The Influence of Plasma Spraying Process Parameters on Microstructure and Selected Properties of Novel NiCrAl-Cr3C2 Composite Coating Tadeusz Kubaszek, Barbara Kościelniak, Marek Góral, Weronika Głód Solid State Phenomena, 2026 The paper presents a new concept of a thermally sprayed composite coating obtained by mixing NiCrAl powder with chromium carbide Cr₃C₂ in an amount of approximately 30 wt.%. The aim of the research was to obtain a material combining the advantages of a metallic matrix and a ceramic phase, with increased resistance to wear and erosion. The plasma spraying (APS) process was carried out on a carbon steel substrate with variable technological parameters: arc current intensity (300/500/700 A) and hydrogen flow (4/8/12 NLPM), while maintaining the other conditions constant.The thickness, porosity, microstructure, chemical composition (using the EDS method), hardness, erosion resistance, and tribological wear of the coatings were evaluated. The results showed that the greatest thickness (approx. 150 µm) and lowest porosity (below 3 vol. %) were obtained at the maximum process parameters – 700 A and 12 NLPM. In turn, the thinnest and most irregular coating (approx. 70 µm) was obtained at the lowest hydrogen flow (4 NLPM), which was due to insufficient melting of the powder particles.Increasing the current intensity and hydrogen flow had a beneficial effect on all analyzed coating properties – especially hardness (up to 273.7 HV0.2), erosion resistance (the smallest mass loss of 0.007 g), and tribological wear resistance (the smallest volume loss of 2.925 mm³). A decrease in any of the parameters resulted in a deterioration of the layer properties. The optimal mechanical and structural properties of the NiCrAl + Cr₃C₂ composite coating were achieved at the maximum plasma spraying parameters: a power current of 700 A and a hydrogen flow rate of 12 NLPM.
Examination of Conductive WC-Ni and Thermal Barrier Coatings Using an Eddy Current Probe Grzegorz Tytko, Tadeusz Kubaszek, Marek Góral, Bo Feng, Yating Yu Applied Sciences Switzerland, 2025 In many industrial applications, engine, turbine, and rotor components are coated with thin layers that protect them from corrosion, high temperatures, or pressure. This paper presents a fast and effective method for testing such protective coatings. For this purpose, an eddy current probe consisting of a single coil was designed and constructed. The high sensitivity of the probe was achieved by using a pot core, which significantly reduced magnetic flux losses. In addition to the substrate, the test samples also contained carbide coatings or thermal barrier coatings (TBCs), which were sprayed with an Axial III triple-plasma torch or a single-electrode torch. The use of different process parameters made it possible to obtain coatings of varying thickness, which were determined using a scanning electron microscope (SEM). Measurements of the probe impedance components were performed in the frequency range from 500 Hz to 50 kHz. In all cases, based on the analysis of changes in resistance and reactance, it was possible to distinguish each of the tested samples. Even slight changes in thickness of only 9 μm caused significant changes in probe impedance, enabling effective testing of carbide coatings and TBCs.
Effect of Ti Doping of Al0.7CoCrFeNi-Based High Entropy Alloys on Their Erosion Resistance by Solid Particles Wojciech J. Nowak, Tadeusz Kubaszek, Andrzej Gradzik, Małgorzata Grądzka-Dahlke, Dariusz Perkowski, Marzena Tokarewicz, Mariusz Walczak, Mirosław Szala Materials, 2025 The erosion resistance of materials against solid particles is a very important property, especially in the transportation of powders or in aeronautics (dust inside jet engines). There is a strong need to introduce new materials that have higher solid particle erosion resistance than state-of-the-art materials. Thus, in the present work, the solid erosion particles of high entropy alloys (HEAs) based on the Al0.7CoCrFeNi matrix were studied compared to the state-of-the-art stainless steel AISI 304. Furthermore, the effect of the addition of Ti to HEAs on hardness and erosion resistance was investigated. Current research included the development of the chemical composition of a new kind of HEA designed on the basis of thermodynamical calculations performed in CALPHAD, its manufacturing, full characterization involving microstructural and phase analyses, hardness measurements, solid particle erosion tests, and finally, the elucidation of erosion mechanisms. It was found that HEAs showed higher hardness as well as erosion resistance than AISI 304. Moreover, it was found that the increase in Ti content in an HEA resulted in an increase in the hardness and resistance to the erosion of the studied HEA. As the main reason for this phenomenon, the stabilization of the β-BCC phase, suppression of the α-FCC phase, and the appearance of the Ni3Ti phase in the studied HEA were claimed.
Thermal Conductivity of Sustainable Earthen Materials Stabilized by Natural and Bio-Based Polymers: An Experimental and Statistical Analysis Rizwan Shoukat, Marta Cappai, Giorgio Pia, Tadeusz Kubaszek, Roberto Ricciu, Łukasz Kolek, Luca Pilia Energies, 2025 The natural and sustainable ability of earthen building materials makes them highly valuable. Bio-stabilization involves using biological materials or processes in earthen construction to enhance the performance and characteristics of earthen materials. The main objective of bio-stabilization is to substitute high-energy-intensive building materials with more green, thermally efficient substitutions, ultimately reducing indirect emissions. The large-scale use of earth presents a viable alternative due to its extensive availability and, more importantly, its low embodied energy. The aim of this work is to investigate the thermal conductivity of earth stabilized with Opuntia Ficus-Indica (OFI), a natural biopolymer, and to assess how these properties vary based on mix design. A comparative analysis is performed to evaluate the thermal performance of bio-based polymer-stabilized earthen materials (S-30, S-40, D-30, and D-40) alongside natural biopolymer-stabilized earth (OFI-30 and OFI-40) under dry conditions, employing an experimental method. A scanning electron microscope was employed to examine the microstructure of bio-stabilized earthen materials from the samples. Statistical analysis was conducted on the collected data using ANOVA with a significance level of 0.05. The Tukey test was applied to identify specific mean pairings that demonstrate significant differences in the characteristics of the mixtures at each replacement level, maintaining a confidence interval of 95%. The experimental and statistical findings reveal that the OFI-30, D-40, and S-40 mixtures exhibit strong bonding with earthen materials and high thermal performance compared to all other mix designs in environmental samples. Additionally, these mix designs show further improvement in thermal performance in the dry conditions.
TBC SYSTEMS FOR HIGH MELTING POINT METALS AND ALLOYS Grzegorz MOSKAL, Agata DUDEK, Marta MIKUŚKIEWICZ, Tadeusz KUBASZEK, Mirosław TUPAJ, Ernest SZAJNA, Igor MOSKAL Metal International Conference on Metallurgy and Materials Conference Proceedings, 2025 The article presents research findings on the microstructural studies of thermal barrier coatings (TBC) deposited on molybdenum, featuring a bond coat made of molybdenum silicide.Ceramic coatings within the TBC system were produced through plasma spraying in air.Conventional 8YSZ and rare-earth zirconate powders (lanthanum and neodymium zirconates) were utilized to achieve this.The ceramic layer's thickness was measured to be approximately 250 m.The interlayer consisted of a MoSi2 diffusion coating, formed by the diffusion process during the siliconizing of the molybdenum substrate.Ideally, the thickness of this zone should be around 100 m.The research scope included a visual characterization of the TBC system to assess its overall integrity.In the second phase of the research, topographic parameters of the surface were evaluated, mainly focusing on the roughness of individual elements within the system.The subsequent assessment highlighted the phase composition of these individual system elements.During the cross-sectional tests, the ceramic layer was evaluated in terms of the architecture of cracks and pores.Quantitative and qualitative assessments were conducted, categorizing the pores as spherical, horizontal, and vertical.The final aspect of the cross-section evaluation was the bond quality between the ceramic layer and the silicide bond coat.
The influence of MCrAlY coating application and its thickness on the heat transfer during water spray cooling Elżbieta Jasiewicz, Beata Hadała, Tadeusz Kubaszek, Barbara Kościelniak, Agnieszka Cebo-Rudnicka, Kamil Dychtoń, Paweł Pędrak International Journal of Heat and Mass Transfer, 2024 The main purpose of the paper was to determine the influence of NiCoCrAlY coating application and its thickness on the heat transfer during water spray cooling under surface boiling conditions. The scope of the research included: sensor preparation, measurements of the sensor temperature during cooling, and numerical calculations to determine the intensity of sensor cooling. The intensity of heat removal was determined by the average values of the heat flux on the cooled surfaces. The inverse method for the heat conduction equation was used to determine the heat transfer boundary conditions. Temperature measurements during cooling were carried out for an initial sensor temperature of 500°C, 700°C and 900°C and a liquid pressure 0.1 MPa, 0.2 MPa. Due to this, it was possible to select a coating thickness that contributed to the greatest extent to the increase in the intensity of heat dissipation from the hot surface. The highest values of the heat flux were obtained during the cooling of the sensor with a 134.5 μm coating.
The Influence of Plasma Spraying Parameters on Microstructure and Porosity of Bronze-Polyester Coatings for Plain Bearings Applications Marek Góral, Tadeusz Kubaszek, Barbara Kościelniak, Dorota Stawarz Solid State Phenomena, 2024 The plasma sprayed bronze coatings are widely used for repairing of plain bearing used in different applications. This type of coating was not deeply analyzed in state-of-art publications. In presented article we fill this gap in the case of plasma spraying process. The influence of power current (300/500/700A) and hydrogen flow (0/4/8 NLPM) on microstructure and thickness of aluminium bronze-polyester coating was investigated. The Thermico A60 plasma torch was used for thermal spray process of coating on flat carbon steel samples (grade S355). The Metco 604NS was sprayed with 20g/min powder feed rate. The obtained results showed the presence of local large pores formed by burning of polyester in plasma plume. This gap makes role of oil pockets in bearings. The obtained coatings were characterized by large deviation in thickness in range 200-350 micrometers. It might be concluded that in requires additional milling process after deposition.
The Manufacturing of Environmental Barrier Coatings by HV-APS Plasma Spraying Using Er2O3 and SiO2 Powder Mixture Paweł Pędrak, Tadeusz Kubaszek, Barbara Kościelniak, Marek Góral, Mateusz Micał Manufacturing Technology, 2024 Over the last decades, nickel-based superalloys with TBC coatings have been used as the main material for hot section turbine parts. The next step in the development of engines and increasing the combustion temperature is the use of Ceramic Matrix Composites (CMC). Nevertheless, in the presence of water vapour or molten salts, accelerated degradation of substrate material. This problems can be pre-vented by additional layers or coatings produced on its surface, or combinations of layers and coatings that form Environmental Barrier Coatings (EBCs). The aim of the research was the preparation of sam-ples of a mixture of erbium oxide powders with silicon oxide with the addition of: polyvinyl alcohol, starch and cellulose gum. Then their technological properties were examined. A mixture with the most favourable properties was selected and sprayed using HV-APS method using with various process parameters and investigated. Conducted research showed that energy of HV-APS process is too low for synthesis of erbium disilicate in the resulting coating. The material was only melted, not vaporized. Making powder agglomerates with an average size of 150 μm with the addition of 3% PVA leads to a significant decrease in the surface area of powder grains. This results in a significant increase in flowability and allows it to be used as a charge material for APS plasma spraying.
The Diffusion Coatings for Industrial Tool Application Marcin Drajewicz, Adrianna Przybylo, Jakub Jopek, Marek Góral, Barbara Koscielniak, Kamil Ochal, Tadeusz Kubaszek, Artur Gurak, Kamil Dychton, Mateusz Wozniak, Pawel Kwasniewski, Artur Kawecki, Wojciech Gluchowski, Marek Lagoda Manufacturing Technology, 2022