Plant Science, General Agricultural and Biological Sciences
5
Scopus Publications
180
Scholar Citations
5
Scholar h-index
2
Scholar i10-index
Scopus Publications
The role of BaTiO3 nanoparticles as photocatalysts in the synthesis and characterization of novel fruit dyes is investigated N. N. Shafeera, D. Saravanakkumar, K. Mohamed Rafi, A. Ayeshamariam, K. Kaviyarasu Microscopy Research and Technique, 2025 In the present work, the photocatalytic activity against the natural dye extracted from the novel fruits has been studied by the BaTiO3 nanoparticles (NPs) under a ultra‐violet (UV) light source. The large concentrations of an essential phenolic agent present in this phytochemical extract superimposed with cloths fibers make strong stain and degrade into another form of toxic, which is excluded from the many textiles industries as the colorful waste waters without recycling and removal of that dye pigments have been investigated using both photodegradation and photoluminescence techniques. The entitled nanoparticles (NPs) were prepared using the soft chemical root‐modified solvothermal synthesis combo method and exposure to heat treatment such that the annealing process has been done for different temperatures ranging from 100°C to 250°C. As for as concern the characterization, as a start, structural and morphology studies have been reported here that highly crystalline oriented peaks data using powder x‐ray diffraction techniques (PXRD) as well as the surface morphology including the size, shape, and mass distribution using the field emission scanning electron microscopy (FESEM) techniques, which purely belong to rutile tetragonal structure of the crystal system and circular and noncircular flakes like rough surface morphology materials respectively. The lattice dissociation constant ‘ε’ value of the BaTiO3 NPs has determined to be ~2.71 × 10−3 using the Williamson–Hall (W–H plot) analysis of crystallographic data. In the UV visible spectroscopy findings, since the extreme quantum confinement of BaTiO3 nanoflakes/nanodisc, the optical energy bandgap has been estimated to be a range of 1.98 to 2.67 eV (~2.48 eV) found from the Tauc plot analysis, which contributes to the significantly owing to the enhanced photocatalytic efficiency with excellent performance along exciton formation, superoxide ions, and hydroxyl free radicals generations under UV–vis light irradiation resulting in efficient degradation of typical novel fruit organic dye. Photoluminescence spectra observed at room temperature and low temperature have been observed for the BaTiO3 nanoflakes, which exhibit the blue emission due to the crystalline defects such as the appearance of Ba vacancies leads to the conceivable beginning of p‐type conductivity and the origination of free exciton emission reveals the direct bandgap transition nature of nanoflakes.Research Highlights According to our findings, 89.71% of the natural syzygium cumin is degraded by photocatalysis reaction. As a plausible mechanism for the destruction of natural dyes under solar light, photocatalytic destruction has been proposed. The reaction between these reactive free radical species leads to high efficiency photodegradation with a short decay time. In addition to water treatment and environmental cleaning applications, the excellent performance of this photocatalyst makes it a promising candidate for other applications. Hence, the synthesized BaTiO3 nanoflakes showcase a highly significant advancement towards the development of a textiles dye recycling method.
Novel synthesis of cerium oxide nano photocatalyst by a hydrothermal method Fowziya Shaik Ali, Faisal Al Marzouqi, A. Afroos Banu, M. Ismail Fathima, A. R. Mohamed Jahangir, K. Mohamed Rafi, A. Ayeshamariam Journal of Semiconductors, 2021 Crystalline cubic cerium oxide nano particles have been synthesized from cerium (III) nitrate (Ce (NO3)3.6H2O) and sodium hydroxide by a hydrothermal method. The effect of three different molar ratios of the NaOH precipitating agent on structural, optical, and photo catalytic activity was investigated. The synthesized cerium oxide nano particles were characterized by X-ray diffraction (XRD), a UV–vis spectrometer, scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDAX), Raman spectroscopy and X-ray photo electron spectroscopy (XPS). According to the findings, hydrothermally synthesized cerium oxide NPs have a high efficiency for photocatalytic degradation of methylene blue when exposed to UV light. Environmental water pollution is the major issue of the atmosphere. To get fresh water, humans could search the resources to purify the water in simple way and degradation is the one of the methods to purify salt water.
The role of BaTiO 3 nanoparticles as photocatalysts in the synthesis and characterization of novel fruit dyes is investigated K Shafeera, N. N., Saravanakkumar, D., Mohamed Rafi K, Ayeshamariam, A ... Microscopy Research and Technique, 1-9 , 2024 2024 Citations: 5
AI BASED NANOPARTICLE BASED CANCER TREATMENT DEVICE DKMRDAVDCTDMKKDHSUMAKVMDHKDVRMRKDMKMMSRPDR Garg IN Patent 211,937 , 2024 2024
Facile Green Synthesis of Silver Nanoparticles Using Passiflora edulis and Its Efficacy Against the Breast Cancer Cell Line KMR Pradeep Duraiyarasan, Parthiban Subramaniyan, Arun Melvin, G Siva, S ... Biotechnology of Medicinal Plants with Antiallergy Properties: Research … , 2024 2024 Citations: 3
Larvicidal Activities of Capparis divaricata against Two Mosquito Species, Aedes aegypti and Anopheles stephensi KMRMA P. K. Siva, R. Bhuvaneswari Research Journal of Agricultural Sciences 15 (1), 238–240 , 2024 2024
Enhanced Growth of Green Synthesized Bi2Fe4O9: Nanoparticles Decorated on MWCNT SBMAA A. Afroos Banu, N. N. Shafeera, N. Kalangadan, K. Mohamed Rafi, D ... ORIENTAL JOURNAL OF CHEMISTRY 40 (1), 18-27 , 2024 2024
In vivo degradation of polyethylene terephthalate using microbial isolates from plastic polluted environment Baskaran Maheswaran, Mysoon Al-Ansari, Latifah Al-Humaid, Joseph Sebastin ... Chemosphere , 2022 2022 Citations: 106
Pharmacological and Phytochemical Investigation of Chloroxylon swietenia DC. Nagarajan M, Amzad Basha Kolar, Arumugam M, Mohamed Rafi K Research Journal of Agricultural Sciences An International Journal 13 (5 … , 2022 2022 Citations: 2
Characterization of CeO2-NiO Thin Film Produced by Jet Nebuliser Technique SM Thirumamagal R, Ragamathunnisa M, Mohamed Rafi K, Mohamed Saleem A ... International Journal of Nanobiotechnology 7 (1) , 2021 2021
Novel synthesis of cerium oxide nano photocatalyst by a hydrothermal method Fowziya Shaik Ali, Faisal Al Marzouqi A, Afroos Banu, Ismail Fathima M ... Journal of Semiconductors , 2021 2021 Citations: 8
Genetic Transformation using Agrobacterium rhizogenes for the Production of Valuable Anti-Cancer Compound, Withaferin-A from Withania somnifera (L.) Dunal Thilip C, Raja P, Mohamed Rafi K, Faizal KP, Thiagu G, Aslam A, Shajahan A Jamal Academic Research Journal: An Interdisciplinary 1 (1), 1-5 , 2020 2020 Citations: 2
Facile Synthesis of Copper with CNT for the removal of Ni ions AA Kayalvizhi K, Alhaji N.M.I, Mohamed Rafi K Malaya Journal of Matematik, 2, 4902-4905 , 2020 2020
Removal of Heavy Metals from Wastewater Treatment using Composite Nanomaterials: A Review Prabhavathi G, Karunanithy M, Ayeshamariam A, Sekar N, Mohamed Rafi K, Pon ... Journal of Nanoscience, Nanoengineering & Applications 9 (1) , 2019 2019 Citations: 5
Anticancer Activities of Ag NPS Biosynthesized by Using Cassia auriculata Prem Nawaz M, Raja Mohamed S, Ramamurthy V, Mohamed Rafi K, Ayeshamariam A IOSR Journal of Applied Physics (IOSR-JAP) 10 (2278-4861), 19-26 , 2018 2018 Citations: 2
Green synthesis of Ag NPs synthesized by using Cassia auriculata leaves (C.auriculata) and its applications of cancer activity Ayeshamariam A, Prem Nawaz M, Raja Mohamed S, Mohamed Rafi K IOSR Journal Of Pharmacy 8 (7) , 2018 2018
Effect of Cassia auriculata (C.auriculate) Leaves Extract for the Bio Synthesis of Ag NPs and Its Investigation of Antioxidant Activity AA Prem Nawaz M, Raja Mohamed S, Palanivelu M, Mohamed Rafi K Journal of Bionanoscience 12 (doi:10.1166/jbns.2018.1576) , 2018 2018
Assessment of Heavy Metals in Surface Water of Adirampattinam Seashore, Thanjavur District, Tamil Nadu, India Prem Nawaz M, Raja Mohamed S, Ayeshamariam A, Mohamed Rafi K Fluid Mechanics: Open Access 4 (1 • 1000147) , 2017 2017 Citations: 3
Efficient Agrobacterium Rhizogenes Mediated Hairy Root Culture System for Withanolide Production from Withania Somnifera (L.) Dunal Thilip CS, Aslam A, Mohamed Rafi K, Varutharaju K, Kathiravan K J Appl Biotechnol Bioeng 3 (1), 00053 , 2017 2017 Citations: 1
Phytochemical analysis and evaluation of antimicrobial potential of Senna alata linn. Leaves extract MS Karthika C, Mohamed Rafi K Asian Journal of Pharmaceutical and Clinical Research 9 (2), 253 - 257 , 2016 2016 Citations: 28
Assessment of the Physico-Chemical Properties of Water Samples Collected for Four Different Samples at Ramnad and Sivagangai Districts, Tamil Nadu, In India. Barsana Barvin R, Kashif M, Sree Revathy K, Ayeshamariam A, Mohamed Rafi K ... Journal of Harmonized Research in Applied Sciences 2 (2), 111-117 , 2014 2014
Studies on genetic diversity of Withania somnifera (l.) Dunal of Tamilnadu Aslam A , Mohamed Rafi K, Shajahan A 2013 Citations: 1
MOST CITED SCHOLAR PUBLICATIONS
In vivo degradation of polyethylene terephthalate using microbial isolates from plastic polluted environment Baskaran Maheswaran, Mysoon Al-Ansari, Latifah Al-Humaid, Joseph Sebastin ... Chemosphere , 2022 2022 Citations: 106
Phytochemical analysis and evaluation of antimicrobial potential of Senna alata linn. Leaves extract MS Karthika C, Mohamed Rafi K Asian Journal of Pharmaceutical and Clinical Research 9 (2), 253 - 257 , 2016 2016 Citations: 28
Novel synthesis of cerium oxide nano photocatalyst by a hydrothermal method Fowziya Shaik Ali, Faisal Al Marzouqi A, Afroos Banu, Ismail Fathima M ... Journal of Semiconductors , 2021 2021 Citations: 8
Class-based stratification matrix for physical leaf traits in phenetic relations of Withania somnifera (L.) Dunal accessions Aslam A, Mohamed Rafi K, Kathiravan K, Shajahan A Plant systematics and evolution 288, 99-111 , 2010 2010 Citations: 8
The role of BaTiO 3 nanoparticles as photocatalysts in the synthesis and characterization of novel fruit dyes is investigated K Shafeera, N. N., Saravanakkumar, D., Mohamed Rafi K, Ayeshamariam, A ... Microscopy Research and Technique, 1-9 , 2024 2024 Citations: 5
Removal of Heavy Metals from Wastewater Treatment using Composite Nanomaterials: A Review Prabhavathi G, Karunanithy M, Ayeshamariam A, Sekar N, Mohamed Rafi K, Pon ... Journal of Nanoscience, Nanoengineering & Applications 9 (1) , 2019 2019 Citations: 5
Facile Green Synthesis of Silver Nanoparticles Using Passiflora edulis and Its Efficacy Against the Breast Cancer Cell Line KMR Pradeep Duraiyarasan, Parthiban Subramaniyan, Arun Melvin, G Siva, S ... Biotechnology of Medicinal Plants with Antiallergy Properties: Research … , 2024 2024 Citations: 3
Assessment of Heavy Metals in Surface Water of Adirampattinam Seashore, Thanjavur District, Tamil Nadu, India Prem Nawaz M, Raja Mohamed S, Ayeshamariam A, Mohamed Rafi K Fluid Mechanics: Open Access 4 (1 • 1000147) , 2017 2017 Citations: 3
Direct rhizogenesis from in vitro leaves of Withania somnifera (L.) Dunal. Mohamed Rafi K, Aslam A, Kohila S, Tanweer J, Shajahan A Indian Journal of Plant Physiology 15 (2), 173 - 176 , 2010 2010 Citations: 3
Antimicrobial activity of the leaf extract of Moringa concanensis (Nimmo.) Mohamed Rafi K, Sirajudeen K, Shajahan A Advances in Plant Sciences 18 (II), 893-894 , 2005 2005 Citations: 3
Pharmacological and Phytochemical Investigation of Chloroxylon swietenia DC. Nagarajan M, Amzad Basha Kolar, Arumugam M, Mohamed Rafi K Research Journal of Agricultural Sciences An International Journal 13 (5 … , 2022 2022 Citations: 2
Genetic Transformation using Agrobacterium rhizogenes for the Production of Valuable Anti-Cancer Compound, Withaferin-A from Withania somnifera (L.) Dunal Thilip C, Raja P, Mohamed Rafi K, Faizal KP, Thiagu G, Aslam A, Shajahan A Jamal Academic Research Journal: An Interdisciplinary 1 (1), 1-5 , 2020 2020 Citations: 2
Anticancer Activities of Ag NPS Biosynthesized by Using Cassia auriculata Prem Nawaz M, Raja Mohamed S, Ramamurthy V, Mohamed Rafi K, Ayeshamariam A IOSR Journal of Applied Physics (IOSR-JAP) 10 (2278-4861), 19-26 , 2018 2018 Citations: 2
Efficient Agrobacterium Rhizogenes Mediated Hairy Root Culture System for Withanolide Production from Withania Somnifera (L.) Dunal Thilip CS, Aslam A, Mohamed Rafi K, Varutharaju K, Kathiravan K J Appl Biotechnol Bioeng 3 (1), 00053 , 2017 2017 Citations: 1
Studies on genetic diversity of Withania somnifera (l.) Dunal of Tamilnadu Aslam A , Mohamed Rafi K, Shajahan A 2013 Citations: 1
AI BASED NANOPARTICLE BASED CANCER TREATMENT DEVICE DKMRDAVDCTDMKKDHSUMAKVMDHKDVRMRKDMKMMSRPDR Garg IN Patent 211,937 , 2024 2024
Larvicidal Activities of Capparis divaricata against Two Mosquito Species, Aedes aegypti and Anopheles stephensi KMRMA P. K. Siva, R. Bhuvaneswari Research Journal of Agricultural Sciences 15 (1), 238–240 , 2024 2024
Enhanced Growth of Green Synthesized Bi2Fe4O9: Nanoparticles Decorated on MWCNT SBMAA A. Afroos Banu, N. N. Shafeera, N. Kalangadan, K. Mohamed Rafi, D ... ORIENTAL JOURNAL OF CHEMISTRY 40 (1), 18-27 , 2024 2024
Characterization of CeO2-NiO Thin Film Produced by Jet Nebuliser Technique SM Thirumamagal R, Ragamathunnisa M, Mohamed Rafi K, Mohamed Saleem A ... International Journal of Nanobiotechnology 7 (1) , 2021 2021
Facile Synthesis of Copper with CNT for the removal of Ni ions AA Kayalvizhi K, Alhaji N.M.I, Mohamed Rafi K Malaya Journal of Matematik, 2, 4902-4905 , 2020 2020