TiO2–SnO2 Nanocomposites for Photocatalytic Environmental Remediation under UV-Light Sandip M. Deshmukh, Santosh S. Patil, Santosh B. Babar, Sultan Alshehri, Mohammed M. Ghoneim, Asiya M. Tamboli, Nguyen Hoang Lam, Nguyen Tam Nguyen Truong, Chang Duk Kim, Mohaseen S. Tamboli, Sanjay M. Khetre, Sambhaji R. Bamane Metals, 2022 The photocatalytic removal of water contaminants for ecological systems has become essential in the past few decades. Consequently, for commercialization, cost-efficient, earth-abundant and easy to synthesize photocatalysts for dye degradation are of urgent need. We have demonstrated a simple and feasible approach for fabricating TiO2–SnO2 nanocomposite photocatalysts via urea-assisted-thermal-decomposition with different mass ratios. The as-synthesized materials were characterized by different physicochemical techniques. The phase formation and crystallite size were calculated by using XRD. The STEM, UV-Vis, DRS, HR-TEM and EDS revealed the effective formation of the heterojunction between TiO2 and SnO2, and enrichment in the UV-absorption spectrum. All synthesized materials were used for the photocatalytic degradation of methyl orange (MO) under UV light. The optimized results of the TiO2–SnO2 nanocomposite showed excellent photostability and photocatalytic activity over a number of degradation-reaction cycles of methyl-orange (MO) dye under the illumination of ultraviolet light. In addition, the recent method has great potential to be applied as a proficient method for mixed-metal-oxide-nanocomposite synthesis.
Environmentally benign organic dye conversion under uv light through tio2-zno nanocomposite Sandip M. Deshmukh, Sudhir S. Arbuj, Santosh B. Babar, Shoyebmohamad F. Shaikh, Asiya M. Tamboli, Nguyen Tam Nguyen Truong, Chang-Duk Kim, Sanjay M. Khetre, Mohaseen S. Tamboli, Sambhaji R. Bamane Metals, 2021 In this work, we developed a very simple and novel approach for synthesizing TiO2-ZnO nanocomposites via the urea-assisted thermal decomposition of titanium oxysulphate and zinc acetate at different weight ratios. The synthesized nanocomposite samples were studied by means of HR-TEM, XRD, STEM, UV–Vis DRS, PL and EDS. The observed results demonstrate that the TiO2-ZnO nanocomposite consists of an anatase crystal phase of TiO2 with a crystallite size of 10–15 nm. Combined characterization, including UV–Vis DRS, STEM, EDS and HR-TEM, revealed the successful formation of a heterojunction between TiO2 and ZnO and an improvement in UV spectrum absorption. The photocatalytic activity was explored using MO degradation under ultraviolet light illumination. The results of the optimized TiO2-ZnO nanocomposite show excellent photocatalytic activity and photostability over a number of degradation reaction cycles. In addition, the current approach has immense potential to be used as a proficient method for synthesizing mixed metal oxide nanocomposites.
The Ceramic Nano Material Al Ca Si5 O15 as a Green Catalyst for Water Remediation Research Journal of Chemistry and Environment, 2021
CaTiAlO4spinal ceramic nano ovals: Synthesis, physicochemical characterization and antimicrobial activity with water remediation application Research Journal of Chemistry and Environment, 2021
A facile urea-assisted thermal decomposition process of TiO2 nanoparticles and their photocatalytic activity Sandip Madhukar Deshmukh, Mohaseen S. Tamboli, Hamid Shaikh, Santosh B. Babar, Dipak P. Hiwarale, Ankush Gautam Thate, Asiya F. Shaikh, Mohammad Asif Alam, Sanjay M. Khetre, Sambhaji R. Bamane Coatings, 2021 In the present work, we have reported a facile and large-scale synthesis of TiO2 nanoparticles (NPs) through urea-assisted thermal decomposition of titanium oxysulphate. We have successfully synthesized TiO2 NPs by using this effective route with different weight ratios of titanium oxysulphate: urea. The structures and properties of TiO2 NPs were confirmed by scanning electron microscope) (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), fourier transform infrared spectroscopy (FT-IR), ultra violet–visible spectroscopy (UV-vis), and photoluminescence (Pl) techniques. XRD demonstrated that TiO2 NPs holds of anatase crystal phase with crystallizing size 14–19 nm even after heating at 600 °C. TGA, SEM, and TEM images reveal urea’s role, which controls the size, morphology, and aggregation of TiO2 NPs during the thermal decomposition. These TiO2 NPs were employed for photodegradation of Methyl Orange (MO) in the presence of ultraviolet (UV) radiation. An interesting find was that the TiO2 NPs exhibited better photocatalytic activity and excellent recycling stability over several photodegradation cycles. Furthermore, the present method has a great perspective to be used as an efficient method for large-scale synthesis of TiO2 NPs.
Antibacterial activity of LaNiO3 prepared by sonicated sol-gel method using combination fuel Ashwini Lalaso Jadhav, Sanjay Mahadev Khetre International Nano Letters, 2020 Sonicated sol-gel method was used to prepare LaNiO3from lanthanum nitrate hexahydrate La(NO3)3.6H2O(LN), nickel nitrate Ni(NO3)3.6H2O(NN), glycine and urea. Nanocrystalline LaNiO3powder was formed after heating at 175 °C in 5 min. Particle size of LaNiO3nanopowder was determined by Debay Scherrer’s equation and was found 48 nm. Prepared nanocatalyst characterized with the help of XRD, TGA, SEM, IR, BET surface area, EDX. Surface area of LaNiO3was 9.22 m2/g. We have reported first time good antibacterial activity of LaNiO3forStaphylococcus aureus. Zone of inhibition for LaNiO3was 13 mm studied with the help of agar cup method.
Preparation and study of acetone gas sensing behavior of nanocrystalline LaCrO 3 thick film Sensors and Transducers, 2012
Auto-combustion synthesis of nanocrystalline FeCrO3 S. M. Khetre, A. U. Chopade, H. V. Jadhav, S. R. Kulal, P. N. Jagadale, S. V. Bangale, S. R. Bamane 2011 International Conference on Nanoscience Technology and Societal Implications Nstsi11, 2011
Simple synthesis of ZnCo 2O 4 nanoparticles as gas-sensing materials Sensors and Transducers, 2011
Synthesis and characterization of nanocrystalline Lafeo3 by combustion route Rasayan Journal of Chemistry, 2010
Synthesis and characterization of nanocrystalline LaCrO3 by combustion route Rasayan Journal of Chemistry, 2009
Synthesis and characterization of nanocrystalline Cu-Zn-Ce mixed oxide by combustion route Rasayan Journal of Chemistry, 2009
RECENT SCHOLAR PUBLICATIONS
Nano Marvels: Unleashing Precision with Metal-Oxide/Reduced Graphene Oxide Synergy in Gas Sensors. PS Pawar, AM Nalawade, SM Khetre, SD Jadhav, ST Salunkhe Ecology, Environment & Conservation (0971765X) 30 , 2024 2024
TiO 2 –SnO 2 Nanocomposites for Photocatalytic Environmental Remediation under UV-Light SM Deshmukh, SS Patil, SB Babar, S Alshehri, MM Ghoneim, AM Tamboli, ... Metals 12 (5), 733 , 2022 2022 Citations: 17
Environmentally Benign Organic Dye Conversion under UV Light through TiO 2 -ZnO Nanocomposite SM Deshmukh, SS Arbuj, SB Babar, SF Shaikh, AM Tamboli, ... Metals 11 (11), 1787 , 2021 2021 Citations: 10
Environmentally Benign Organic Dye Conversion under UV Light through TiO2-ZnO Nanocomposite Sandip M. Deshmukh 1 , Sudhir S. Arbuj 2 , Santosh B. Babar 1 , Shoyebmohamad F … SRB S. M. Deshmukh , S.S. Arbuj , S.B. Babar , S. F. Shaikh , A.M. Tamboli ... Metals 11 (1787), 1-12 , 2021 2021
CaTiAlO4 Spinal Ceramic Nano Ovals: Synthesis, Physicochemical Characterization and Antimicrobial Activity with Water Remediation Application BSRKSM Patil M.V. Research Journal of Chemistry and Environment_ 25 (6), 163-170 , 2021 2021
A Facile Urea-Assisted Thermal Decomposition Process of TiO 2 Nanoparticles and Their Photocatalytic Activity SM Deshmukh, MS Tamboli, H Shaikh, SB Babar, DP Hiwarale, AG Thate, ... Coatings 11 (2), 165 , 2021 2021 Citations: 14
Antibacterial activity of LaNiO3 prepared by sonicated sol‑gel method using combination fuel ALJSM Khetre International Nano Letters , 2019 2019 Citations: 16
Photocalytic Degradation of Methylene Blue by heterogeneous Aqueous Suspension of LaCrO3 Nanocatalyst in Presence of Sunlight SM Khetre Ajanta 8 (I), 165-172 , 2019 2019
Antibacterial activity of LaNiO AL Jadhav, SM Khetre 2019
Synthesis, characterization and hydrophilic properties of ZnFe2O4–TiO2 composite film S Xu, H Huang, C Wang, Z Huang, C Wang Materials Research Bulletin 65, 210-215 , 2015 2015 Citations: 14
Synthesis, characterization and electrical property of nanocrystalline Cu 0.5 Ni 0.5 Ce 3 O 5 HV Jadhav, SG Jadhav, SM Khetre Journal of Materials Science: Materials in Electronics 25 (10), 4375-4379 , 2014 2014
Electrical and dielectric properties of nanocrystalline LaCrO 3 SM Khetre, AU Chopade, CJ Khilare, HV Jadhav, PN Jagadale, ... Journal of Materials Science: Materials in Electronics 24 (11), 4361-4366 , 2013 2013 Citations: 26
Synthesis and characterization of nanostructured CaSiO3 biomaterial PN Jagadale, SR Kulal, MG Joshi, PP Jagtap, SM Khetre, SR Bamane Materials Science-Poland 31 (2), 269-275 , 2013 2013 Citations: 11
A novel nanocoralloids CrFeO 3 nanoparticle: synthesis, electrical property and wettability SM Khetre Journal of Materials Science: Materials in Electronics 24 (4), 1213-1219 , 2013 2013 Citations: 10
Ethanol gas sensing properties of nano-porous LaFeO3 thick film SM Khetre, AU Chopade, CJ Khilare, SR Kulal, HV Jadhav, PN Jagadale, ... Sensors Transducers 149, 13-19 , 2013 2013 Citations: 15
Synthesis of Dy doped Co–Zn ferrite by sol–gel auto combustion method and its characterization SR Kulal, SS Khetre, PN Jagdale, VM Gurame, DP Waghmode, ... Materials letters 84, 169-172 , 2012 2012 Citations: 68
Preparation and Study of Acetone Gas Sensing Behavior of nanocrystalline LaCrO^ sub 3^ Thick Film SM Khetre, CJ Khilare, VS Shivankar, SR Bamane Sensors & Transducers 137 (2), 165 , 2012 2012 Citations: 8
Auto-combustion synthesis of nanocrystalline FeCrO3 SM Khetre, AU Chopade, HV Jadhav, SR Kulal, PN Jagadale, ... 2011 International Conference on Nanoscience, Technology and Societal … , 2011 2011 Citations: 5
Simple Synthesis of ZnCo^ sub 2^ O^ sub 4^ Nanoparticles as Gas-sensing Materials SV Bangale, SM Khetre, DR Patil, SR Bamane Sensors & Transducers 134 (11), 95 , 2011 2011 Citations: 19
Synthesis of pure nanoporous LaFeO3 by using organic fuel SM Khetrea, AU Chopadea, CJ Khilarea, SR Bamane Int. J. Porous Mater 1 (1), 1-5 , 2011 2011 Citations: 16
MOST CITED SCHOLAR PUBLICATIONS
Studies on electrical and dielectric properties of LaFeO3 SM Khetre, HV Jadhav, PN Jagadale, SR Kulal, SR Bamane Adv. Appl. Sci. Res 2 (4), 503-511 , 2011 2011 Citations: 96
Synthesis of Dy doped Co–Zn ferrite by sol–gel auto combustion method and its characterization SR Kulal, SS Khetre, PN Jagdale, VM Gurame, DP Waghmode, ... Materials letters 84, 169-172 , 2012 2012 Citations: 68
Synthesis and Characterization of Nanocrystalline LaFeO3 by Combustion Route HVJSRB S. M. Khetre Rasayan journal of chemistry 3 (1), 82-86 , 2010 2010 Citations: 50
Use of mixed metal oxide as a catalyst in the decomposition of hydrogen peroxide SM Khetre, HV Jadhav, SV Bangale, PN Jagdale, SR Bamane Ind J Chem 2 (2), 252-259 , 2011 2011 Citations: 31
Electrical and dielectric properties of nanocrystalline LaCrO 3 SM Khetre, AU Chopade, CJ Khilare, HV Jadhav, PN Jagadale, ... Journal of Materials Science: Materials in Electronics 24 (11), 4361-4366 , 2013 2013 Citations: 26
Removal of alizarin red-S from aqueous solution by adsorption on nanocrystalline Cu 0.5 Zn 0.5 Ce 3 O 5 . HV Jadhav, SM Khetre, SR Bamane 2011 Citations: 21
Synthesis, characterization and hydrophilic properties of nanocrystalline ZnFe2O4 oxide SRB SV Bangale, SM Khetre Archives of Applied Science Research 3 (4), 471-479 , 2011 2011 Citations: 20
Simple Synthesis of ZnCo^ sub 2^ O^ sub 4^ Nanoparticles as Gas-sensing Materials SV Bangale, SM Khetre, DR Patil, SR Bamane Sensors & Transducers 134 (11), 95 , 2011 2011 Citations: 19
TiO 2 –SnO 2 Nanocomposites for Photocatalytic Environmental Remediation under UV-Light SM Deshmukh, SS Patil, SB Babar, S Alshehri, MM Ghoneim, AM Tamboli, ... Metals 12 (5), 733 , 2022 2022 Citations: 17
Antibacterial activity of LaNiO3 prepared by sonicated sol‑gel method using combination fuel ALJSM Khetre International Nano Letters , 2019 2019 Citations: 16
Synthesis of pure nanoporous LaFeO3 by using organic fuel SM Khetrea, AU Chopadea, CJ Khilarea, SR Bamane Int. J. Porous Mater 1 (1), 1-5 , 2011 2011 Citations: 16
Ethanol gas sensing properties of nano-porous LaFeO3 thick film SM Khetre, AU Chopade, CJ Khilare, SR Kulal, HV Jadhav, PN Jagadale, ... Sensors Transducers 149, 13-19 , 2013 2013 Citations: 15
A Facile Urea-Assisted Thermal Decomposition Process of TiO 2 Nanoparticles and Their Photocatalytic Activity SM Deshmukh, MS Tamboli, H Shaikh, SB Babar, DP Hiwarale, AG Thate, ... Coatings 11 (2), 165 , 2021 2021 Citations: 14
Synthesis, characterization and hydrophilic properties of ZnFe2O4–TiO2 composite film S Xu, H Huang, C Wang, Z Huang, C Wang Materials Research Bulletin 65, 210-215 , 2015 2015 Citations: 14
Synthesis, characterization and hydrophilic properties of nanocrystalline ZnCo2O4 oxide by combustion route SV Bangale, SM Khetre, SR Bamane Der Chemica Sinica 2 (4), 303-311 , 2011 2011 Citations: 12
Synthesis and characterization of nanostructured CaSiO3 biomaterial PN Jagadale, SR Kulal, MG Joshi, PP Jagtap, SM Khetre, SR Bamane Materials Science-Poland 31 (2), 269-275 , 2013 2013 Citations: 11
Environmentally Benign Organic Dye Conversion under UV Light through TiO 2 -ZnO Nanocomposite SM Deshmukh, SS Arbuj, SB Babar, SF Shaikh, AM Tamboli, ... Metals 11 (11), 1787 , 2021 2021 Citations: 10
A novel nanocoralloids CrFeO 3 nanoparticle: synthesis, electrical property and wettability SM Khetre Journal of Materials Science: Materials in Electronics 24 (4), 1213-1219 , 2013 2013 Citations: 10
Solar photodegradation of methylene blue by LaMnO3 nanorods as a heterogeneous catalyst SM Khetrea, HV Jadhavb, PN Jagadaleb, SV Bangale, SR Kulalb, ... Archives of Applied Science Research 3 (4), 450-462 , 2011 2011 Citations: 9
Preparation and Study of Acetone Gas Sensing Behavior of nanocrystalline LaCrO^ sub 3^ Thick Film SM Khetre, CJ Khilare, VS Shivankar, SR Bamane Sensors & Transducers 137 (2), 165 , 2012 2012 Citations: 8