PMF@SO3H nanosheet: an efficient novel bifunctional acid–base catalyst for the one-pot synthesis of 14-Aryl-14H-Dibenzo[a,j]xanthenes and evaluation of their antimicrobial activities supported by DFT and molecular docking studies Zahra Karimi, Leila Amiri-Zirtol, Zahra Nazemoroaya, Najmedin Azizi, Reza Ranjbar-Karimi, Seyedeh Narjes Abootalebi, Ahmad Gholami Journal of Saudi Chemical Society, 2026 This study presents the design and synthesis of a highly efficient solid acid catalyst based on mesoporous poly(melamine–formaldehyde) (MPMF) functionalized with 1,4-butanesultone. The composite was characterized using FT-IR, EDX, XRD, and SEM, confirming the incorporation of acidic groups. Its catalytic activity was assessed for synthesizing xanthene derivatives in water at 70 °C, achieving excellent yields in short reaction times. The catalyst showed high stability, maintaining efficiency over five cycles. Additionally, the antibacterial activity of the synthesized xanthene compounds was evaluated against Staphylococcus aureus , E. coli , MRSA , VRE , and Acinetobacter baumannii . Notably, compounds 14-(4-nitrophenyl)-14 H -dibenzo[ a,j ]xanthene ( 5b ) and 14-(4-methoxyphenyl)-14 H -dibenzo[ a,j ]xanthene ( 8b ) exhibited the strongest antibacterial properties, indicating their potential for pharmaceutical applications. Molecular docking study of the tested compounds was performed to investigate the interaction mode of these compounds with the active site of Staphylococcus aureus Gyrase B enzyme. DFT studies on compounds 5b and 8b reveal that 5b is more reactive with a smaller HOMO–LUMO gap and localized electron density, while 8b is more stable with delocalized orbitals. ESP and reactivity descriptors confirm the correlation between charge distribution, hardness, and molecular stability.
Dual Brønsted acidic-basic function immobilized on the 3D mesoporous polycalix [4]resorcinarene: As a highly recyclable catalyst for the synthesis of spiro acenaphthylene/indene heterocycles Aref Mahmoudi Asl, Bahador Karami, Mahnaz Farahi, Zahra Karimi Heliyon, 2024 In this study, a novel dual Bronsted acidic-basic nano-scale porous organic polymer catalyst, PC4RA@SiPr-Pip-BuSO3H, was synthesized through various steps: preparation of a 3D network of polycalix, modification with (3-chloropropyl)-trimethoxysilane, then functionalization of polymer with piperazine and n-butyl sulfonic acid under the provided conditions. The catalyst characterization was performed by FT-IR, TGA, EDS, elemental mapping, PXRD, TEM, and FE-SEM analyses, confirming high chemical stability, activity, recoverability, and excellent covalent anchoring of functional groups. So, the designed catalyst was utilized for preparing spiro-acenaphthylene and amino-spiroindene heterocycles, providing good performance with a high yield of the corresponding products. Accordingly, this catalyst can be used in different organic transformations. Necessary experiments were conducted for the recyclability test of the polymeric catalyst, and the results showed the PC4RA@SiPr-Pip-BuSO3H catalyst can be reused 10 times without any decrease in its activity or quality with excellent stability. The structure of resultant spiro heterocycles was confirmed using 1H NMR, 13C NMR, and FT-IR.
Synthesis of polymer propane sulfonate Contains ionic liquid based on imidazolium and study of its catalytic properties in the process of acylation of alcohols and esterification of acids زهرا کریمی, اکبر حسن پور, سحر کنگری, اعظم مرجانی Applied Chemistry Today, 2022 The main purpose of this study is the direct synthesis of regular mesoporous polymer with 3-(1-Vinyl imidazolium-3-yl) propane-1-sulfonate (MPIL-PS) ionic liquid units and its use as a catalytic substrate in the esterification of acids and the acylation of alcohols. in this research,Polyvinyl benzene polymer was synthesized with imidazolium units. In the next step, the regular mesoporous polymer (MPIL-PS) was activated with the Propane sultone group, and then the desired catalyst (H2SO4 @ MPIL-PS) was prepared by the interaction of ionic liquid units created on the surface of the polymer with sulfuric acid groups. The synthesized catalyst has the simultaneous advantages of ionic liquids and polymer nanostructured materials. By changing the reaction conditions and reducing the percentage of ionic liquids used in the presence of small amounts of catalyst, this catalyst was used in the reaction of esterification of acids and acylation of alcohols with high yields of products. The resulting catalyst after synthesis, The synthesized catalyst were characterized by various techniques such as nitrogen adsorption-desorption analysis, thermal gravimetric analysis (TGA) and FT-IR spectroscopy. Also, the catalyst recycling test showed that the catalytic system can be recycled up to 5 times with high efficiency without any significant reduction in activity.
Synthesis of A Novel Heterocyclic System of 3,8-Disubstituted-5H-Pyrimido[5’,4’:5,6][1,4]Thiazino[3,2-e][1,2,4]Triazine Azam Karimian, Zahra Karimi Polycyclic Aromatic Compounds, 2022 The new compounds 6-methyl-8-morpholino-2H pyrimido[5’,4’:5,6][1,4]thiazino[3,2e][1,2,4]triazin-3(5H)-one (3a) and 6-methyl-8-(piperidin-1-yl)-2Hpyrimido[5’,4’:5,6][1,4]thiazino[3,2-e][1,2,4]triazin-3(5H)-one (3b) were obtained from cyclocondensation of 6-bromo-1,2,4-triazine-3,5(2H,4H)-dione (1) with appropriate 5-amino-6methylpyrimidine-4-thiol (2a, b) in dimethylformamide and in the presence of potassium carbonate under reflux. Reaction of compounds (3a, b) with phosphorous oxychloride gave 4-(3-chloro-6-methyl-5H-pyrimido[5’,4’:5,6][1,4]thiazino[3,2-e][1,2,4]triazin-8-yl)morpholine (4a) and 3-chloro-6-methyl-8-(piperidin-1-yl)-5H-pyrimido[5’,4’:5,6][1,4]thiazino[3,2-e][1,2,4]triazine (4b). Nucleophilic substitution of chlorine atom of compounds (4a, b) with typical secondary amines in DMF and K2CO3 produced the new derivatives of the 3,8-disubstituted-5H-pyrimido[5’,4’:5,6][1,4]thiazino[3,2-e][1,2,4]triazine ring systems (5a–f). All the synthesized products were characterized and confirmed by their spectroscopic and microanalytical data.
TiO 2 as an efficient catalytic surface for reduction of carbonyl compounds with NaBH 4 under solvent-free, solid-gel and microwave irradiation Oriental Journal of Chemistry, 2011
A novel and highly efficient heterogeneous bioorganic nanocatalyst for the green synthesis of diverse heterocyclic compounds Z Karimi, L Amiri-zirtol, R Ranjbar-Karimi, Z Nazemoroaya, MM Nemati, ... Inorganic Chemistry Communications, 116181 , 2026 2026
PMF@ SO3H nanosheet: an efficient novel bifunctional acid–base catalyst for the one-pot synthesis of 14-Aryl-14H-Dibenzo [a, j] xanthenes and evaluation of their antimicrobial … Z Karimi, L Amiri-Zirtol, Z Nazemoroaya, N Azizi, R Ranjbar-Karimi, ... Journal of Saudi Chemical Society 30 (1), 2 , 2026 2026 Citations: 1
Nanao/organocatalyat SiO 2 /4-(2-Aminoethyl)-morpholine as a new, reusable, and efficacious catalyst for the synthesis of polyhydroquinolines derivatives and … L Amiri-Zirtol, Z Karimi, J Farahbakhsh, A Gholami, SN Abootalebi BMC chemistry 19 (1), 58 , 2025 2025 Citations: 2
l -Aspartic acid-functionalized magnetic nanoparticles: as a new magnetically reusable bifunctional acid–base catalysts for the synthesis of benzo[ b ]pyran and pyrano[3,2 … L Amiri-Zirtol, H Mostashfi, R Sabet, Z Karimi, R Ranjbar-Karimi Scientific Reports 15 (1), 248 , 2025 2025 Citations: 10
The Thorpe-Ziegler reaction: A powerful strategy for the synthesis of heterocycles L Amiri-Zirtol, Z Karimi, F Azodzadegan, P Gholamzadeh Advances in Heterocyclic Chemistry , 2024 2024 Citations: 2
Preparation of a new reusable magnetic organocatalyst to synthesis of polyhydroquinoline derivatives as cytotoxic agents: synthesis and biological evaluation L Amiri-Zirtol, A Yargholi, L Emami, Z Karimi, S Khabnadideh Journal of Saudi Chemical Society 28 (6), 101922 , 2024 2024 Citations: 8
A novel and efficient boron-containing magnetic catalyst based on graphene oxide (GO-Fe3O4-BFn) for synthesis of pyrazole and pyranopyrazole derivatives L Amiri-zirtol, S Sadeghian, A Abdolmaleki, A Mohammadi, M Salehi, ... Journal of Molecular Structure 1307, 137868 , 2024 2024 Citations: 14
The study of acid leaching on the mineralogical and microscopic changes of red mud Z Karimi, A Rahbar-Kelishami Mining, Metallurgy & Exploration 41 (2), 1121-1133 , 2024 2024 Citations: 18
Efficient utilization of red mud waste via stepwise leaching to obtain α-hematite and mesoporous γ-alumina Z Karimi, A Rahbar-Kelishami Scientific Reports 13 (1), 8527 , 2023 2023 Citations: 69
Preparation of highly efficient and eco-friendly alumina magnetic hybrid nanosorbent from red mud: Excellent adsorption capacity towards nitrate Z Karimi, A Rahbar-Kelishami Journal of Molecular Liquids 368, 120751 , 2022 2022 Citations: 42
Investigation on the removal of dyes from wastewater using alumina composite nano adsorbent Z Karimi, A Allahverdi, F Oshani Journal of Studies in Color World 10 (2), 41-59 , 2020 2020 Citations: 4
Recycling of Red Mud for Value-Added Applications: A Comprehensive Review M Mahinroosta, Z Karimi, A Allahverdi Reference Module in Materials Science and Materials Engineering , 2020 2020 Citations: 55
High purity amorphous alumina nanoparticles from hazardous aluminum dross M Mahinroosta, A Allahverdi, Z Karimi The16th Iranian National Congress of Chemical Engineering , 2019 2019
Utilization of red mud for extraction of alumina nanopowder Z Karimi, A Allahverdi, M Mahinroosta The16th Iranian National Congress of Chemical Engineering , 2019 2019
Recovery of Metals from Red Mud Using Mineral Acids Z Karimi, A Allahverdi, M Mahinroosta Conference: Proceedings of Iran International Aluminium Conference (IIAC2018) , 2018 2018 Citations: 2
A UBI-QEP microkinetic study for Fischer-Tropsch synthesis on iron catalysts M Moqadam, M Rahmani, Z Karimi, A Naderifar Procedia Engineering 42, 34-44 , 2012 2012 Citations: 16
A study on vapour-liquid equilibria in Fischer-Tropsch synthesis Z Karimi, M Rahmani, M Moqadam Procedia Engineering 42, 25-33 , 2012 2012 Citations: 22
MOST CITED SCHOLAR PUBLICATIONS
Efficient utilization of red mud waste via stepwise leaching to obtain α-hematite and mesoporous γ-alumina Z Karimi, A Rahbar-Kelishami Scientific Reports 13 (1), 8527 , 2023 2023 Citations: 69
Recycling of Red Mud for Value-Added Applications: A Comprehensive Review M Mahinroosta, Z Karimi, A Allahverdi Reference Module in Materials Science and Materials Engineering , 2020 2020 Citations: 55
Preparation of highly efficient and eco-friendly alumina magnetic hybrid nanosorbent from red mud: Excellent adsorption capacity towards nitrate Z Karimi, A Rahbar-Kelishami Journal of Molecular Liquids 368, 120751 , 2022 2022 Citations: 42
A study on vapour-liquid equilibria in Fischer-Tropsch synthesis Z Karimi, M Rahmani, M Moqadam Procedia Engineering 42, 25-33 , 2012 2012 Citations: 22
The study of acid leaching on the mineralogical and microscopic changes of red mud Z Karimi, A Rahbar-Kelishami Mining, Metallurgy & Exploration 41 (2), 1121-1133 , 2024 2024 Citations: 18
A UBI-QEP microkinetic study for Fischer-Tropsch synthesis on iron catalysts M Moqadam, M Rahmani, Z Karimi, A Naderifar Procedia Engineering 42, 34-44 , 2012 2012 Citations: 16
A novel and efficient boron-containing magnetic catalyst based on graphene oxide (GO-Fe3O4-BFn) for synthesis of pyrazole and pyranopyrazole derivatives L Amiri-zirtol, S Sadeghian, A Abdolmaleki, A Mohammadi, M Salehi, ... Journal of Molecular Structure 1307, 137868 , 2024 2024 Citations: 14
l -Aspartic acid-functionalized magnetic nanoparticles: as a new magnetically reusable bifunctional acid–base catalysts for the synthesis of benzo[ b ]pyran and pyrano[3,2 … L Amiri-Zirtol, H Mostashfi, R Sabet, Z Karimi, R Ranjbar-Karimi Scientific Reports 15 (1), 248 , 2025 2025 Citations: 10
Preparation of a new reusable magnetic organocatalyst to synthesis of polyhydroquinoline derivatives as cytotoxic agents: synthesis and biological evaluation L Amiri-Zirtol, A Yargholi, L Emami, Z Karimi, S Khabnadideh Journal of Saudi Chemical Society 28 (6), 101922 , 2024 2024 Citations: 8
Investigation on the removal of dyes from wastewater using alumina composite nano adsorbent Z Karimi, A Allahverdi, F Oshani Journal of Studies in Color World 10 (2), 41-59 , 2020 2020 Citations: 4
Nanao/organocatalyat SiO 2 /4-(2-Aminoethyl)-morpholine as a new, reusable, and efficacious catalyst for the synthesis of polyhydroquinolines derivatives and … L Amiri-Zirtol, Z Karimi, J Farahbakhsh, A Gholami, SN Abootalebi BMC chemistry 19 (1), 58 , 2025 2025 Citations: 2
The Thorpe-Ziegler reaction: A powerful strategy for the synthesis of heterocycles L Amiri-Zirtol, Z Karimi, F Azodzadegan, P Gholamzadeh Advances in Heterocyclic Chemistry , 2024 2024 Citations: 2
Recovery of Metals from Red Mud Using Mineral Acids Z Karimi, A Allahverdi, M Mahinroosta Conference: Proceedings of Iran International Aluminium Conference (IIAC2018) , 2018 2018 Citations: 2
PMF@ SO3H nanosheet: an efficient novel bifunctional acid–base catalyst for the one-pot synthesis of 14-Aryl-14H-Dibenzo [a, j] xanthenes and evaluation of their antimicrobial … Z Karimi, L Amiri-Zirtol, Z Nazemoroaya, N Azizi, R Ranjbar-Karimi, ... Journal of Saudi Chemical Society 30 (1), 2 , 2026 2026 Citations: 1
A novel and highly efficient heterogeneous bioorganic nanocatalyst for the green synthesis of diverse heterocyclic compounds Z Karimi, L Amiri-zirtol, R Ranjbar-Karimi, Z Nazemoroaya, MM Nemati, ... Inorganic Chemistry Communications, 116181 , 2026 2026
High purity amorphous alumina nanoparticles from hazardous aluminum dross M Mahinroosta, A Allahverdi, Z Karimi The16th Iranian National Congress of Chemical Engineering , 2019 2019
Utilization of red mud for extraction of alumina nanopowder Z Karimi, A Allahverdi, M Mahinroosta The16th Iranian National Congress of Chemical Engineering , 2019 2019