American Chemical Society, 2023
Unusual Dinitrogen Binding and Electron Storage in Dinuclear Iron Complexes Dieter Sorsche, Matthias E. Miehlich, Keith Searles, Guillaume Gouget, Eva M. Zolnhofer, Skye Fortier, Chun-Hsing Chen, Michael Gau, Patrick J. Carroll, Christopher B. Murray, Kenneth G. Caulton, Marat M. Khusniyarov, Karsten Meyer, Daniel J. Mindiola Journal of the American Chemical Society, 2020
Electrochemical Investigation of a Rotationally Flexible Bibenzimidazole Di-iron Complex M Nilsson, PG Porta, D Sorsche, E Ahlberg, M Busch Electrochimica Acta, 149122 , 2026 2026
Hot-Carrier Injection and Millisecond Charge Separation from a Robust Heteroleptic Iron(II) Chromophore Immobilized on TiO 2 T Whittemore, M Schmalle, E Ryndin, M Spitler, EHP Brohmer, S Rau, ... Journal of the American Chemical Society , 2026 2026
Local Environmental Effects on Light-Driven CO 2 Reduction in Liposomes A Abbas, R Jacobi, I Merker, R Müller, NR Ritz, N Kumar, HM Elbeheiry, ... ACS catalysis 16 (5), 4362-4372 , 2026 2026
A Bright New Link–A Novel Light-Switch-Capable Bridging Ligand in Photoactive Metal Complexes D Isakov, K Witas, M Semwal, P Traber, ASJ Rein, D Sorsche, ... ChemRxiv 2025 (1222) , 2025 2025
Entropy-driven ligand exchange in a rotationally flexible dinuclear Fe (II)-Fe (II) complex PG Porta, B Kintzel, B Weber, M Busch, D Sorsche ChemRxiv 2025 (1126) , 2025 2025 Citations: 1
Lichtgetriebener Elektronentransfer durch Phospholipid‐Doppelschichten in anaerober und aerober Atmosphäre N Sinambela, R Jacobi, D Sorsche, L González, A Pannwitz Angewandte Chemie 137 (22), e202423393 , 2025 2025
Photoinduced electron transfer across phospholipid bilayers in anaerobic and aerobic atmospheres N Sinambela, R Jacobi, D Sorsche, L González, A Pannwitz Angewandte Chemie International Edition 64 (22), e202423393 , 2025 2025 Citations: 13
Shifting the MLCT of d6 metal complexes to the red and NIR D Sorsche, MAL Lima, N Meitinger, K Prasad, S Mandal, KD Glusac, ... Coordination Chemistry Reviews 530, 216454 , 2025 2025 Citations: 20
Beyond the First Coordination Sphere─ Manipulating the Excited-State Landscape in Iron (II) Chromophores with Protons K Witas, SS Nair, T Maisuradze, L Zedler, H Schmidt, P Garcia-Porta, ... Journal of the American Chemical Society 146 (29), 19710-19719 , 2024 2024 Citations: 21
Stabilizing decavanadate cluster as electrode material in sodium and lithium‐ion batteries M Ghosh, D Sorsche, R Binte Ahmed, M Anjass ChemSusChem 16 (24), e202300631 , 2023 2023 Citations: 8
Kristalle züchten: zwischen Alchemie und Wissenschaft M Müßler, A Pannwitz, D Sorsche Nachrichten aus der Chemie 71 (12), 64-67 , 2023 2023 Citations: 1
Blickpunkt Anorganik: Die Eisenzeit der Photochemie beginnt. A Pannwitz, D Sorsche Nachrichten aus der Chemie 71 (10) , 2023 2023
Coupled reaction equilibria enable the light-driven formation of metal-functionalized molecular vanadium oxides S Repp, M Remmers, ASJ Rein, D Sorsche, D Gao, M Anjass, ... Nature Communications 14 (1), 5563 , 2023 2023 Citations: 11
Silica Supported Organometallic Ir I Complexes Enable Efficient Catalytic Methane Borylation O Staples, MS Ferrandon, GP Laurent, U Kanbur, AJ Kropf, MR Gau, ... Journal of the American Chemical Society 145 (14), 7992-8000 , 2023 2023 Citations: 23
Supramolecular Aggregation Control in Polyoxometalates Covalently Functionalized with Oligoaromatic Groups S Knoll, M Hänle, AK Mengele, D Sorsche, S Rau, C Streb Chemistry–A European Journal 29 (15), e202203469 , 2023 2023 Citations: 1
Red Light Absorption of [Re I (CO) 3 (α-diimine)Cl] Complexes through Extension of the 4,4′-Bipyrimidine Ligand’s π-System N Meitinger, S Mandal, D Sorsche, A Pannwitz, S Rau Molecules 28 (4), 1905 , 2023 2023 Citations: 5
Mechanistic insights into template-driven polyoxovanadate self-assembly: the role of internal and external templates S Repp, KL Junginger, D Sorsche, T Zorn, AC Pöppler, Y Kikukawa, ... Dalton Transactions 52 (13), 4002-4007 , 2023 2023 Citations: 7
A Triad Photoanode for Visible Light‐Driven Water Oxidation via Immobilization of Molecular Polyoxometalate on Polymeric Carbon Nitride R Gong, D Mitoraj, D Gao, M Mundszinger, D Sorsche, U Kaiser, C Streb, ... Advanced Sustainable Systems 6 (5), 2100473 , 2022 2022 Citations: 25
Cation-controlled capture of polyoxovanadate-based organic–inorganic 1D architectures S Repp, M Steiner, M Anjass, D Sorsche, C Streb Chemical Communications 58 (96), 13397-13400 , 2022 2022 Citations: 5
Self-activation of a polyoxometalate-derived composite electrocatalyst for the oxygen evolution reaction R Gong, D Gao, R Liu, D Sorsche, J Biskupek, U Kaiser, S Rau, C Streb ACS Applied Energy Materials 4 (11), 12671-12676 , 2021 2021 Citations: 44
MOST CITED SCHOLAR PUBLICATIONS
Optical sensing of anions via supramolecular recognition with biimidazole complexes SA Rommel, D Sorsche, M Fleischmann, S Rau Chemistry–A European Journal 23 (72), 18101-18119 , 2017 2017 Citations: 48
Rational design of a catalyst for the selective monoborylation of methane S Ahn, D Sorsche, S Berritt, MR Gau, DJ Mindiola, MH Baik ACS Catalysis 8 (11), 10021-10031 , 2018 2018 Citations: 46
Self-activation of a polyoxometalate-derived composite electrocatalyst for the oxygen evolution reaction R Gong, D Gao, R Liu, D Sorsche, J Biskupek, U Kaiser, S Rau, C Streb ACS Applied Energy Materials 4 (11), 12671-12676 , 2021 2021 Citations: 44
Unusual dinitrogen binding and Electron storage in dinuclear Iron complexes D Sorsche, ME Miehlich, K Searles, G Gouget, EM Zolnhofer, S Fortier, ... Journal of the American Chemical Society 142 (18), 8147-8159 , 2020 2020 Citations: 44
Synthesis and characterization of ruthenium and rhenium dyes with phosphonate anchoring groups M Braumüller, M Schulz, M Staniszewska, D Sorsche, M Wunderlin, ... Dalton Transactions 45 (22), 9216-9228 , 2016 2016 Citations: 31
Supramolecular activation of a molecular photocatalyst MG Pfeffer, C Pehlken, R Staehle, D Sorsche, C Streb, S Rau Dalton transactions 43 (35), 13307-13315 , 2014 2014 Citations: 30
Synthesis and characterization of an immobilizable photochemical molecular device for H 2-generation M Braumüller, M Schulz, D Sorsche, M Pfeffer, M Schaub, J Popp, ... Dalton transactions 44 (12), 5577-5586 , 2015 2015 Citations: 29
Metal–ligand cooperativity promoting sulfur atom transfer in ferrous complexes and isolation of a sulfurmethylenephosphorane adduct D Sorsche, ME Miehlich, EM Zolnhofer, PJ Carroll, K Meyer, DJ Mindiola Inorganic Chemistry 57 (18), 11552-11559 , 2018 2018 Citations: 26
Oxygen‐Dependent Photocatalytic Water Reduction with a Ruthenium (imidazolium) Chromophore and a Cobaloxime Catalyst L Petermann, R Staehle, M Pfeifer, C Reichardt, D Sorsche, M Wächtler, ... Chemistry–A European Journal 22 (24), 8240-8253 , 2016 2016 Citations: 26
A Triad Photoanode for Visible Light‐Driven Water Oxidation via Immobilization of Molecular Polyoxometalate on Polymeric Carbon Nitride R Gong, D Mitoraj, D Gao, M Mundszinger, D Sorsche, U Kaiser, C Streb, ... Advanced Sustainable Systems 6 (5), 2100473 , 2022 2022 Citations: 25
Visible-light sensitized photocatalytic hydrogen generation using a dual emissive heterodinuclear cyclometalated iridium (III)/ruthenium (II) complex SA Rommel, D Sorsche, S Schönweiz, J Kübel, N Rockstroh, B Dietzek, ... Journal of Organometallic Chemistry 821, 163-170 , 2016 2016 Citations: 25
Silica Supported Organometallic Ir I Complexes Enable Efficient Catalytic Methane Borylation O Staples, MS Ferrandon, GP Laurent, U Kanbur, AJ Kropf, MR Gau, ... Journal of the American Chemical Society 145 (14), 7992-8000 , 2023 2023 Citations: 23
Protonation‐Dependent Luminescence of an Iridium (III) Bibenzimidazole Chromophore SA Rommel, D Sorsche, N Rockstroh, FW Heinemann, J Kübel, ... European Journal of Inorganic Chemistry 2015 (22), 3730-3739 , 2015 2015 Citations: 22
Optimized synthesis of a tert-butyl-phenyl-substituted tetrapyridophenazine ligand and its Ru (II) complexes and determination of dimerization behaviour of the complexes … K Ritter, C Pehlken, D Sorsche, S Rau Dalton Transactions 44 (19), 8889-8905 , 2015 2015 Citations: 22
Beyond the First Coordination Sphere─ Manipulating the Excited-State Landscape in Iron (II) Chromophores with Protons K Witas, SS Nair, T Maisuradze, L Zedler, H Schmidt, P Garcia-Porta, ... Journal of the American Chemical Society 146 (29), 19710-19719 , 2024 2024 Citations: 21
Efficient Access to 5‐Bromo‐and 5, 6‐Dibromophenanthroline Ligands A Stumper, TD Pilz, M Schaub, H Görls, D Sorsche, K Peuntinger, D Guldi, ... European Journal of Inorganic Chemistry 2017 (32), 3799-3810 , 2017 2017 Citations: 21
Shifting the MLCT of d6 metal complexes to the red and NIR D Sorsche, MAL Lima, N Meitinger, K Prasad, S Mandal, KD Glusac, ... Coordination Chemistry Reviews 530, 216454 , 2025 2025 Citations: 20
A supramolecular H-bond driven light switch sensor for small anions SA Rommel, D Sorsche, S Rau Dalton Transactions 45 (1), 74-77 , 2016 2016 Citations: 18
Ruthenium Imidazophenanthrolinium Complexes with Prolonged Excited‐State Lifetimes R Staehle, C Reichardt, J Popp, D Sorsche, L Petermann, K Kastner, ... European Journal of Inorganic Chemistry 2015 (23), 3932-3939 , 2015 2015 Citations: 18
Synthesis and Characterization of a Trisheteroleptic Ru II ‐Based Molecular Switch K Monczak, K Peuntinger, D Sorsche, FW Heinemann, DM Guldi, S Rau Chemistry–A European Journal 20 (47), 15426-15433 , 2014 2014 Citations: 18
