Synthesis, characterization and biological activity of binuclear palladium(II) complexes Debakanta Tripathy, Soumya Lipsa Rath, Niladri Bihari Debata, Dillip Kumar Chand Results in Chemistry, 2025 Two N,N,N′,N′ -tetramethylethylenediamine (tmeda) protected palladium(II) complexes 1 and 2 were synthesized using two amide functionalized ligands L1 and L2 respectively. Complexes 1 and 2 were characterized by 1 H, 13 C NMR, H H COSY, C H COSY and ESI-MS. Molecular structures of both the complexes were confirmed by single crystal X-ray diffraction of analogous complexes 1′ and 2′. Molecular packing in the crystal lattice was evaluated using Hirshfeld surface analysis. It was found that the H…H interaction is the major contributor to the molecular packing in complex 1′. However, in complex 2′, O…H/H…O short contact is the major stabilising factor of the crystal lattice. The biological activity of complexes 1′ and 2′ were evaluated using molecular docking tool. Both the complexes were found to interact with MexB protein and complex 2′ having higher binding affinity as evident from the binding energy values. • Two cis-proctected palladium(II) complexes were synthesized and characterized by NMR and ESI-MS. • Molecular structure was established by single crystal X-ray diffraction technique. • Intermolecular interactions in the crystal lattice were evaluated by Hirshfeld surface analysis. • Interaction of the complexes with MeXB protein was examined using molecular docking tool.
A discrete Cu2(Pd-bpy)2L2heterometallic compound with superoxide dismutase enzyme like activity Soumya Mishra, Biswaranjan Paital, Himansu Sekhar Sahoo, Samar Gaurav Pati, Debakanta Tripathy, Niladri Bihari Debata Dalton Transactions, 2020 An aqueous soluble discrete heterometallic compound consisting of Cu(ii) and Pd(ii) units with SOD mimicking activity has been demonstrated.
Synthesis, characterization and biological activity of binuclear palladium (II) complexes D Tripathy, SL Rath, NB Debata, DK Chand Results in Chemistry 15, 102310 , 2025 2025.0
Platinum (II) based macrocyclic host for recognition of aromatic hydrocarbons D Tripathy, SL Rath, NB Debata, AK Pal, DK Chand, GS Hanan Journal of Molecular Structure 1292, 136104 , 2023 2023.0 Citations: 3
Coordination driven discrete metallopolygons and cages from unsymmetric bidentate ligands D Tripathy, NB Debata, KC Naik, HS Sahoo Coordination Chemistry Reviews 456, 214396 , 2022 2022.0 Citations: 40
Artificial superoxide dismutase for cosmetic therapy and industrial use NB Debata, HS Sahoo, B Paital Academia Letters, 1-5 , 2021 2021.0 Citations: 5
A discrete Cu 2 (Pd-bpy) 2 L 2 heterometallic compound with superoxide dismutase enzyme like activity S Mishra, B Paital, HS Sahoo, SG Pati, D Tripathy, NB Debata Dalton Transactions 49 (26), 8850-8854 , 2020 2020.0 Citations: 7
Development of coordination driven self-assembled discrete spherical ensembles NB Debata, D Tripathy, HS Sahoo Coordination Chemistry Reviews 387, 273-298 , 2019 2019.0 Citations: 71
One-pot synthesis of self-assembled heteroleptic palladium (II) complexes with tmeda: An application of ligand exchange reactions S Bandi, NB Debata, V Ramkumar, DK Chand Inorganic Chemistry Communications 39, 75-78 , 2014 2014.0 Citations: 13
Self-assembled coordination complexes from various palladium (II) components and bidentate or polydentate ligands NB Debata, D Tripathy, DK Chand Coordination Chemistry Reviews 256 (17-18), 1831-1945 , 2012 2012.0 Citations: 207
A model study of alternative approach toward a class of palladium (II) based self-assembly NB Debata, V Ramkumar, DK Chand Inorganica Chimica Acta 372 (1), 71-78 , 2011 2011.0 Citations: 6
Coordination-driven self-assembly in a single pot NB Debata, D Tripathy, V Ramkumar, DK Chand Tetrahedron Letters 51 (33), 4449-4451 , 2010 2010.0 Citations: 20
Development of a targeted siRNA delivery system using FOL-PEG-PEI conjugate BK Biswal, NB Debata, RS Verma Molecular biology reports 37 (6), 2919-2926 , 2010 2010.0 Citations: 45
Influence of cis-protecting groups toward ligand exchange reactions in polynuclear Pd (II)-based coordination cages HS Sahoo, DK Chand, NB Debata Inorganica chimica acta 360 (1), 31-38 , 2007 2007.0 Citations: 13
Isolation, Identification and Evaluation of the Effective Phyto-Compounds for The Management of Groundnut Beetles Infesting Stored Groundnut (Arachis Hypogaea L.) L Chowdhury, M Dash, S Mohapatra, D Mohanty, PK Sahoo, N Debata, ...
LIGAND EXCHANGE REACTIONS AROUND PALLADIUM (II) IONS IN MONONUCLEAR COMPLEXES GENERATED FROM A META-SUBSTITUTED PYRIDINE LIGAND NB Debataa, DK Chanda, HS Sahooa
MOST CITED SCHOLAR PUBLICATIONS
Self-assembled coordination complexes from various palladium (II) components and bidentate or polydentate ligands NB Debata, D Tripathy, DK Chand Coordination Chemistry Reviews 256 (17-18), 1831-1945 , 2012 2012.0 Citations: 207
Development of coordination driven self-assembled discrete spherical ensembles NB Debata, D Tripathy, HS Sahoo Coordination Chemistry Reviews 387, 273-298 , 2019 2019.0 Citations: 71
Development of a targeted siRNA delivery system using FOL-PEG-PEI conjugate BK Biswal, NB Debata, RS Verma Molecular biology reports 37 (6), 2919-2926 , 2010 2010.0 Citations: 45
Coordination driven discrete metallopolygons and cages from unsymmetric bidentate ligands D Tripathy, NB Debata, KC Naik, HS Sahoo Coordination Chemistry Reviews 456, 214396 , 2022 2022.0 Citations: 40
Coordination-driven self-assembly in a single pot NB Debata, D Tripathy, V Ramkumar, DK Chand Tetrahedron Letters 51 (33), 4449-4451 , 2010 2010.0 Citations: 20
One-pot synthesis of self-assembled heteroleptic palladium (II) complexes with tmeda: An application of ligand exchange reactions S Bandi, NB Debata, V Ramkumar, DK Chand Inorganic Chemistry Communications 39, 75-78 , 2014 2014.0 Citations: 13
Influence of cis-protecting groups toward ligand exchange reactions in polynuclear Pd (II)-based coordination cages HS Sahoo, DK Chand, NB Debata Inorganica chimica acta 360 (1), 31-38 , 2007 2007.0 Citations: 13
A discrete Cu 2 (Pd-bpy) 2 L 2 heterometallic compound with superoxide dismutase enzyme like activity S Mishra, B Paital, HS Sahoo, SG Pati, D Tripathy, NB Debata Dalton Transactions 49 (26), 8850-8854 , 2020 2020.0 Citations: 7
A model study of alternative approach toward a class of palladium (II) based self-assembly NB Debata, V Ramkumar, DK Chand Inorganica Chimica Acta 372 (1), 71-78 , 2011 2011.0 Citations: 6
Artificial superoxide dismutase for cosmetic therapy and industrial use NB Debata, HS Sahoo, B Paital Academia Letters, 1-5 , 2021 2021.0 Citations: 5
Platinum (II) based macrocyclic host for recognition of aromatic hydrocarbons D Tripathy, SL Rath, NB Debata, AK Pal, DK Chand, GS Hanan Journal of Molecular Structure 1292, 136104 , 2023 2023.0 Citations: 3
Synthesis, characterization and biological activity of binuclear palladium (II) complexes D Tripathy, SL Rath, NB Debata, DK Chand Results in Chemistry 15, 102310 , 2025 2025.0
Isolation, Identification and Evaluation of the Effective Phyto-Compounds for The Management of Groundnut Beetles Infesting Stored Groundnut (Arachis Hypogaea L.) L Chowdhury, M Dash, S Mohapatra, D Mohanty, PK Sahoo, N Debata, ...
LIGAND EXCHANGE REACTIONS AROUND PALLADIUM (II) IONS IN MONONUCLEAR COMPLEXES GENERATED FROM A META-SUBSTITUTED PYRIDINE LIGAND NB Debataa, DK Chanda, HS Sahooa