Design and synthesis of advanced engineered nanomaterials for photovoltaic, hydrogen generation, CO2 reduction, water purification, photo-/electro-catalysis and biomedical applications.
95
Scopus Publications
3630
Scholar Citations
34
Scholar h-index
74
Scholar i10-index
Scopus Publications
Alloyed shell engineered heavy-metal-free quantum dots for efficient photoelectrochemical hydrogen generation Umair Sohail, S. Kokilavani, Swedha Madhu, Manmeet Kaur Chhina, Kuljeet Singh Grewal, Aitazaz A. Farooque, Mandeep K. Chahal, Gurpreet Singh Selopal Chemical Engineering Journal, 2026 Heavy-metal-free quantum dots (QDs) based photoelectrochemical (PEC) water splitting has emerged as a promising approach for green hydrogen (H 2 ) production. However, a high density of surface defects/traps substantially limits efficient carrier dynamics and, consequently, overall device performance. In this work, we engineered Cu-Zn-In-Se (Cu-ZISe) QD surfaces by optimizing the alloyed ZnSeS (ZSeS) shell via aluminum (Al) doping to enhance optoelectronic properties and PEC H 2 production performance. The strategic growth of an alloyed ZSeS shell layer effectively passivates surface trap/defect states, promoting a favorable band alignment for efficient carrier dynamics. The incorporation of Al into the alloyed shell layer modulates the electronic band structure and induces the formation of a thin Al-oxide layer, thereby enhancing carrier separation, improving interfacial stability, and enhancing the efficiency of PEC devices. The optimized Cu-ZISe/ZSeS:Al core/alloyed shell QDs-based PEC with polysulfide electrolyte of 0.25 M Na 2 S and 0.35 M Na 2 SO 4 (pH = 14) exhibits a high photocurrent density of 13.91 mA/cm 2 at 1 V under one-sun illumination (AM 1.5G, 100 mW.cm −2 ), which is 65% superior compared to the core Cu-ZISe QDs-based PEC device (8.40 mA/cm 2 at 1 V). Importantly, the PEC device retained 87% and 36% of its initial performance after 2 h and 10 h continuous operation, respectively, under one-sun illumination. This work provides critical insights into alloyed-shell and dopant-assisted engineering strategies for advancing heavy-metal-free QDs-PEC systems toward practical green H 2 production and other QDs-based optoelectronic devices. • Al-ZnSeS alloyed shell passivates core QD surface traps and enhances stability. • Alloyed-shell Al-ZnSeS engineering improves interface quality and carrier dynamics. • PEC device with alloyed-shell QDs yield 65% higher performance than the control QDs. • Stable PEC device with 87% photocurrent retained after 7000 s continuous operation.
Recent advances in agricultural and marine waste-derived carbon dots for clean energy technologies Manmeet Kaur Chhina, Sukhjinder Singh, Swedha Madhu, Kuljeet Singh Grewal, Aitazaz A. Farooque, Gurpreet Singh Selopal Carbon, 2026 Quantum dots (QDs) are tiny-sized nanoparticles that offer distinct optical and electronic properties tunable with size/shape/composition, resulting from the quantum confinement effect. However, high-performing heavy-metal-based QDs (e.g., CdS, PbS) exhibit toxicity, raising concerns for large-scale applications. Carbon quantum dots (CQDs) and graphene quantum dots (GQDs) offer a safer alternative and possess remarkable properties, including biocompatibility, solution processability, and photostability. In recent years, carbon-rich agricultural and marine waste streams have been explored as effective precursors for synthesizing CQDs and GQDs. Additionally, these sources offer a promising alternative to traditional methods, making the synthesis process more environmentally friendly and cost-effective and promoting the circular economy. This review focuses on CQDs and GQDs derived solely from agricultural and marine waste, using different innovative top-down and bottom-up approaches, emphasizing their potential for scalability and environmental benefits. It provides a comprehensive review of the structural, morphological, optical, and fluorescence properties of CQDs and GQDs synthesized from agricultural and marine waste, emphasizing novel techniques for tuning their emission characteristics. A critical evaluation of the environmental, ecological, and toxicity aspects of CQDs and GQDs is presented. Lastly, the review highlights the applications of these CQDs and GQDs in clean energy technologies such as photovoltaic, green hydrogen production, and supercapacitors. The review concludes by outlining current limitations and future research opportunities for CQDs and GQDs derived from agricultural and marine waste, emphasizing their potential in cost-effective clean energy technologies and their role in promoting a circular economy by converting waste into value-added technologies. Carbon dots derived from agricultural and marine waste and their applications in supercapacitors, photovoltaics, and green hydrogen production via photo/electrocatalytic water splitting.
Hybrid TiN - MXene Photoanodes Drive Efficient Photoelectrochemical Water Splitting Parul Bansal, Gurpreet Singh Selopal, Kokilavani Shanmugasundaram, Hadis Zarrin, Federico Rosei Solar Rrl, 2026 We developed quantum dot (QD)‐sensitized hybrid TiO 2 nanocomposite photoanodes consisting of titanium‐based MXene (Ti 3 C 2 T x ) and titanium nitride (TiN) to promote synergy between the transport efficiency of MXenes and the plasmonic properties of TiN nanoparticles (NPs), toward enhancing the performance of photoelectrochemical (PEC) water splitting. MXenes sheets were synthesized at room temperature through delamination of an aluminum layer of the MAX phase of titanium aluminum carbide (Ti 3 AlC 2 ), and subsequently, nano‐sized dot‐like TiN NPs were incorporated through sonication and hydrothermal reaction. The PEC system based on the optimized TiO 2 ‐MXene‐TiN (MXene:TiN 1:4 wt%) hybrid network sensitized with CdS/CdSe/ZnS QDs yields a high photocurrent density of 15.80 mA cm −2 (at 1.0 V vs. the reversible hydrogen electrode [RHE]) under 1 sun illumination (AM 1.5G, 100 mW cm −2 ), which is almost double (~119%) as compared to the control TiO 2 /QDs device (7.20 mA cm −2 ). This significant enhancement in current density is attributed to the plasmonic effect of TiN NPs, improved charge carrier mobility and reduced recombination losses arising from the incorporated MXene sheets. This improvement in charge transport directly contributes to higher device efficiency, as demonstrated by faster transient voltage decay rates and prolonged carrier lifetimes in our measurements.
Highly luminescent all-inorganic lead-free AgInS2/ZnS QDs for multicolor and multistage anti-counterfeiting and encryption Pawan Kumar, Lei Jin, Gurpreet Singh Selopal, Omar Abdelkarim, Jiabin Liu, David Barba, Aycan Yurtsever, Zhiming M. Wang, Federico Rosei Nano Materials Science, 2026 We describe the design and synthesis of eco-friendly AgInS 2 /ZnS QDs via a facile one-pot synthesis method for application in encryption and anti-counterfeiting. A significant enhancement in PLQY (up to 45 %) and stability are observed with increased ZnS shell thickness. By varying the Ag:In composition from 1:2 to 1:0.25, the PL emission of AgInS 2 /ZnS QDs can be tuned from the visible to NIR (up to 900 nm). The ink fabricated with AgInS 2 /ZnS QDs shows greater thermal and water stability compared to AgInS 2 QDs. The patterns printed with these luminescent inks show excellent water and thermal stability and the capability to print on surfaces of any type and color, making them promising for practical use. These printed patterns are completely transparent/invisible in normal light and visible under 254 nm, 365 nm and 464 nm (blue LED) illumination. These features offer rapid responsive and multi-layered information encryption, and sophisticated anti-counterfeiting.
Advanced Surface Engineering and Passivation Strategies of Quantum Dots for Breaking Efficiency Barrier of Clean Energy Technologies: A Comprehensive Review Kokilavani S., Gurpreet Singh Selopal Advanced Functional Materials, 2026 Abstract Colloidal quantum dots (QDs) have garnered significant attention for their unique potential in clean energy technologies, owing to their tunable optoelectronic properties. However, the presence of surface traps/defects is a major limitation, adversely affecting charge dynamics, optical properties, and overall device performance. This review presents a comprehensive understanding of the origin and intrinsic nature of these surface defects, focusing on how they influence the performance of QDs‐based devices. Recent advances in surface engineering strategies, including solid‐phase and solution‐phase ligand exchange strategies, are delved into, as they play a crucial role in mitigating the impact of surface defects and allow tuning of QDs structural and optoelectronic properties. Furthermore, the review addresses the role of purification procedures and sensitization techniques in enhancing the QDs properties. The recent progress in the development of surface‐engineered QDs‐based clean energy technologies, including photovoltaic (PV), luminescent solar concentrators (LSC) for electricity, and photoelectrochemical (PEC) for green hydrogen production, where improvements in both efficiency and stability of these technologies are thoroughly discussed. The practical challenges and hurdles in scaling up these approaches are also critically examined and future directions are explored to inspire further advances in the rational design of QDs for solar energy conversion and other optoelectronic technologies.
Thermal and Mechanical Properties of Advanced Ceramics Pankaj Kumar, Neha Thakur, Jasmeet Kaur, Manmeet Kaur Chhina, Gurpreet Singh Selopal Multifunctional and Smart Materials Advances in Sustainable Engineering Applications, 2026 Advanced ceramics are emerging as indispensable materials in modern engineering and technology due to their exceptional thermal and mechanical properties. These materials, characterized by high hardness, superior wear resistance, and excellent thermal stability, are extensively utilized in aerospace, automotive, electronics, and biomedical applications. Their ability to withstand extreme temperatures, resist thermal shock, and exhibit low thermal expansion makes them ideal for high-temperature environments. Mechanically, advanced ceramics demonstrate remarkable strength-to-weight ratios and resistance to deformation under stress, enabling their use in demanding structural applications. This chapter explores the intrinsic and extrinsic factors influencing the thermal and mechanical properties of advanced ceramics, such as grain size, porosity, and chemical composition. Furthermore, the impact of processing techniques, including sintering and hot pressing, on these properties is discussed. Emphasis is placed on the interplay between thermal conductivity, fracture toughness, and elastic modulus, which governs the material’s performance under operational conditions. Applications of advanced ceramics in cutting-edge technologies, such as thermal barrier coatings, engine components, and medical implants, are also highlighted. Challenges related to brittleness, machining, and cost-effectiveness are addressed, along with recent advancements in nano-structuring and composite fabrication that aim to overcome these limitations.
Renewable hydrogen from seafood shell waste for long-term energy storage on islands Vasudha Kaura, Misbaudeen Aderemi Adesanya, Gurpreet Singh Selopal, Kuljeet Singh Grewal Energy Conversion and Management, 2025 This study explores the potential of renewable seafood shell waste for sustainable energy conversion and long-term storage, particularly for isolated communities. Despite its rich chitin and protein composition, seafood shell waste is often neglected. The research evaluates and compares three advanced gasification technologies: biomass gasification, plasma gasification, and chemical looping, to convert seafood shell waste into syngas and H 2 . The study uses validated Aspen Plus models to optimize feedstock blending ratios and operational parameters. Results show that feedstocks high in lobster and shrimp shells yield higher H 2 outputs and improved syngas quality compared to clam-dominated blends. For instance, biomass gasification at 1200 °C yielded approximately 500 kg/h of H 2 from pure lobster or shrimp feeds, while plasma gasification at 4500 °C achieved yields near 730 kg/h. Plasma gasification, when integrated with fuel cell conversion and heat recovery systems, can generate over 10,000 kWh during a 6-hour peak period, enough to power over 1100 single-detached homes. Its levelized cost of hydrogen (LCOH) varies from $5.72-$8.37/kg H 2 , making it less expensive than chemical looping and biomass gasification. Plasma gasification also has the lowest global warming potential (GWP) at 6 kg CO 2 e/kg H 2 . Combining plasma gasification with carbon capture and storage may reduce GWP to 0.3 kg CO 2 e/kg H 2 and can be further explored. These findings underscore the technical and economic viability of converting seafood shell renewable waste into H 2 , advancing sustainable energy transitions, and supporting net-zero goals.
Graphene below the percolation threshold in TiO2 for dye-sensitized solar cells Kadiatou Therese Dembele, Gurpreet Singh Selopal, Riccardo Milan, Charles Trudeau, Daniele Benetti, Afsoon Soudi, Marta Maria Natile, Giorgio Sberveglieri, Sylvain Cloutier, Isabella Concina, Federico Rosei, Alberto Vomiero Journal of Materials Chemistry A, 2015
Graphene as transparent front contact for dye sensitized solar cells Gurpreet Singh Selopal, Riccardo Milan, Luca Ortolani, Vittorio Morandi, Rita Rizzoli, Giorgio Sberveglieri, Giulio Paolo Veronese, Alberto Vomiero, Isabella Concina Solar Energy Materials and Solar Cells, 2015
Alloyed shell engineered heavy-metal-free quantum dots for efficient photoelectrochemical hydrogen generation U Sohail, S Kokilavani, S Madhu, MK Chhina, KS Grewal, AA Farooque, ... Chemical Engineering Journal, 177139 , 2026 2026
Advancing sustainable agriculture in Atlantic Canada through HYDRA-SE: A hybrid decision and regression stacked ensemble for yield prediction A Kaur, R Malekian, GS Randhawa, AA Farooque, EH Garmdareh, ... Advanced Engineering Informatics 71, 104433 , 2026 2026 Citations: 1
Hybrid TiN‐MXene Photoanodes Drive Efficient Photoelectrochemical Water Splitting P Bansal, GS Selopal, K Shanmugasundaram, H Zarrin, F Rosei Solar RRL 10 (5), e202500820 , 2026 2026
Recent advances in agricultural and marine waste-derived carbon dots for clean energy technologies MK Chhina, S Singh, S Madhu, KS Grewal, AA Farooque, GS Selopal Carbon, 121444 , 2026 2026
The Application of Carbon Dots in Crops for Sustainable Agriculture X Li, L Jin, GS Selopal, F Rosei, J Li ChemistryEurope 4 (2), e202500224 , 2026 2026
Renewable hydrogen from seafood shell waste for long-term energy storage on islands V Kaura, MA Adesanya, GS Selopal, KS Grewal Energy Conversion and Management 345, 120331 , 2025 2025 Citations: 1
Sugar kelp application for sustainable potato production in Prince Edward Island: Impacts on soil, greenhouse gas emissions, and yield A Khan, R Malekian, TJ Esau, GS Selopal, KS Grewal Field Crops Research 333, 110068 , 2025 2025 Citations: 1
Synergistic effect of Cu: Zn-In-Se2 QDs/Fe3O4 hybrid mesoporous films optimization and magnetic fields for solar-driven wastewater purification S Madhu, U Sohail, SY Kim, G Abdelmageed, NY Doumon, GI Koleilat, ... Sustainable Materials and Technologies, e01745 , 2025 2025 Citations: 1
Recent progress in triboelectric nano-generators: Powering the future of smart agriculture S Singh, MK Chhina, T Esau, KS Grewal, AA Farooque, GS Selopal Nano Energy, 111502 , 2025 2025 Citations: 3
Unlocking durability and efficiency in perovskite solar cells via sulfur-based thiazoline engineered passivation G Abdelmageed, A El-Halaby, K Tantawy, AFG Leontowich, GS Selopal, ... Journal of Materials Science: Materials in Energy 1 (1), 4 , 2025 2025 Citations: 1
In-situ surface engineering of ternary eco-friendly QDs for enhanced photoelectrochemical hydrogen production S Kokilavani, GS Selopal, L Jin, F Vidal, F Rosei Chemical Engineering Journal, 169245 , 2025 2025 Citations: 2
Cutting-edge advances in W-based chalcogenides for efficient photocatalytic hydrogen evolution L Phor, M Afzal, V Meena, J Malik, SM Simon, GS Selopal, S Chahal Sustainable Materials and Technologies 45, e01514 , 2025 2025 Citations: 4
Eco‐Friendly Quantum Dots for Solar‐Driven H 2 Production: Structural Engineering to Performance Optimization U Sohail, S Kokilavani, KS Grewal, AA Farooque, GI Koleilat, GS Selopal EcoMat 7 (9), e70026 , 2025 2025 Citations: 3
Marine waste-assisted hybrid nano-fertilizers for controlled nutrient release MJ Khan, MK Chhina, S Jayakumar, KI Al-Murghrabi, KS Grewal, ... MRS Advances, 1-9 , 2025 2025
Carbon quantum dots: Synthesis via hydrothermal processing, doping strategies, integration with photocatalysts, and their application in photocatalytic hydrogen production Z Wang, R Changotra, M Dasog, GS Selopal, J Yang, QS He Sustainable Materials and Technologies 44, e01386 , 2025 2025 Citations: 44
Magnetic Field Enhanced Photoelectrochemical Water Splitting: Unravelling the Role of the TiO 2 Photoanode V Venkataraman, TK Johal, GS Selopal, D Yang, L Jin, F Vetrone, F Rosei 247th ECS Meeting (May 18-22, 2025) , 2025 2025
Textile wastewater treatment using ternary hybrid nanocomposites of hexagonal NiO with MWCNT/GO S Subramanyam, L Phor, A Singh, S Dahiya, GS Selopal, A Kumar, ... Journal of Water Process Engineering 71, 107149 , 2025 2025 Citations: 9
Harnessing the Synergetic Effects of Ag, Mn Dopants in Eco‐Friendly Ultraviolet Selective Quantum Dots for Luminescent Solar Concentrators L Jin, E Hamzehpoor, GS Selopal, J Liu, P Kumar, D Benetti, X Tong, ... Small Methods 9 (2), 2301695 , 2025 2025 Citations: 17
Advanced surface engineering and passivation strategies of quantum Dots for breaking efficiency barrier of clean energy technologies: a comprehensive review S Kokilavani, GS Selopal Adv Mater , 2025 2025 Citations: 7
Valorization and repurposing of seafood waste to next-generation carbon nanofertilizers R Javed, U Sharafat, A Rathnayake, L Galagedara, GS Selopal, ... Bioresource Technology 416, 131783 , 2025 2025 Citations: 18
MOST CITED SCHOLAR PUBLICATIONS
Core/shell quantum dots solar cells GS Selopal, H Zhao, ZM Wang, F Rosei Advanced Functional Materials 30 (13), 1908762 , 2020 2020 Citations: 295
Hybrid Carbon Nanotubes–TiO 2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells KT Dembele, GS Selopal, C Soldano, R Nechache, JC Rimada, I Concina, ... The Journal of Physical Chemistry C 117 (28), 14510-14517 , 2013 2013 Citations: 181
Near‐infrared, heavy metal‐free colloidal “Giant” core/shell quantum dots X Tong, XT Kong, Y Zhou, F Navarro‐Pardo, GS Selopal, S Sun, ... Advanced Energy Materials 8 (2), 1701432 , 2018 2018 Citations: 157
Heavy metal-free, near-infrared colloidal quantum dots for efficient photoelectrochemical hydrogen generation X Tong, Y Zhou, L Jin, K Basu, R Adhikari, GS Selopal, H Zhao, S Sun, ... Nano Energy 31, 441-449 , 2017 2017 Citations: 149
Highly stable colloidal “giant” quantum dots sensitized solar cells GS Selopal, H Zhao, X Tong, D Benetti, F Navarro‐Pardo, Y Zhou, ... Advanced Functional Materials 27 (30), 1701468 , 2017 2017 Citations: 142
Metal-free organic dyes for TiO 2 and ZnO dye-sensitized solar cells GS Selopal, HP Wu, J Lu, YC Chang, M Wang, A Vomiero, I Concina, ... Scientific reports 6 (1), 18756 , 2016 2016 Citations: 102
Controlling photoinduced electron transfer from PbS@ CdS core@ shell quantum dots to metal oxide nanostructured thin films H Zhao, Z Fan, H Liang, GS Selopal, BA Gonfa, L Jin, A Soudi, D Cui, ... Nanoscale 6 (12), 7004-7011 , 2014 2014 Citations: 100
Graphene below the percolation threshold in TiO 2 for dye-sensitized solar cells KT Dembele, GS Selopal, R Milan, C Trudeau, D Benetti, A Soudi, ... Journal of Materials Chemistry A 3 (6), 2580-2588 , 2015 2015 Citations: 92
Review of hybrid 1D/2D photocatalysts for light-harvesting applications A Nawaz, S Goudarzi, MA Asghari, S Pichiah, GS Selopal, F Rosei, ... ACS Applied Nano Materials 4 (11), 11323-11352 , 2021 2021 Citations: 88
“Green”, gradient multi-shell CuInSe2/(CuInSexS1-x) 5/CuInS2 quantum dots for photo-electrochemical hydrogen generation F Li, M Zhang, D Benetti, L Shi, LV Besteiro, H Zhang, J Liu, GS Selopal, ... Applied Catalysis B: Environmental 280, 119402 , 2021 2021 Citations: 84
ZnO@SnO 2 engineered composite photoanodes for dye sensitized solar cells R Milan, GS Selopal, M Epifani, MM Natile, G Sberveglieri, A Vomiero, ... Scientific reports 5 (1), 14523 , 2015 2015 Citations: 83
Efficient and stable photoelectrochemical hydrogen generation using optimized colloidal heterostructured quantum dots H Zhang, LV Besteiro, J Liu, C Wang, GS Selopal, Z Chen, D Barba, ... Nano Energy 79, 105416 , 2020 2020 Citations: 71
Effect of blocking layer to boost photoconversion efficiency in ZnO dye-sensitized solar cells GS Selopal, N Memarian, R Milan, I Concina, G Sberveglieri, A Vomiero ACS Applied Materials & Interfaces 6 (14), 11236-11244 , 2014 2014 Citations: 64
Efficient solar-driven hydrogen generation using colloidal heterostructured quantum dots K Wang, X Tong, Y Zhou, H Zhang, F Navarro-Pardo, GS Selopal, G Liu, ... Journal of materials chemistry A 7 (23), 14079-14088 , 2019 2019 Citations: 61
Synergistic Effect of Plasmonic Gold Nanoparticles Decorated Carbon Nanotubes in Quantum Dots/TiO2 for Optoelectronic Devices GS Selopal, M Mohammadnezhad, LV Besteiro, O Cavuslar, J Liu, ... Advanced Science, 2001864 , 2020 2020 Citations: 59
Graphene as transparent front contact for dye sensitized solar cells GS Selopal, R Milan, L Ortolani, V Morandi, R Rizzoli, G Sberveglieri, ... Solar Energy Materials and Solar Cells 135, 99-105 , 2015 2015 Citations: 58
Heavy‐metal‐free colloidal quantum dots: progress and opportunities in solar technologies L Jin, GS Selopal, X Tong, DF Perepichka, ZM Wang, F Rosei Advanced Materials 36 (33), 2402912 , 2024 2024 Citations: 57
Environmentally friendly Mn-alloyed core/shell quantum dots for high-efficiency photoelectrochemical cells R Wang, X Tong, AI Channa, Q Zeng, J Sun, C Liu, X Li, J Xu, F Lin, ... Journal of Materials Chemistry A 8 (21), 10736-10741 , 2020 2020 Citations: 57
Visible and near-infrared, multiparametric, ultrasensitive nanothermometer based on dual-emission colloidal quantum dots J Liu, H Zhang, GS Selopal, S Sun, H Zhao, F Rosei Acs Photonics 6 (10), 2479-2486 , 2019 2019 Citations: 57
Interfacial engineering in colloidal “giant” quantum dots for high-performance photovoltaics GS Selopal, H Zhao, G Liu, H Zhang, X Tong, K Wang, J Tang, X Sun, ... Nano Energy 55, 377-388 , 2019 2019 Citations: 56