Physicochemical and photocatalytic properties of Ag2CrO4/Fe2O3/CeO2 ternary nanocomposite Mahendran Ananthkumar, Jeyaram Jayaprakash, Abhijit Debnath, Mohammed F. Albeshr, Raja Mythili, Pachaimuthu Akilan, Alagesan Kannan, Shanmugam Vignesh, Venkatachalam Chandrasekaran Luminescence, 2024 The study presents Ag2CrO4/Fe2O3/CeO2 ternary nanocomposite, based on Fe2O3/CeO2 binary composites, which demonstrated excellent photocatalytic performance in the photodegradation of methylene blue under solar irradiation. The Ag2CrO4/Fe2O3/CeO2 nanocomposites was orthorhombic, ilmenite, and cubic‐fluorite phases of Ag2CrO4, Fe2O3, and CeO2, respectively, according to the XRD examination. A strong bond between Ag2CrO4, Fe2O3, and CeO2 within the nanocomposite was demonstrated by the SEM and TEM investigations. Moreover, it was discovered that the coupling of Ag2CrO4 and Fe2O3 caused a red shift and moved CeO2 absorption edge from the UV to the visible spectrum. The reason behind this is that the band gap of CeO2 reduced 2.85 to 2.69 eV and the absorbance band intensity increased in visible region. Utilizing visible light, Ag2CrO4/Fe2O3/CeO2 ternary nanocomposites exhibit enhanced photocatalytic properties (98.90%) for the degradation of methylene blue (MB) within 100 min. The long‐term reliability and recyclability of the photocatalyst were explored through 3 successive cycles. An active radical quenching test was conducted to elucidate the involvement of O2− and OH which are the primary reactive species in the photocatalytic breakdown of MB. Ag2CrO4/Fe2O3/CeO2 ternary nanocomposites displayed notable improvements in photodegradation activity, making them well suited for the effective removal of hazardous dyes present in textile effluents.
An Efficient Photocatalytic and Antibacterial Performance of Ni/Ce–Codoped CdS Nanostructure under Visible Light Irradiation Rajendran Ranjith, Varadharajan Krishnakumar, Singaram Boobas, Jayaraman Venkatesan, Jeyaram Jayaprakash Chemistryselect, 2018 Abstract In the present work, the Ni/Ce‐codoped CdS Nanoparticles (NPs) were synthesized through a hydrothermal method. The phase structure, chemical state, chemical composition, morphology and optical properties of prepared samples were characterized using X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), Energy Dispersive X‐Ray Analysis (EDX), Fourier transform infrared spectroscopy (FT‐IR), High‐resolution transmission electron microscopy (HRTEM), UV‐Vis diffuse reflectance spectroscopy (DRS), Photoluminescence (PL) spectroscopy studies and their photocatalytic activities of Rhodamine B (RhB) degradation were studied under visible light irradiation. The Ni and Ce doped CdS NPs showed higher photocatalytic activity compared to that of pure CdS, and the activity was further enhanced by codoping of Ni and Ce into CdS. The enhancement of photocatalytic activity is due to the synergistic effect of Ni and Ce ions and with a narrowed bandgap, which may facilitate inhabitation of the photogenerated charge carrier recombination. Meanwhile, the possible photocatalytic mechanism of Ni and Ce codoped CdS was proposed on the basis of trapping experiments. Additionally, the antibacterial activity of Ni/Ce codoped CdS NPs was evaluated against E. coli and S. aureus .
Photocatalytic degradation of metronidazole and methylene blue by PVA-assisted Bi2WO6-CdS nanocomposite film under visible light irradiation Ranjith Rajendran, Krishnakumar Varadharajan, Venkatesan Jayaraman, Boobas Singaram, Jayaprakash Jeyaram Applied Nanoscience Switzerland, 2018 The enhanced photocatalytic performance of nanocomposite is synthesized via the hydrothermal method and characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FT-IR), UV–visible diffuse reflectance spectroscopy (UV–Vis DRS) and photoluminescence spectroscopy (PL). Under visible light irradiation, PVA assisted Bi2WO6–CdS nanocomposite film displayed enhanced photocatalytic efficiency and inhibition of photocorrosion as compared with pure CdS, pure Bi2WO6 and Bi2WO6–CdS composite. The PVA assisted Bi2WO6–CdS composite film catalyst showed stable catalytic performance until seven successive runs with 92% of methylene blue(MB) degradation, and easy to recover after degradation of organic pollutant. PVA assisted Bi2WO6–CdS nanocomposite film has optimal band edge position for superior photocatalytic degradation. Furthermore, the trapping experiment was carried out using different scavenger for active species. Among the active species, OH· are the most responsive species which play a vital role in the degradation of metronidazole and MB.