Structural and Dielectric Properties of PVDF/6A Clay Nanocomposites Chetan V. Chanmal, Sushil S. Bandgar, Chagan D. Mungamode, Sanjeev D. Chavan, Shailesh G. Pawar, Ramesh N. Mulik, Vikas L. Mathe, Jyoti P. Jog Macromolecular Symposia, 2021 Abstract The paper describes the study of structural and dielectric properties of PVDF blended with organically modified clay. The PVDF/clay nanocomposites are prepared by simple melt mixing method. The prepared nanocomposites are characterized for structural and dielectric properties. The structural characterization done using X‐ray diffraction and infra‐red spectroscopy techniques indicates the crystallization of ferroelectric β phase in nanocomposites. The dielectric study shows the composition‐dependent significant enhancement in the dielectric permittivity, particularly in the low‐frequency region. The enhancement in the dielectric permittivity is explained on the basis of increase in the conductivity and formation of minicapacitor‐like network in the nanocomposites. The dielectric loss spectra of PVDF shows two relaxations corresponding to the glass transition temperature and crystalline relaxation. In case of PVDF/Clay nanocomposites, the dielectric relaxation corresponding to the crystalline relaxation completely disappears, which is attributed to the dielectric manifestation of ferroelectric β phase in nanocomposites. The observed dielectric permittivity data can be very well fitted using Vo‐Shi model, which takes contribution of interphase to the dielectric permittivity. The enhancement in the dielectric permittivity along with ferroelectric β phase in PVDF/clay nanocomposites brings the potential application in energy storage devices.
Photoluminescence in Eu 3+ activated Li 4 MoO 5 phosphors B. V. Tupte, M. M. Bhave, C. D. Mungmode, D. H. Gahane, S. V. Moharil Aip Conference Proceedings, 2019 In the present work Li4-xMoO5:xEu3+ (x=0.01, 0.03, 0.05 & 0.07) novel phosphors are prepared using Combustion synthesis method and their luminescent properties were investigated. The excitation spectra consist of broad charge transfer bands in the short-wave UV region of Mo6+→O2- and Eu3+→O2- with two sharp lines around 395nm and 465nm of the Eu3+ 4f excitation transitions. The results indicated that the characteristic emissions of MoO4 are quenched absolutely and phosphor exhibited intense red photoluminescence at 617 nm when excited by the light of 395nm, which was attributed to the electric dipole energy transition of 5D0→7F2 transition of Eu3+. The optimal doping concentration for Eu3+ ions is found to be 3 mol% and the quenching mechanism is attributed to the dipole-dipole interaction.In the present work Li4-xMoO5:xEu3+ (x=0.01, 0.03, 0.05 & 0.07) novel phosphors are prepared using Combustion synthesis method and their luminescent properties were investigated. The excitation spectra consist of broad charge transfer bands in the short-wave UV region of Mo6+→O2- and Eu3+→O2- with two sharp lines around 395nm and 465nm of the Eu3+ 4f excitation transitions. The results indicated that the characteristic emissions of MoO4 are quenched absolutely and phosphor exhibited intense red photoluminescence at 617 nm when excited by the light of 395nm, which was attributed to the electric dipole energy transition of 5D0→7F2 transition of Eu3+. The optimal doping concentration for Eu3+ ions is found to be 3 mol% and the quenching mechanism is attributed to the dipole-dipole interaction.
Photoluminescence of orthorhombic Li 2 Mg 2 (MoO 4 ) 3 crystal doped with Yb 3+ ions M. M. Bhave, B. V. Tupte, C. D. Mungmode, D. H. Gahane, S. V. Moharil Aip Conference Proceedings, 2019 The lithium magnesium molybdate Li2-2xMg2+x (MoO4)3: xYb3+ (x= 0.01, 0.03, 0.05 and 0.07) phosphors were prepared by combustion synthesis method at 750 °C. The phases of prepared phosphors were confirmed by X-ray diffraction pattern and luminescent properties of phosphor materials were systematically studied. Li2Mg2(MoO4)3 has an orthorhombic symmetry and has discovered a three-dimensional framework consisting of metal-oxygen octahedra and trigonal prisms (where Li and Mg reside) that are interconnected by MoO4 tetrahedra. As a result of host absorption of Li2Mg2(MoO4)3, a broad excitation band ranging from 200 to 400 nm is recorded when Yb3+ emission was observed, photoluminescence spectra measured suggests the efficient energy transfer from host to Yb3+ ions. Upon ultraviolet excitation, an intense near-infrared emission of Yb3+ (2F5/2 → 2F7/2) around 986 nm is observed in Li2Mg2(MoO4)3: Yb3+. All the results indicate that Yb3+ doped Li2Mg2(MoO4)3 crystal can serve as UV excited phosphor that is a promising candidate as an associated application for the tunable laser.
Photoluminescence Characteristics Of YCa4O (BO3) 3: Dy3+ Phosphor For w-LEDs Prepared by Combustion Techniques PR Yawale, DH Gahane, IS Mohurley, CD Mungmode, CM Nandanwar Journal of Optics, 1-7 , 2024 2024 Citations: 3
Synthesis and photoluminescence study of Sm 3+ -activated KBaY(BO 3 ) 2 phosphor for solid-state lighting PR Yawale, DH Gahane, IS Mohurley, CM Nandanwar, CD Mungmode Journal of Optics 53 (5), 5024-5030 , 2024 2024 Citations: 8
Eu 3+ ion-doped Sr 3 Y(AlO) 3 (BO 3 ) 4 novel phosphor: synthesis and optical properties PR Yawale, DH Gahane, IS Mohurley, CD Mungmode, CM Nandanwar Journal of Optics 53 (5), 4325-4330 , 2024 2024 Citations: 11
Study of Photoluminescence Properties of Li2M(MoO4)2:Yb3+ (M= Ca, Sr) Phosphor DHG B.V. Tupte, M.M. Bhave, C.D. Mungmode International Journal of Advance and Applied Research 5 (27), 70-74 , 2024 2024
Blue-yellow emitting Dy 3+ doped K 2 Y 2 B 2 O 7 novel phosphor for WLED application PR Yawale, CD Mungmode, DH Gahane, IS Mohurley Journal of Optics 53 (3), 2704-2708 , 2024 2024 Citations: 4
Photoluminescence investigation of novel KCaPO4:Sm3+ phosphors for n‐UV based solid state lighting Prepared by wet chemical synthesis SJD C. M. Nandanwar, N. S. Kokode, A. V. Nande, C. D. Mungmode, A. N ... Optical and Quantum Electronics 55, 1173 , 2023 2023 Citations: 14
Synthesis and photoluminescence in Eu2+ activated alkali/alkaline earth halides and chlorophosphate blue phosphors CD Mungmode, DH Gahane Phosphor Handbook, 135-153 , 2023 2023
Thermoluminescence Studies in Europium Doped KSr 2 Br 5 and CsBa 2 I 5 Halide Phosphors CD Mungmode, DH Gahane, CV Chanmal, SV Moharil Techno-Societal 2016, International Conference on Advanced Technologies for … , 2022 2022
Peculiar synthesis and photoluminescence characterization of series of (Ca 2− X )PO 4 Cl:xEu 2+ phosphor CD Mungmode, DH Gahane, CV Chanmal, BV Tupte, MM Bhave, ... Journal of Optics 51 (4), 1065-1070 , 2022 2022 Citations: 6
Structural and dielectric properties of PVDF/6A clay nanocomposites CV Chanmal, SS Bandgar, CD Mungamode, SD Chavan, SG Pawar, ... Macromolecular Symposia 400 (1), 2100032 , 2021 2021 Citations: 8
Photoluminescence Properties of Some Molybdate Phosphors Containing Bismuth SVM B.V. Tupte1, D.H. Gahane, M.M. Bhave, C.D. Mungmode International Journal of Scientific Research in Science and Technology (http … , 2021 2021
Synthesis and Characterization Zinc Oxide Thin Films Prepared by Chemical Bath Deposition RNM C. V. Chanmal, S. S. Bandgar, C. D. Mungamode, S. G. Pawar International Journal of Scientific Research in Science and Technology (http … , 2021 2021
Photoluminescence of orthorhombic Li 2 Mg 2 (MoO 4 ) 3 crystal doped with Yb 3+ ions MM Bhave, BV Tupte, CD Mungmode, DH Gahane, SV Moharil AIP Conference Proceedings 2104 (1), 030038 , 2019 2019 Citations: 1
Photoluminescence in Eu 3+ activated Li 4 MoO 5 phosphors BV Tupte, MM Bhave, CD Mungmode, DH Gahane, SV Moharil AIP Conference Proceedings 2104 (1), 020008 , 2019 2019
Synthesis and luminescent properties of Eu 3+ activated Li 3 Sr 2 La 3 (MoO 4 ) 8 red emitting phosphors DH Gahane, BV Tupte, PW Yawalkar, MM Bhave, CD Mungmode, ... AIP Conference Proceedings 2104 (1), 020009 , 2019 2019 Citations: 1
Luminescence in Eu2+ activated (Ca5-xSrx)(PO4) 3Cl (x= 0.1, 2.4) phosphors CD Mungmode, DH Gahane, BV Tupte, MM Bhave, SV Moharil Materials Today: Proceedings 15, 555-559 , 2019 2019 Citations: 5
On the preparation and photoluminescence of Eu 2+-doped alkaline-earth apatites M 5 (PO 4) 3 Cl (M= Ca, Sr, Ba) CD Mungmode, DH Gahane, SV Moharil Journal of Optics, 1-5 , 2018 2018 Citations: 6
Wet chemical synthesis and luminescence in Ca 5 (PO 4 ) 3 M:Eu 2+ (M = Br, I) phosphors for solid state lighting CD Mungmode, DH Gahane, SV Moharil AIP Conference Proceedings 1953 (1), 060037 , 2018 2018 Citations: 2
Combustion Synthesis and Luminescent Properties of Red-Emitting Sr4-x Al6MoO16: xEu3+ Phosphors BV Tupte, MM Bhave, CD Mungmode, DH Gahane, SV Moharil Int. J. Sci. Res. Sci. Eng. 4, 319-323 , 2018 2018 Citations: 3
MOST CITED SCHOLAR PUBLICATIONS
Photoluminescence investigation of novel KCaPO4:Sm3+ phosphors for n‐UV based solid state lighting Prepared by wet chemical synthesis SJD C. M. Nandanwar, N. S. Kokode, A. V. Nande, C. D. Mungmode, A. N ... Optical and Quantum Electronics 55, 1173 , 2023 2023 Citations: 14
Eu 3+ ion-doped Sr 3 Y(AlO) 3 (BO 3 ) 4 novel phosphor: synthesis and optical properties PR Yawale, DH Gahane, IS Mohurley, CD Mungmode, CM Nandanwar Journal of Optics 53 (5), 4325-4330 , 2024 2024 Citations: 11
Synthesis and photoluminescence study of Sm 3+ -activated KBaY(BO 3 ) 2 phosphor for solid-state lighting PR Yawale, DH Gahane, IS Mohurley, CM Nandanwar, CD Mungmode Journal of Optics 53 (5), 5024-5030 , 2024 2024 Citations: 8
Structural and dielectric properties of PVDF/6A clay nanocomposites CV Chanmal, SS Bandgar, CD Mungamode, SD Chavan, SG Pawar, ... Macromolecular Symposia 400 (1), 2100032 , 2021 2021 Citations: 8
Peculiar synthesis and photoluminescence characterization of series of (Ca 2− X )PO 4 Cl:xEu 2+ phosphor CD Mungmode, DH Gahane, CV Chanmal, BV Tupte, MM Bhave, ... Journal of Optics 51 (4), 1065-1070 , 2022 2022 Citations: 6
On the preparation and photoluminescence of Eu 2+-doped alkaline-earth apatites M 5 (PO 4) 3 Cl (M= Ca, Sr, Ba) CD Mungmode, DH Gahane, SV Moharil Journal of Optics, 1-5 , 2018 2018 Citations: 6
Luminescence in Eu2+ activated (Ca5-xSrx)(PO4) 3Cl (x= 0.1, 2.4) phosphors CD Mungmode, DH Gahane, BV Tupte, MM Bhave, SV Moharil Materials Today: Proceedings 15, 555-559 , 2019 2019 Citations: 5
Synthesis and Photoluminescence of Blue Emitting Ca5 (PO4) 3Cl Phosphor CD Mungmode, DH Gahane, SV Moharil International Journal of Luminescence and Application , 2015 2015 Citations: 5
Blue-yellow emitting Dy 3+ doped K 2 Y 2 B 2 O 7 novel phosphor for WLED application PR Yawale, CD Mungmode, DH Gahane, IS Mohurley Journal of Optics 53 (3), 2704-2708 , 2024 2024 Citations: 4
Luminescence characteristics of Eu2+ activated RbSr2Br5 phosphor C Mungmode, D Gahane, S Moharil Proceeding of National Conference on “Advanced Materials, 161-163 , 2014 2014 Citations: 4
Photoluminescence Characteristics Of YCa4O (BO3) 3: Dy3+ Phosphor For w-LEDs Prepared by Combustion Techniques PR Yawale, DH Gahane, IS Mohurley, CD Mungmode, CM Nandanwar Journal of Optics, 1-7 , 2024 2024 Citations: 3
Combustion Synthesis and Luminescent Properties of Red-Emitting Sr4-x Al6MoO16: xEu3+ Phosphors BV Tupte, MM Bhave, CD Mungmode, DH Gahane, SV Moharil Int. J. Sci. Res. Sci. Eng. 4, 319-323 , 2018 2018 Citations: 3
Bionano Frontier DH Gahane, BM Bahirwar, CD Mungmode, SV Moharil Special Issue 38 , 2011 2011 Citations: 3
Wet chemical synthesis and luminescence in Ca 5 (PO 4 ) 3 M:Eu 2+ (M = Br, I) phosphors for solid state lighting CD Mungmode, DH Gahane, SV Moharil AIP Conference Proceedings 1953 (1), 060037 , 2018 2018 Citations: 2
Photoluminescence of orthorhombic Li 2 Mg 2 (MoO 4 ) 3 crystal doped with Yb 3+ ions MM Bhave, BV Tupte, CD Mungmode, DH Gahane, SV Moharil AIP Conference Proceedings 2104 (1), 030038 , 2019 2019 Citations: 1
Synthesis and luminescent properties of Eu 3+ activated Li 3 Sr 2 La 3 (MoO 4 ) 8 red emitting phosphors DH Gahane, BV Tupte, PW Yawalkar, MM Bhave, CD Mungmode, ... AIP Conference Proceedings 2104 (1), 020009 , 2019 2019 Citations: 1
Development of blue phosphor for white light emitting diode DH Gahane, CD Mungmode, SV Moharil bionano Frontier, 38-40 , 2011 2011 Citations: 1
Study of Photoluminescence Properties of Li2M(MoO4)2:Yb3+ (M= Ca, Sr) Phosphor DHG B.V. Tupte, M.M. Bhave, C.D. Mungmode International Journal of Advance and Applied Research 5 (27), 70-74 , 2024 2024
Synthesis and photoluminescence in Eu2+ activated alkali/alkaline earth halides and chlorophosphate blue phosphors CD Mungmode, DH Gahane Phosphor Handbook, 135-153 , 2023 2023
Thermoluminescence Studies in Europium Doped KSr 2 Br 5 and CsBa 2 I 5 Halide Phosphors CD Mungmode, DH Gahane, CV Chanmal, SV Moharil Techno-Societal 2016, International Conference on Advanced Technologies for … , 2022 2022