Corrosion inhibition of mild steel using parinari polyandra leave extracts in diluted hydrochloric acids F O Nwosu, S O Amusat Portugaliae Electrochimica Acta, 2021 Metallic materials remain an indispensable element in industries. The present study is aimed at the assessment of Parinari polyandra leaves inhibition properties on mild steel in a 1 M HCl solution. This was investigated using gravimetric and electrochemical methods. Physicochemical and spectroscopic analyses of the leaves extract were done using standard methods. A yield of 19.82% was obtained, while the leaves extract FTIR spectra showed bands of 3404 cm -1 and 2926 cm -1 , which indicated the presence of a strong band of phenolic O-H and C-H stretch functional groups, respectively. A maximum corrosion inhibition efficiency of 97.22% was obtained. Langmuir adsorption isotherm fitted the inhibitor data well. From electrochemical methods, the corrosion rate value of 17.626 mmpy obtained for the uninhibited mild steel was higher than 0.02044 – 2.2267 mmpy range values recorded for the mild steel surface covered with P. polyandra leaves extract in an acidic medium. SEM images showed the leaves extract inhibition effect against mild steel corrosion in a 1 M HCl solution. Electrochemical analysis using the Tafel plot also showed the leaves extract corrosion inhibition capacity, suggesting a mixed type inhibitor. Thus, P. polyandra leaves extract might act as a green corrosion inhibitor for mild steel utilized in industrial applications.
Mild steel corrosion inhibition in a NaCl solution by lignin extract of chromolaena odorata M M Muzakir, F O Nwosu, S O Amusat Portugaliae Electrochimica Acta, 2019 The inhibitive action of Chromolaena odorata stems extract, in various concentrations, against mild steel corrosion in a 1 M NaCl solution , was studied using weight loss, potentiodynamic polarization methods and scanning e lectron microscopy. Maximum inhibition efficiency of 99.83 % was obtained, at 3 03 K, for an extract concentration of 3000 mgL. The activation and free energies for the inhibiti on reactions supported the physical adsorption mechanism. The extract adsorpti on onto the mild steel surface was found to be exothermic, spontaneous, and to obey th e Langmuir adsorption model. FTIR analysis showed the presence of hydroxyl (OH) an d carbonyl(C=O) functional groups and aromatic rings in lignin, which are the binding groups that might be responsible for lignin’s inhibitive action against mild steel corrosion. Furthermore, SEM analysis revealed that the mild steel surface was a ffected by lignin’s adsorption, due to the formation of a protective film.
Thermodynamic and adsorption studies of corrosion inhibition of mild steel using lignin from siam weed (chromolaena odorata) in acid medium Journal of Materials and Environmental Science, 2016
The potential of Terminalia catappa (Almond) and Hyphaene thebaica (Dum palm) fruits as raw materials for livestock feed African Journal of Biotechnology, 2008
Anti-fungal activities of m-iodobenzoic acid and some of its metal derivatives on bread mucor Bulletin of the Chemical Society of Ethiopia, 2005
Comparison of some preconcentration methods for certain metal ions in human milk and yogurts Bulletin of the Chemical Society of Ethiopia, 2003
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MOST CITED SCHOLAR PUBLICATIONS
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The potential of Terminalia catappa (Almond) and Hyphaene thebaica (Dum palm) fruits as raw materials for livestock feed FO Nwosu, OO Dosumu, JOC Okocha African journal of Biotechnology 7 (24) , 2008 2008 Citations: 85
Thermodynamic and adsorption studies of corrosion inhibition of mild steel using lignin from siam weed (Chromolaena odorata) in acid medium FO Nwosu, MM Muzakir J. Mater. Environ. Sci 7 (5), 1663-1673 , 2016 2016 Citations: 49
Adsorption of atrazine from aqueous solution using unmodified and modified bentonite clays OJ Ajala, FO Nwosu, RK Ahmed Applied water science 8 (7), 214 , 2018 2018 Citations: 33
Antimicrobial studies and phytochemical screening of extracts of Hyphaene thebaica (Linn) Mart fruits. OO Dosumu, FO Nwosu, CD Nwogu 2006 Citations: 33
Comparative study of the constituents of the fruits pulps and seeds of Canarium ovatum, Persea americana and Dacryodes edulis OOOFONCM OKOYE Jordan Journal of Chemistry (JJC) 12 (2), 113-125 , 2017 2017 Citations: 30
Mild steel corrosion inhibition in a NaCl solution by lignin extract of Chromolaena odorata MM Muzakir, FO Nwosu, SO Amusat Sociedade Portuguesa de Electroquímica , 2019 2019 Citations: 28
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Comparative investigation of wear metals in virgin and used lubricant oils FO Nwosu, BI Olu-Owolabi, KO Adebowale, L Leke Terrestrial and Aquatic Environmental Toxicology 2 (1), 38-43 , 2008 2008 Citations: 13
Phytochemical screening and anti-microbial studies of extracts of Hyphaene thebaica linn (Mart) Palmae OO Dosumu, FO Nwosu, CJ Nwogu Int. J. Trop. Med 1 (4), 186-189 , 2006 2006 Citations: 12
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Comparison of Some Pre Concentration methods for certain Metal ions in Human Milk and Yoghurts. FAIE Nwosu, F.O., Adekola Bulletin Chemical Society of Ethiopia. 17 (1), 1 – 9 , 2003 2003 Citations: 11
Heavy metals and macronutrients content in selected herbal plants of South-Western Nigeria. AA Lasisi, BC Ejelonu, FO Nwosu, MA Olayiwola, AA Yusuff 2006 Citations: 10
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Removal of anthracene from solution using [Cu(INA)2] metal – organic frame work synthesized by a sol solvent free method. AC Tella, FO Nwosu, SE Elaigwu, CP Ezeh, VO Adimula Nigerian Journal of Materials Science and Engineering 7 (1.), 26 - 34 , 2016 2016 Citations: 8