Materials Science, Surfaces and Interfaces, Condensed Matter Physics, Chemistry
23
Scopus Publications
398
Scholar Citations
12
Scholar h-index
15
Scholar i10-index
Scopus Publications
Oxygen-Deficient TiO2-Based Dual-Functional Electrochromic Smart Windows: Achieving High Coloration Efficiency and Energy Storage Through Oxygen Defect Engineering Mukhesh K Ganesha, Fuad Seneen, Poornachandra G Kulkarni, Hafis Hakkeem, Ganesha Krishna V S, Kumar Shubham, Ashutosh K Singh Small, 2025 Electrochromic smart windows (ECSWs) have yet to achieve widespread adoption, primarily due to the high cost associated with the exorbitant material used presently. In this study, we explore titanium dioxide (TiO2), a more abundant and cost‐effective alternative, as an electrochromic (EC) material with potential for enhanced performance. We address the issue of TiO2’s low coloration efficiency (CE) by introducing oxygen defects. Using reactive sputtering, we varied the oxygen flow rate during TiO2 deposition, creating oxygen defect concentrations between 29.9% and 41% and interaction of film with different electrolytes, EC, and energy performance was studied. This led to significant improvements in opacity and EC performance, with only 338 nm thick film, the device shows 55%, 47%, and 44% modulation in solar, luminous, and NIR transmittance and the film shows high CE (22.79 and 26.99 cm2 C−1 at 550 and 632 nm, respectively). The film also exhibited excellent dual‐functionality, with an areal capacitance (Ca) of 34 mF cm−2, demonstrating its energy storage capability. The scalability of the process was confirmed by powering a timer display for 11 minutes with a large‐area (25 cm2) ECSW. This work paves the way for affordable, dual‐functional ECSWs, offering a sustainable solution for modern infrastructure applications.
Ultrathin sputtered NiO films for enhanced electrochromic performance in smart windows Ganesha Krishna V. S., Mukhesh K. Ganesha, Chirag Sarthi J., Hafis Hakkeem, Ashutosh K. Singh, Giridhar U. Kulkarni Journal of Materials Chemistry A, 2024 Optimizing ultrathin NiO layers via sputtering to achieve cost-effective and energy-efficient electrochromic smart windows for modern infrastructure and automobile industries.
A review on integration of Zn based buffer layers in II-generation solar cells for enhanced efficiency Ganesha Krishna V S, Seemesh Bhaskar, Mahesha M G Cogent Engineering, 2024 Photon-driven technologies encompass the utility of carefully engineered materials for myriad applications. Over the past decade, thin films of II–VI chalcogenide materials have emerged as versatile candidates for the efficient construction of photovoltaic devices. The buffer layer which serves as a lattice fixer in solar cells plays a role in determining the photon-driven processes between the absorber and the window layers, significantly affecting the performance of the working device. However, mostly used buffer layer, CdS is highly toxic. Recently, there is quest to replace the highly toxic cadmium sulfide (CdS) buffer layers with Zn-based materials to obtain high-efficiency solar cells. Among the II–VI compounds, zinc sulfide (ZnS) and zinc selenide (ZnSe) present promising futuristic scope for research in the photovoltaics field and are recognized as alternatives to the widely used toxic CdS buffer layer. Although significant research has been devoted in this direction, a comprehensive review capturing the latest advancements in photon-driven technologies pertaining to Zn based buffer layers in photovoltaics, has not yet been conducted. In light of these observations, we present a review focusing on the recent progress in the incorporation of Zn based buffer layers into different solar cells constituting CdTe, CIGS, and CZTS. The light matter interactions that depend on the thickness, and the band alignment of the buffer layer with the absorber is discussed in detail.
Assessment of the anharmonic phonon decay, Fröhlich interactions, and phonon lifetime in Zn0.98Mn0.02S thin films through temperature-dependent Raman spectroscopy V S Ganesha Krishna, M G Mahesha Journal of Raman Spectroscopy, 2023 This report accounts for the occurrence of the temperature‐induced variation in the phonon properties and the spatial variation in the Raman spectra for the spray‐deposited Zn0.98Mn0.02S thin films. The study of the temperature dependence of the Raman line position, line width, and the phonon lifetime using the theoretical models that consider the thermal expansion and three‐ and four‐phonon anharmonic effects is the novelty of this work. The lifetime of the LO phonon in Zn0.98Mn0.02S thin film was as low as 0.234 ps, indicating material suitability for optical limiting applications. The intensity ratio I2LO/I1LO ranges within 0.5 at most of the (x, y) positions in the Raman mapping data, indicating the nanocrystalline nature of Zn0.98Mn0.02S.
Spectroscopic valuation of phonon lifetime and surface characteristics of Zn0.96Mg0.04S thin film Ganesha Krishna V S, M. G. Mahesha Journal of Chemical Physics, 2022 The anharmonic properties of the longitudinal optical (LO) phonon mode of Mg-doped ZnS (Zn0.96 Mg0.04S) are investigated using the Balkanski and Klemens models on the temperature-dependent Raman spectra. The variation in the position of the Raman line, peak width, and phonon lifetime with temperature was fitted using three and four phonon decay mechanisms. The values of the anharmonic fitting parameters indicated low anharmonicity. A lifetime of ∼0.17 ps at 90 K indicated a fast phonon decay. In addition, the thin film is analyzed to evaluate its surface characteristics using Raman mapping that showed chemical homogeneity over a large area of the film. Furthermore, we analyzed spatial variations of Raman line intensity, peak area, linewidth, and line position of the LO phonon mode. Raman analysis helped in understanding the phonon–phonon interaction mechanism in Zn0.96 Mg0.04S thin films.
A NEGATIVE DIFFERENTIAL RESISTANCE (NDR) DEVICE AND A METHOD OF MANUFACTURING THERE OF C Kumar, S Majumder, GK V S, SK Sahu IN Patent App. 202,641,048,746 , 2026 2026
An electrochromic device, an anode and processes thereof GU Kulkarni, AK Singh, GK V S, M K G, C Sarthi IN Patent App. 202,341,090,016 , 2025 2025
Oxygen‐Deficient TiO2‐Based Dual‐Functional Electrochromic Smart Windows: Achieving High Coloration Efficiency and Energy Storage Through Oxygen Defect Engineering MK Ganesha, F Seneen, PG Kulkarni, H Hakkeem, G Krishna VS, ... Small, 2500822 , 2025 2025 Citations: 11
A review on integration of Zn based buffer layers in II-generation solar cells for enhanced efficiency G Krishna VS, S Bhaskar, M MG Cogent Engineering 11 (1), 2387260 , 2024 2024 Citations: 6
Ultrathin sputtered NiO films for enhanced electrochromic performance in smart windows GK VS, MK Ganesha, H Hakkeem, AK Singh, GU Kulkarni Journal of Materials Chemistry A 12 (30), 19378-19391 , 2024 2024 Citations: 46
Fast response and multi-color photodetection in p-type Cu: CdS thin films GK VS, P Kumar Materials Advances 5 (4), 1576-1587 , 2024 2024 Citations: 13
Analysis of surface properties of Mg doped ZnS and ZnSe thin films through x-ray photoelectron spectroscopy VSG Krishna, MG Mahesha Journal of Electron Spectroscopy and Related Phenomena 266, 147341 , 2023 2023 Citations: 7
Assessment of the anharmonic phonon decay, Fröhlich interactions, and phonon lifetime in Zn 0.98 Mn 0.02 S thin films through temperature‐dependent Raman … VS Ganesha Krishna, MG Mahesha Journal of Raman Spectroscopy 54 (4), 446-452 , 2023 2023 Citations: 4
(Mg, Mn)-dual doping synergism towards luminescence and electrical properties of ZnO/p-Si heterojunction diodes GK VS, MG Mahesha RSC advances 13 (46), 32282-32295 , 2023 2023 Citations: 9
Investigation on spray deposited Zn based chalcogenide thin films for optoelectronic applications GK V S, M M G http://hdl.handle.net/10603/426897 , 2022 2022
Spectroscopic and electrical analysis of spray deposited copper oxide thin films A Prakash, GK VS, SN Moger, MG Mahesha Materials Today Communications 32, 103926 , 2022 2022 Citations: 26
Spectroscopic valuation of phonon lifetime and surface characteristics of Zn 0.96 Mg 0.04 S thin film. VSG Krishna, MG Mahesha The Journal of Chemical Physics 157 (1), 014703-014703 , 2022 2022 Citations: 3
Analysis of the effect of copper concentration on the structural, spectroscopic, and electrical properties of Cu: ZnO thin films GK VS, MG Mahesha Journal of Alloys and Compounds 899, 163357 , 2022 2022 Citations: 14
Structural, optical, and electrical characterization of spray-deposited Mg 0.02 Zn 0.98 Se thin film for buffer layer application VSG Krishna, MG Mahesha Journal of Materials Science: Materials in Electronics 33 (11), 8529-8533 , 2022 2022 Citations: 4
" ZnS, an excellent material in photonics"-A review based on Z-scan study VS Ganesha Krishna, MG Mahesha Physica B Condensed Matter 628, 413628 , 2022 2022 Citations: 12
Influence of the substrate temperature on the structural, optical, and morphological properties of (1 0 1) oriented ZnSe thin films for window applications in solar cells VSG Krishna, MG Mahesha Materials Today: Proceedings 58, 623-626 , 2022 2022 Citations: 3
Spectroscopic investigation of Cu x Mg 0.2− x Zn 0.8 S ( x = 0, 0.05, 0.10, 0.15) thin films for deep and dilute blue LED applications GK VS, S Chattopadhyay, KP Misra, M MG Luminescence 37 (1), 28-39 , 2022 2022 Citations: 2
n-ZnO/p-CuZnS heterostructure deposited by spray pyrolysis for photosensor application in the UV region VSG Krishna, MG Mahesha Sensors and Actuators A: Physical 332, 113169 , 2021 2021 Citations: 14
XPS analysis of ZnS0. 4Se0. 6 thin films deposited by spray pyrolysis technique GK VS, MG Mahesha Journal of Electron Spectroscopy and Related Phenomena 249, 147072 , 2021 2021 Citations: 51
Role of copper dopant in two-photon absorption and nonlinear optical properties of sprayed ZnS thin films for optical limiting applications GK VS, SR Maidur, PS Patil, MG Mahesha Physics Letters A, 127276 , 2021 2021 Citations: 29
MOST CITED SCHOLAR PUBLICATIONS
XPS analysis of ZnS0. 4Se0. 6 thin films deposited by spray pyrolysis technique GK VS, MG Mahesha Journal of Electron Spectroscopy and Related Phenomena 249, 147072 , 2021 2021 Citations: 51
Ultrathin sputtered NiO films for enhanced electrochromic performance in smart windows GK VS, MK Ganesha, H Hakkeem, AK Singh, GU Kulkarni Journal of Materials Chemistry A 12 (30), 19378-19391 , 2024 2024 Citations: 46
Characterization of transparent p-type Cu: ZnS thin films grown by spray pyrolysis technique VSG Krishna, MG Mahesha Journal of Alloys and Compounds 848, 156568 , 2020 2020 Citations: 37
Thickness optimization of ZnO/CdS/CdTe solar cell by numerical simulation D Parashar, VSG Krishna, SN Moger, R Keshav, MG Mahesha Transactions on Electrical and Electronic Materials 21 (6), 587-593 , 2020 2020 Citations: 33
Role of copper dopant in two-photon absorption and nonlinear optical properties of sprayed ZnS thin films for optical limiting applications GK VS, SR Maidur, PS Patil, MG Mahesha Physics Letters A, 127276 , 2021 2021 Citations: 29
Spectroscopic and electrical analysis of spray deposited copper oxide thin films A Prakash, GK VS, SN Moger, MG Mahesha Materials Today Communications 32, 103926 , 2022 2022 Citations: 26
Characterization of spray deposited ternary ZnSxSe (1-x) thin films for solar cell buffers GK VS, MG Mahesha Surfaces and interfaces 20, 100509 , 2020 2020 Citations: 26
Enhanced optical nonlinearity in sprayed Mn doped ZnS thin films VSG Krishna, SR Maidur, PS Patil, MG Mahesha Chemical Physics Letters 750, 137457 , 2020 2020 Citations: 22
Analysis of the effect of copper concentration on the structural, spectroscopic, and electrical properties of Cu: ZnO thin films GK VS, MG Mahesha Journal of Alloys and Compounds 899, 163357 , 2022 2022 Citations: 14
n-ZnO/p-CuZnS heterostructure deposited by spray pyrolysis for photosensor application in the UV region VSG Krishna, MG Mahesha Sensors and Actuators A: Physical 332, 113169 , 2021 2021 Citations: 14
Absence of Mn emission in MnxZn (1-x) S thin films grown by spray pyrolysis technique GK VS, MG Mahesha Journal of Luminescence 230, 117716 , 2021 2021 Citations: 14
Fast response and multi-color photodetection in p-type Cu: CdS thin films GK VS, P Kumar Materials Advances 5 (4), 1576-1587 , 2024 2024 Citations: 13
" ZnS, an excellent material in photonics"-A review based on Z-scan study VS Ganesha Krishna, MG Mahesha Physica B Condensed Matter 628, 413628 , 2022 2022 Citations: 12
Sprayed nanocrystalline ZMS thin films for nonlinear optical device applications GK VS, PS Patil, SR Maidur, MG Mahesha Optical Materials 96, 109304 , 2019 2019 Citations: 12
Oxygen‐Deficient TiO2‐Based Dual‐Functional Electrochromic Smart Windows: Achieving High Coloration Efficiency and Energy Storage Through Oxygen Defect Engineering MK Ganesha, F Seneen, PG Kulkarni, H Hakkeem, G Krishna VS, ... Small, 2500822 , 2025 2025 Citations: 11
(Mg, Mn)-dual doping synergism towards luminescence and electrical properties of ZnO/p-Si heterojunction diodes GK VS, MG Mahesha RSC advances 13 (46), 32282-32295 , 2023 2023 Citations: 9
Analysis of surface properties of Mg doped ZnS and ZnSe thin films through x-ray photoelectron spectroscopy VSG Krishna, MG Mahesha Journal of Electron Spectroscopy and Related Phenomena 266, 147341 , 2023 2023 Citations: 7
A review on integration of Zn based buffer layers in II-generation solar cells for enhanced efficiency G Krishna VS, S Bhaskar, M MG Cogent Engineering 11 (1), 2387260 , 2024 2024 Citations: 6
Assessment of the anharmonic phonon decay, Fröhlich interactions, and phonon lifetime in Zn 0.98 Mn 0.02 S thin films through temperature‐dependent Raman … VS Ganesha Krishna, MG Mahesha Journal of Raman Spectroscopy 54 (4), 446-452 , 2023 2023 Citations: 4
Structural, optical, and electrical characterization of spray-deposited Mg 0.02 Zn 0.98 Se thin film for buffer layer application VSG Krishna, MG Mahesha Journal of Materials Science: Materials in Electronics 33 (11), 8529-8533 , 2022 2022 Citations: 4