Solid State Gas Sensors
Solar Energy Materials
Carrier Transport in Thin films
Supercapacitors
Electrochromic Materials
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Scopus Publications
Scopus Publications
Enhancement in Photoluminescence and Photocatalytic Performances of Solution Combustion Synthesized ZnO Nanoparticles upon Sm Doping Nikita Sharma, Pradosh Prakash Sahay Physica Status Solidi A Applications and Materials Science, 2025 This study explores the synthesis of ZnO nanoparticles through a solution‐combustion route, examining their structural, photoluminescent, and photocatalytic properties upon introducing Sm as a dopant. All synthesized samples display a hexagonal wurtzite structure, with crystallite sizes between 55 and 73 nm. Field‐emission scanning electron microscopy reveals significant sample morphological variation. Diffuse reflectance spectroscopy indicates that doping with Sm3+ results in a slight decrease in the bandgap energy. The photoluminescence (PL) emission spectra at excitation wavelengths of 325, 350, and 390 nm show broad emission bands spanning from the violet to the green regions of the visible spectrum, attributed to defects in ZnO. Additionally, the PL intensity increases with Sm doping up to 2 mol% Sm, after which it declines. The photocatalytic degradation efficiency improves upon Sm doping up to 3 mol% and thereafter decreases.
Characterization of Ce3+ and Eu3+ doped and co-doped ZnO nanoparticles for luminescence applications Nikita Sharma, P P Sahay Physica Scripta, 2024 This paper investigates the synthesis of Ce3+ and Eu3+ doped, as well as co-doped ZnO nanoparticles using the solution combustion route. The nanoparticles exhibit a hexagonal wurtzite structure of ZnO with crystallite sizes ranging from 19 to 22 nm. Structural parameters, including lattice constants, bond lengths, and bond angles, are evaluated. Morphological diversity is observed in field-emission scanning electron microscopy images. The diffuse reflectance spectroscopy results reveal an energy band gap of 3.20 eV for undoped ZnO nanoparticles. The energy band gap value slightly decreases for Eu-doped ZnO and certain (Ce, Eu) co-doped ZnO nanoparticles. Photoluminescence (PL) excitation peaks are attributed to energy levels of native defects in the ZnO band gap, along with f–d and f–f transitions of rare-earth ions (Ce3+, Eu3+). The PL emission spectra under different excitation wavelengths (350 nm, 394 nm, and 465 nm) display varied peak positions. ZnO co-doped with 0.96 mol% of Ce3+ and 0.92 mol% of Eu3+ emerges as a promising material for luminescence applications, exhibiting a significant increase in green emission intensity. Consequently, this study represents a novel contribution to the field of ZnO-based luminescent materials.
Structural, photoluminescence, and photocatalytic performances of Ce3+-activated orthovanadate oxides M3(VO4)2 (M: Mg or Zn) synthesized by solution combustion route Nikita Sharma, Pradosh Prakash Sahay Luminescence, 2024 This paper presents a research investigation into the synthesis of vanadate oxides M3(VO4)2 (M: Mg or Zn) using the solution combustion method and investigates their structural, photoluminescence, and photocatalytic properties after introducing cerium (Ce) as a dopant. The resulting synthesized samples all display an orthorhombic crystalline structure with crystallite sizes ranging from 71 to 110 nm. Morphological diversity among the samples is revealed through field‐emission scanning electron microscopy (FESEM) imagery. Diffuse reflectance spectroscopy discloses that the introduction of Ce3+ as a dopant leads to an increase in the band gap energy. Notably, when excited at a wavelength of 340 nm, the photoluminescence emission intensity reaches its peak across all samples. This intensity undergoes enhancement due to Ce3+ doping, causing a slight shift toward shorter wavelengths attributable to the augmented band gap resulting from the dopant. Markedly, among the investigated materials, Ce3+‐activated Mg3(VO4)2 stands out with the most pronounced emission intensity, positioning it as a highly promising luminescent material. Additionally, the incorporation of Ce3+ has a positive effect on the photocatalytic performance of Mg3(VO4)2, resulting in notable improvement.
Effect of (Ce, Dy) co-doping on the microstructural, optical, and photoluminescence characteristics of solution combustion synthesized ZnO nanoparticles Nikita Sharma, Pradosh Prakash Sahay Luminescence, 2023 Solution combustion synthesized ZnO nanoparticles with Ce, Dy doped and co-doped with varying dopant concentrations were characterized for their microstructural, optical and photoluminescence characteristics. The synthesized nanoparticles have been found to match the standard hexagonal wurtzite structure of ZnO. The lattice fringes in the high-resolution transmission electron micrographs and the bright spotty rings in the selected area electron diffraction pattern authenticate the high crystallinity of the nanoparticles. The diffuse reflectance spectroscopy provides the energy bandgap for the undoped ZnO to be 3.18 eV, decreasing upon doping and co-doping. A sharp narrow UV emission peak at ~ 398 nm originating from the excitonic recombination is found in the PL spectra of the nanoparticles. The visible emission peaks in the PL spectra are assigned to f-d and f-f electron transitions of Ce3+ and Dy3+ ions, respectively, in addition to different native defects in ZnO. The visible emissions (blue, yellow and red) have been found to improve upon (Ce, Dy) co-doping, and therefore (Ce, Dy) co-doped ZnO nanoparticles can be considered as a promising luminescent material for the development of energy-saving light sources.
Structural, optical and ethanol gas-sensing properties of zinc oxide thin film prepared by spray pyrolysis technique using ultrasonic nebuliser Indian Journal of Pure and Applied Physics, 2013
Contribution of the interface state continuum to the non-linearities of Schottky (I-V) characteristics Proceedings of SPIE the International Society for Optical Engineering, 1998