Influence of Reaction Parameters on Nanogold-Catalyzed Glucose and Xylose Oxidation: A Joint Experimental and DFT Study Jay Pee Oña, Laura Laverdure, Rose Marie Latonen, Narendra Kumar, Markus Peurla, Ilari Angervo, Karoliina Honkala, Henrik Grénman ACS Catalysis, 2024 The electrocatalytic oxidation (ECO) of glucose on gold requires alkaline conditions and relatively high potentials (>0.3 V RHE ). Although the adsorption of hydroxide ions (OH ads ) is also known to occur under these conditions, the generally accepted proton-coupled electron transfer mechanism for sugar ECO does not explicitly state the role of OH ads in the sugar adsorption or oxidation steps. To investigate this, we carried out a combined experimental and density functional theory (DFT) study on the ECO of glucose and xylose over a nanogold catalyst under temperature and pH control. Grand canonical DFT (GC-DFT) was used to identify the preferred reaction mechanism in which OH ads facilitates the thermodynamically feasible formation of gluconic and xylonic acid. Calculated results also showed that OH ads plays a role in improving the acid selectivity. Constant-potential electrolyses in sugar solutions were performed using mesoporous (Sibunit) carbon-supported Au nanoparticles (AuNPs) with an average cluster size of 4.7 nm. Experimental results showed that the highest conversions for glucose (57.7%) and xylose (49.4%) were obtained at 25 °C and pH 12.5, with gluconic and xylonic acid selectivity of 81.5 and 87.8%, respectively. The catalytic activities were high considering the low Au loading (∼0.1% wt). Higher pH led to a decrease in the ECO rate possibly due to excess hydroxide ions blocking active sites for sugar adsorption. Our results highlight the importance of computational studies in elucidating reaction mechanisms for sugar ECO where sugar acids are the main oxidation products. This is crucial in designing reaction systems for the viable production of these value-added chemicals from biomass.
Graphene and graphene-cellulose nanocrystal composite films for sustainable anodes in biophotovoltaic devices Sara Lund, Laura T. Wey, Jouko Peltonen, Johan Bobacka, Rose-Marie Latonen, Yagut Allahverdiyeva Sustainable Energy and Fuels, 2023 This work demonstrates the innovative utilisation of sheer exfoliated few-layer graphene and graphene–CNC films as eco-friendly electrodes for efficient current extraction from cyanobacteria, promising advancements in biophotovoltaic applications.
Kinetic studies of solid foam catalysts for the production of sugar alcohols: Xylitol from biomass resources German Araujo-Barahona, Alberto Goicoechea-Torres, Kari Eränen, Rose-Marie Latonen, Teija Tirri, Annika Smeds, Dmitry Murzin, Juan García-Serna, Tapio Salmi Chemical Engineering Science, 2023 Structured catalysts, such as solid foams, represent a very promising technology for continuous and stable production of high-value compounds derived from biomass, traditionally produced with batch and semibatch technologies using suspended catalysts. However, the synthesis of structured catalysts presents additional challenges related to their structure and the generation of porous coatings with suitable properties for dispersing the catalytically active phase on the support. This work was focused on synthesizing a Ru/C solid foam catalyst and investigating its activity in the selective hydrogenation of xylose to xylitol under different operational conditions. The carbon coating, the key step of preparation, was based on the formation and pyrolysis of poly(furfuryl alcohol) in the presence of different amounts of poly(ethylene glycol) (PEG; M = 8 kDa) as a pore former, which enabled tuning the support porosity. Thus, the catalyst prepared with 5 wt% PEG presented a micro-to-mesopores volume ratio of 1, and a good dispersion of Ru nanoparticles, as well as a better stability compared to the catalyst prepared without PEG. The extensive kinetic data collected in this work were mathematically modelled using three different approaches to elucidate the reactant adsorption mode: a non-competitive adsorption model, a non-competitive adsorption model considering the effect of temperature, and a semi-competitive adsorption model. The non-competitive temperature-dependent model displayed better performance in terms of fitting and reliability of the estimated parameters and predicted the adsorption of xylose as an endothermic process. On the other hand, the semi-competitive model gave similar results in terms of fitting and a value for the competitiveness factor of 0.74, which matches the hypothesis that the larger molecules, sugars, can occupy most of the active sites, while some interstitial sites remain accessible for hydrogen adsorption. The modelling results revealed a complex mode of sugar adsorption on the catalyst surface. This modelling concept can be applied to any system in which the molecule sizes are very different.
Electrocatalytic Hydrogenation of Glucose and Xylose on Electrochemically Roughened Metal Catalysts Jay Pee Oña, Rose Marie Latonen, Narendra Kumar, Jan-Erik Eriksson, Ilari Angervo, Henrik Grénman ACS Catalysis, 2023 High Resolution Image Download MS PowerPoint Slide Electrocatalytic hydrogenation (ECH) of glucose and xylose was studied on Ag, Au, Cu, Pt, and Zn polycrystalline metals. The metal catalysts were roughened electrochemically to expose more active sites. Estimates of surface roughness obtained from the determination of electrochemical surface areas (ECSA) were consistent with those obtained from physical measurements (i.e., confocal white light microscopy). The rough Cu catalyst gave the highest selectivity of 21.1% toward sorbitol production for a glucose conversion of 25.7% and the highest xylitol selectivity of 67.1% for a xylose conversion of 30.8%. Aside from hydrogenation products, significant amounts of 2-deoxyxylitol were formed over the Ag and Zn catalysts during xylose ECH. The results obtained demonstrate the dependence of ECH rate and product selectivity on the chemical properties of the metal catalysts. pH studies of ECH reactions show that appreciable yields of sorbitol and xylitol can be achieved at neutral pH (pH 7), with negligible formation of ketose side products. Furthermore, the Faradaic efficiency (FE) toward xylitol formation increased with more negative applied potentials and was highest at −1.0 V (vs RHE), while the maximum FE for sorbitol occurred at a less negative potential (−0.7 V). Therefore, the ECH rate depends not only on the amount of available chemisorbed hydrogen obtained from water splitting reactions but also on the reactivity of the substrate toward ECH. This work provides the basis for improving electrocatalytic systems for ECH of sugars and a step toward efficient valorization of these compounds from versatile biomass sources.
Aqueous Processable One-Dimensional Polypyrrole Nanostructured by Lignocellulose Nanofibril: A Conductive Interfacing Biomaterial Shujun Liang, Wenyang Xu, Liqiu Hu, Ville Yrjänä, Qingbo Wang, Emil Rosqvist, Luyao Wang, Jouko Peltonen, Jessica M. Rosenholm, Chunlin Xu, Rose-Marie Latonen, Xiaoju Wang Biomacromolecules, 2023 One-dimensional (1D) nanomaterials of conductive polypyrrole (PPy) are competitive biomaterials for constructing bioelectronics to interface with biological systems. Synergistic synthesis using lignocellulose nanofibrils (LCNF) as a structural template in chemical oxidation of pyrrole with Fe(III) ions facilitates surface-confined polymerization of pyrrole on the nanofibril surface within a submicrometer- and micrometer-scale fibril length. It yields a core–shell nanocomposite of PPy@LCNF, wherein the surface of each individual fibril is coated with a thin nanoscale layer of PPy. A highly positive surface charge originating from protonated PPy gives this 1D nanomaterial a durable aqueous dispersity. The fibril–fibril entanglement in the PPy@LCNFs facilely supported versatile downstream processing, e.g., spray thin-coating on glass, flexible membranes with robust mechanics, or three-dimensional cryogels. A high electrical conductivity in the magnitude of several to 12 S·cm–1 was confirmed for the solid-form PPy@LCNFs. The PPy@LCNFs are electroactive and show potential cycling capacity, encompassing a large capacitance. Dynamic control of the doping/undoping process by applying an electric field combines electronic and ionic conductivity through the PPy@LCNFs. The low cytotoxicity of the material is confirmed in noncontact cell culture of human dermal fibroblasts. This study underpins the promises for this nanocomposite PPy@LCNF as a smart platform nanomaterial in constructing interfacing bioelectronics.
Electrocatalytic hydrogenation and oxidation of glucose and xylose on mesoporous carbon-supported Au nanocatalysts Jay Pee Oña, Rose-Marie Latonen, Narendra Kumar, Markus Peurla, Ilari Angervo, Henrik Grénman Electrochimica Acta, 2023 Electrocatalytic conversion of hemicellulose-derived glucose and xylose presents a sustainable approach to utilize renewable energy (e.g. solar, wind) to produce value-added chemicals. In this work, the electrochemical hydrogenation and oxidation of glucose and xylose at ambient conditions were studied using dispersed, mesoporous Sibunit Carbon (SC)-supported Au nanocatalysts (SC/AuNPs) with different cluster sizes (4.4 nm, 5.9 nm, 10-30 nm), providing novel results on the cluster size - activity relation. For the electrocatalytic hydrogenation (ECH) of glucose and xylose into sorbitol and xylitol, respectively, higher conversion rates were obtained when more negative potentials were applied. This indicates that the hydrogenation reaction proceeds concurrently with hydrogen evolution reaction (HER). SC/AuNPs with smaller Au clusters were more active towards glucose or xylose ECH at all potentials applied. The selectivity (Faradaic efficiency) increased towards more negative potentials for glucose ECH but followed an opposite trend for xylose ECH. Analysis using in-situ FTIR-ATR spectroscopy showed that water adsorption which leads to HER, was more extensive in xylose solution than in glucose solution at lower potentials. This would indicate greater inhibition of xylose ECH than glucose ECH at more negative potentials. The electrocatalytic oxidation (ECO) of glucose and xylose to gluconic acid and xylonic acid, respectively, was observed to occur at -0.05, +0.3, and +0.4 V (vs Ag/AgCl) using the present electrocatalytic set up. Constant-potential electrolysis at these potentials showed differences in ECO rate depending on the applied potential and average Au cluster size. The highest glucose and xylose ECO rate was obtained for the SC/AuNPs with the smallest average Au cluster size (4.4 nm) at +0.3 V. Constant-potential electrolysis of the sugars at +0.3 V using this catalyst resulted in 42 % yield of gluconic acid and 32 % yield of xylonic acid in 6 hours, both with a very low Au loading of 0.08 % wt.. These results show the strong influence of Au cluster size on the catalytic activities of SC/AuNPs toward sugar ECH or ECO.
Erosive potential of ice tea beverages and kombuchas Elisa Lind, Hilma Mähönen, Rose-Marie Latonen, Lippo Lassila, Marja Pöllänen, Vuokko Loimaranta, Merja Laine Acta Odontologica Scandinavica, 2023 Objectives Kombuchas and other tea-based beverages are often perceived as healthy products despite the lack of knowledge on their effects on oral health. This in vitro study determined the erosive potential of commercial kombuchas, and ice teas compared to cola drinks. Materials and methods The pH and fluoride content of 7 kombuchas and 18 tea drinks were measured with ion-selective electrodes. Calcium dissolution from hydroxyapatite grains was quantified by atomic absorption spectroscopy after beverage exposure. The effect of beverages on the enamel surface was visualized by scanning electron microscopy (SEM). Distilled water, and cola drinks were used as negative and positive controls. Results The kombuchas exhibited lower pH values (2.82–3.66) than the ice teas (2.94–4.86), but still higher than the cola drinks (2.48–2.54). The fluoride concentration varied between 0.05 and 0.46 ppm and for 7 beverages the concentration was below the detection limit. The calcium release for kombuchas was 198–746 mg/l, for ice teas 16.1–507 mg/l, and for cola drinks 57.7–71.9 mg/l. Twenty-two beverages had a significantly greater calcium release than the cola drinks (p = .009–.014). The surface etching of the enamel was seen in the SEM analysis after beverage exposure. Conclusions Tea-based beverages have even higher erosive potential than cola drinks. Kombuchas especially, displayed a considerable erosive potential.
Shear exfoliated few-layer graphene and cellulose nanocrystal composite as biocompatible anode with efficient charge transfer Sara Lund, Elisabeth Björnvik, Qingbo Wang, Xiaoju Wang, Sindhujaa Vajravel, Laura T. Wey, Yagut Allahverdiyeva, Jussi Kauppila, Jan-Henrik Smått, Jouko Peltonen, Rose-Marie Latonen, Tom Lindfors Carbon Trends, 2022 Electroconductive composites of graphene and cellulose nanocrystals (CNC) were prepared by direct exfoliation of natural flake graphite in CNC suspensions. Using the scalable high-shear exfoliation method, we show that the environmentally friendly CNC is an excellent graphene stabilizer as we prepared aqueous graphene-CNC dispersions with a high concentration (4.0 mg ml−1) and yield (4.0%) after only 2 h exfoliation time. With this fast and facile method, we exfoliated graphite using CNC with different amounts of negatively charged sulfate ester groups. We found that the graphene concentration is proportional to zeta potential of the CNC suspension suggesting that electrostatic repulsion plays a key role in graphene stabilization. Albeit the insulating nature of CNC, the spray-coated composite films were electrically conductive with conductivity up to 280 S m−1, depending on the CNC amount. Cyclic voltammetry measurements showed a reversible redox response for the Fe(CN)63-/4− couple proving that the electron transfer was efficient in the composite film. Furthermore, biocompatibility studies with photosynthetic microorganisms revealed no toxic effects as the cells maintained their photosynthetic performance and growth when placed in direct contact with the composite. The cytocompatibility, electroactivity and good water-stability make the composite film a promising anode for bioelectrochemical applications.
Electrocatalytic hydrogenation of glucose and xylose using carbon fiber supported Au nanocatalysts Jay Pee Oña, Rose-Marie Latonen, Narendra Kumar, Markus Peurla, Ilari Angervo, Henrik Grénman Electrochimica Acta, 2022 Recent evidences have shown catalyst structure sensitivity of electrocatalytic hydrogenation (ECH) of organic molecules in aqueous phase. In this study, ECH of glucose and xylose was investigated using gold nanoparticles (AuNPs) on activated carbon fiber (CF) support as catalyst. CF supported AuNPs catalysts (CF/AuNPs) were synthesized by deposition-precipitation method and were characterized by physicochemical (SEM, TEM, XRD, N2 physisorption, ICP-OES) and electrochemical methods. Chemical or thermal pre-treatment of CF prior to Au deposition resulted in different AuNPs size distributions. The activity towards glucose or xylose ECH were observed to be dependent on the particle size of AuNPs and the applied potential. Compared to a polycrystalline Au catalyst, higher reaction rates for glucose and xylose ECH were observed for a CF/AuNPs catalyst with a higher surface area. This indicates that the activity of Au towards glucose and xylose ECH is dependent on the surface area and particle size, and particle size control can be achieved by simple chemical or thermal pretreatment of the catalyst support.
Electrochemical study on the growth of multilayer film electrodes of the conducting polymers PPP, POT and of the copolymer of PPP and POT Materials Research Society Symposium Proceedings, 1997
RECENT SCHOLAR PUBLICATIONS
Graphene nanoplatelet-chitosan coated melamine foam with Janus structure for solar steam generation MS Zafar, M Vocciante, J Bobacka, RM Latonen, H Grénman Separation and Purification Technology, 137426 , 2026 2026
Sustainable Energy & Fuels RM Latonen, Y Allahverdiyeva 2024
Influence of reaction parameters on nanogold-catalyzed glucose and xylose oxidation: a joint experimental and DFT study JP Oña, L Laverdure, RM Latonen, N Kumar, M Peurla, I Angervo, ... ACS Catalysis 14 (3), 1532-1544 , 2024 2024 Citations: 14
Graphene and graphene–cellulose nanocrystal composite films for sustainable anodes in biophotovoltaic devices S Lund, LT Wey, J Peltonen, J Bobacka, RM Latonen, Y Allahverdiyeva Sustainable Energy & Fuels 8 (2), 210-224 , 2024 2024 Citations: 13
Kinetic studies of solid foam catalysts for the production of sugar alcohols: Xylitol from biomass resources G Araujo-Barahona, A Goicoechea-Torres, K Eränen, RM Latonen, T Tirri, ... Chemical Engineering Science 281, 119130 , 2023 2023 Citations: 7
Electrocatalytic hydrogenation of glucose and xylose on electrochemically roughened metal catalysts JP Ona, RM Latonen, N Kumar, JE Eriksson, I Angervo, H Grénman ACS Catalysis 13 (21), 14300-14313 , 2023 2023 Citations: 17
Erosive potential of ice tea beverages and kombuchas E Lind, H Mähönen, RM Latonen, L Lassila, M Pöllänen, V Loimaranta, ... Acta Odontologica Scandinavica 81 (6), 491-498 , 2023 2023 Citations: 10
Aqueous processable one-dimensional polypyrrole nanostructured by lignocellulose nanofibril: a conductive interfacing biomaterial S Liang, W Xu, L Hu, V Yrjana, Q Wang, E Rosqvist, L Wang, J Peltonen, ... Biomacromolecules 24 (8), 3819-3834 , 2023 2023 Citations: 9
Electrocatalytic hydrogenation and oxidation of glucose and xylose on mesoporous carbon-supported Au nanocatalysts JP Oña, RM Latonen, N Kumar, M Peurla, I Angervo, H Grénman Electrochimica Acta 437, 141536 , 2023 2023 Citations: 30
Shear exfoliated few-layer graphene and cellulose nanocrystal composite as biocompatible anode with efficient charge transfer S Lund, E Björnvik, Q Wang, X Wang, S Vajravel, LT Wey, ... Carbon Trends 9, 100210 , 2022 2022 Citations: 9
Electrocatalytic hydrogenation of glucose and xylose using carbon fiber supported Au nanocatalysts JP Ona, RM Latonen, N Kumar, M Peurla, I Angervo, H Grénman Electrochimica Acta 426, 140754 , 2022 2022 Citations: 19
Carbon Trends S Lund, E Björnvik, Q Wang, X Wang, S Vajravel, LT Wey, ... 2022
Electrocatalytic Hydrogenation of Glucose and Xylose on Highly Dispersed Carbon Fiber Supported AU Nanocatalysts JP Oña, RM Latonen, N Kumar, M Peurla, I Angervo, H Grenman Available at SSRN 4046333 , 2022 2022 Citations: 1
Fast high-shear exfoliation of natural flake graphite with temperature control and high yield S Lund, J Kauppila, S Sirkiä, J Palosaari, O Eklund, RM Latonen, ... Carbon 174, 123-131 , 2021 2021 Citations: 81
Highly sensitive and stable fructose self-powered biosensor based on a self-charging biosupercapacitor P Bollella, Z Boeva, RM Latonen, K Kano, L Gorton, J Bobacka Biosensors and Bioelectronics 176, 112909 , 2021 2021 Citations: 42
Multilayer and surface immobilization of EDOT-decorated nanocapsules E Lindner, BP Hambly, CK Sears, M Guzinski, F Perez, RM Latonen, ... Langmuir , 2021 2021 Citations: 1
Multilayer and Surface Immobilization of EDOT-Decorated Nanocapsules BP Hambly, CK Sears, M Guzinski, F Perez, RM Latonen, J Bobacka, ... Langmuir 37 (1), 499-508 , 2020 2020 Citations: 1
Electrospinning of Electroconductive Water-Resistant Nanofibers of PEDOT–PSS, Cellulose Nanofibrils and PEO: Fabrication, Characterization, and Cytocompatibility RM Latonen, JAW Cabrera, S Lund, S Kosourov, S Vajravel, Z Boeva, ... ACS Applied Bio Materials 4 (1), 483-493 , 2020 2020 Citations: 32
The flake graphite prospect of Piippumäki—an example of a high-quality graphite occurrence in a retrograde metamorphic terrain in Finland J Palosaari, RM Latonen, JH Smått, S Raunio, O Eklund Mineralium Deposita 55 (8), 1647-1660 , 2020 2020 Citations: 29
Silver (I)-selective electrodes based on rare earth element double-decker porphyrins NK Joon, JE Barnsley, R Ding, S Lee, RM Latonen, J Bobacka, ... Sensors and Actuators B: Chemical 305, 127311 , 2020 2020 Citations: 41
MOST CITED SCHOLAR PUBLICATIONS
Biocomposites of nanofibrillated cellulose, polypyrrole, and silver nanoparticles with electroconductive and antimicrobial properties P Bober, J Liu, KS Mikkonen, P Ihalainen, M Pesonen, C Plumed-Ferrer, ... Biomacromolecules 15 (10), 3655-3663 , 2014 2014 Citations: 131
Pre-polarized hydrophobic conducting polymer solid-contact ion-selective electrodes with improved potential reproducibility N He, S Papp, T Lindfors, L Hofler, RM Latonen, RE Gyurcsányi Analytical chemistry 89 (4), 2598-2605 , 2017 2017 Citations: 104
Electrochemical synthesis of poly (3, 4-ethylenedioxythiophene) in aqueous dispersion of high porosity reduced graphene oxide T Lindfors, ZA Boeva, RM Latonen RSC advances 4 (48), 25279-25286 , 2014 2014 Citations: 86
Fast high-shear exfoliation of natural flake graphite with temperature control and high yield S Lund, J Kauppila, S Sirkiä, J Palosaari, O Eklund, RM Latonen, ... Carbon 174, 123-131 , 2021 2021 Citations: 81
Improved charging/discharging behavior of electropolymerized nanostructured composite films of polyaniline and electrochemically reduced graphene oxide T Lindfors, RM Latonen Carbon 69, 122-131 , 2014 2014 Citations: 67
Electrochemical synthesis of a copolymer of poly (3-octylthiophene) and poly (paraphenylene) RM Latonen, C Kvarnström, A Ivaska Electrochimica Acta 44 (12), 1933-1943 , 1999 1999 Citations: 44
Conducting ink based on cellulose nanocrystals and polyaniline for flexographical printing RM Latonen, A Määttänen, P Ihalainen, W Xu, M Pesonen, M Nurmi, C Xu Journal of Materials Chemistry C 5 (46), 12172-12181 , 2017 2017 Citations: 43
Highly sensitive and stable fructose self-powered biosensor based on a self-charging biosupercapacitor P Bollella, Z Boeva, RM Latonen, K Kano, L Gorton, J Bobacka Biosensors and Bioelectronics 176, 112909 , 2021 2021 Citations: 42
Silver (I)-selective electrodes based on rare earth element double-decker porphyrins NK Joon, JE Barnsley, R Ding, S Lee, RM Latonen, J Bobacka, ... Sensors and Actuators B: Chemical 305, 127311 , 2020 2020 Citations: 41
The sequential injection system with adsorptive stripping voltammetric detection WW Kubiak, RM Latonen, A Ivaska Talanta 53 (6), 1211-1219 , 2001 2001 Citations: 40
In situ UV–vis and FTIR attenuated total reflectance studies on the electrochemically synthesized copolymer from biphenyl and 3-octylthiophene RM Latonen, C Kvarnström, A Ivaska Journal of Electroanalytical Chemistry 512 (1-2), 36-48 , 2001 2001 Citations: 39
Influence of hydrophobization of the polyazulene ion-to-electron transducer on the potential stability of calcium-selective solid-contact electrodes N He, L Höfler, RM Latonen, T Lindfors Sensors and Actuators B: Chemical 207, 918-925 , 2015 2015 Citations: 37
Electrochemical characterization of poly (3, 4-ethylenedioxythiophene)(PEDOT) doped with sulfonated thiophenes Z Mousavi, T Alaviuhkola, J Bobacka, RM Latonen, J Pursiainen, A Ivaska Electrochimica Acta 53 (11), 3755-3762 , 2008 2008 Citations: 35
Electrochemically controlled ion transport across polypyrrole/multi-walled carbon nanotube composite membranes MN Akieh, RM Latonen, S Lindholm, SF Ralph, J Bobacka, A Ivaska Synthetic metals 161 (17-18), 1906-1914 , 2011 2011 Citations: 34
Electrochemically controlled transport of anions across polypyrrole-based membranes J Arroyo, M Akieh-Pirkanniemi, G Lisak, RM Latonen, J Bobacka Journal of Membrane Science 581, 50-57 , 2019 2019 Citations: 33
Electrocatalytic oxidation of cellulose at a gold electrode Y Sugano, RM Latonen, M Akieh‐Pirkanniemi, J Bobacka, A Ivaska ChemSusChem 7 (8), 2240-2247 , 2014 2014 Citations: 33
Electrospinning of Electroconductive Water-Resistant Nanofibers of PEDOT–PSS, Cellulose Nanofibrils and PEO: Fabrication, Characterization, and Cytocompatibility RM Latonen, JAW Cabrera, S Lund, S Kosourov, S Vajravel, Z Boeva, ... ACS Applied Bio Materials 4 (1), 483-493 , 2020 2020 Citations: 32
Electrocatalytic hydrogenation and oxidation of glucose and xylose on mesoporous carbon-supported Au nanocatalysts JP Oña, RM Latonen, N Kumar, M Peurla, I Angervo, H Grénman Electrochimica Acta 437, 141536 , 2023 2023 Citations: 30
The flake graphite prospect of Piippumäki—an example of a high-quality graphite occurrence in a retrograde metamorphic terrain in Finland J Palosaari, RM Latonen, JH Smått, S Raunio, O Eklund Mineralium Deposita 55 (8), 1647-1660 , 2020 2020 Citations: 29
Direct Electron Transfer of Trametes hirsuta Laccase in a Dual-Layer Architecture of Poly(3,4-ethylenedioxythiophene) Films X Wang, RM Latonen, P Sjoberg-Eerola, JE Eriksson, J Bobacka, H Boer, ... The Journal of Physical Chemistry C 115 (13), 5919-5929 , 2011 2011 Citations: 28