Dr. A. JAMAL ABDUL NASSER

@jmc.edu

Associate Professor, Department of Chemistry
Jamal Mohamed College (Autonomous), Tiruchirappall

Dr. A. JAMAL ABDUL NASSER


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https://researchid.co/ajamalabdulnasser
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Scopus Publications

Scopus Publications

  • Crystal structure, DFT and Hirshfeld surface analysis of 2-amino-4-(2-chlorophenyl)-7-hydroxy-4H-benzo[1,2-b]pyran-3-carbonitrile
    M. Beemarao, S. Silambarasan, A. Jamal Abdul Nasser, M. Purushothaman, K. Ravichandran
    Acta Crystallographica Section E Crystallographic Communications, 2019
    The benzopyran ring of the title compound, C16H11ClN2O2, is planar [maximum deviation = 0.079 (2) Å] and is almost perpendicular to the chlorophenyl ring [dihedral angle = 86.85 (6)°]. In the crystal, N—H...O, O—H...N, C—H...O and C—H...Cl hydrogen bonds form inter- and intramolecular interactions. The DFT/B3LYP/6-311G(d,p) method was used to determine the HOMO–LUMO energy levels. The molecular electrostatic potential surfaces were investigated by Hirshfeld surface analysis and two-dimensional fingerprint plots were used to analyse the intermolecular interactions in the molecule.
  • Crystal structures of two 4H-chromene derivatives: 2-amino-3-cyano-4-(3,4-dichlorophenyl)-7-hydroxy-4H-benzo[1,2-b]pyran 1,4-dioxane monosolvate and 2-amino-3-cyano-4-(2,6-dichlorophenyl)-7-hydroxy-4H-benzo[1,2-b]pyran
    S. Silambarasan, A. Jamal Abdul Nasser, T. Mohandas
    Acta Crystallographica Section E Crystallographic Communications, 2019
    In the title compounds, C16H9Cl2N2O2·C4H8O2 and C16H9Cl2N2O2, the bicyclic 4H-chromene cores are nearly planar with maximum deviations of 0.081 (2) and 0.087 (2) Å. In both structures, the chromene derivative molecules are linked into centrosymmetric dimers by pairs of N—H...O hydrogen bonds, forming R2 2 (16) motifs. These dimers are further linked in the 3,4-dichlorophenyl derivative by N—H...N hydrogen bonds into double layers parallel to (100) and in the 2,6-dichlorophenyl derivative by O—H...N hydrogen bonds into ribbons along the [1\\overline{1}0] direction. In the 3,4-dichlorophenyl derivative, the 1,4-dioxane solvent molecules are connected to the chromene molecules via O—H...O hydrogen bonds.
  • Comparative study of N-[(4-methoxyphenyl) (morpholin-4-yl)methyl]acetamide (MMPA) and N-[morpholin-4-yl(phenyl)methyl]acetamide (MPA) as corrosion inhibitors for mild steel in sulfuric acid solution
    A. Jamal Abdul Nasser, M. Anwar Sathiq
    Arabian Journal of Chemistry, 2017
    Two Mannich bases namely, N -[(4-methoxyphenyl)(morpholin-4-yl)methyl]acetamide (MMPA) and N -[morpholin-4-yl(phenyl)methyl]acetamide (MPA) were synthesized and their influence on the inhibition of corrosion of mild steel in 1.0 M H 2 SO 4 was investigated by weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and FT-IR spectroscopy. The weight loss measurements showed that these inhibitors have excellent inhibiting effect at a concentration of 0.01 M. The inhibitor efficiency was found to depend on both concentration and molecular structure of the inhibitor. Both the compounds have been found to be relatively good inhibitors. Potentiodynamic polarization curves revealed that the studied inhibitors represent a mixed-type, predominantly cathodic control. An equivalent circuit is suggested based on an analysis of EIS data. The negative value of standard free energy of adsorption in the presence of inhibitor suggests spontaneous adsorption of inhibitors on the mild steel surface. The activation energy of corrosion and other thermodynamic parameters were calculated to elaborate the mechanism of corrosion inhibition. The Temkin isotherm was found to provide an accurate description of the adsorption behavior of the inhibitors. Surface analysis using scanning electron microscope (SEM) shows a significant morphological improvement on the mild steel surface with the addition of inhibitors. FT-IR spectra revealed the interaction between inhibitor molecules and mild steel surface.
  • N-[Morpholin-4-yl(phenyl)methyl]acetamide as corrosion inhibitor for mild steel in hydrochloric acid medium
    A. Jamal Abdul Nasser, M. Anwar Sathiq
    Arabian Journal of Chemistry, 2016
    The inhibiting effect and adsorption behavior of N -[morpholin-4-yl(phenyl)methyl]acetamide (MPA) on mild steel in hydrochloric acid solution were studied by weight loss measurements, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy techniques. The inhibitor showed greater than 90% inhibition efficiency at 0.01 M. Potentiodynamic polarization studies showed that the inhibition action is concentration dependent, at low concentration anodic, higher concentration cathodic, inhibition predominant. Electrochemical impedance spectroscopy (EIS) confirmed that changes in the impedance parameters ( R t and C dl ) are due to surface adsorption. The inhibition efficiencies obtained from weight loss measurements and electrochemical tests were in good agreement. The adsorption process of MPA at the mild steel/hydrochloric acid solution interface is described by Langmuir adsorption isotherm model. The negative value of standard free energy of adsorption in the presence of inhibitor suggests spontaneous adsorption of MPA molecule on the mild steel surface. The activation energy of corrosion and other thermodynamic parameters were calculated to elaborate the mechanism of corrosion inhibition.
  • Anti-Inflammatory Activity of New Series of 1,4-Dihydropyridine Derivatives
    A. Idhayadhulla, R. Surendra Kumar, A. Jamal Abdul Nasser, S. Kavimani, S. Indhumathy
    Pharmaceutical Chemistry Journal, 2015
    Aseries of 1,4-dihydropyridine derivatives (1a – 1g) were prepared by multicomponent condensation reaction of ethylchloroacetate, 4-substituted benzaldehyde, and ammonium hydroxide as starting materials. A new series of dihydrazine carbothioamides (2a – 2g) were prepared by condensation of compounds 1a – 1g with thiosemicarbazide. The structures of synthesized compounds were confirmed by IR and 1H-NMR spectroscopy and elemental analysis. Compounds 1a – g and 2a – 2g were tested for anti-inflammatory activity on Swiss albino rats.
  • Synthesis and evaluation of antimicrobial activity of novel 3-{[1-pyridin-2-yl methylene]amino}-2-thioxoimidazolidin-4-one analogues
    Der Pharmacia Lettre, 2015
  • Inhibition effect of copper complex of 1-(8-hydroxy quinolin-2-yl-methyl) thiourea on the corrosion of mild steel in sodium chloride solution
    Abuthahir S.S. Syed, Nasser A. Jamal Abdul, Rajendran S.
    Open Materials Science Journal, 2014
    The Corrosion inhibition of an inhibitor namely Copper complex of 1-(8-hydroxy quinolin-2-yl-methyl) thiourea (Cu-HTF) which controls the corrosion of mild steel immersed in an aqueous solution containing 60 ppm Cl- has been investigated through electrochemical and mass loss method. The formulation consisting of 60 ppm of Cl- and 50 ppm of Cu-HTF offers good inhibition efficiency of 78 %. Polarization study shows that this formulation acts as a cathodic inhibitor.AC impedance spectra indicate that a protective film is formed on the mild steel surface. Fluorescence spectral analysis was used to detect the presence of iron-inhibitor complex. The surface morphology has been analyzed by FTIR, UV-Visible spectroscopy, Scanning Electron Microscope (SEM) and EDAX. Cu-HTF has the ability to prevent the growth of certain microorganisms such as E. coli, Streptococcus, Pseudomonas and Enterobacter.
  • Synthesis, Characterization and biological activity of certain pyrazole derivatives
    Journal of Chemical and Pharmaceutical Research, 2014
  • Synthesis of novel and diverse 1, 4-dihydropyridine analogues and their antimicrobial and anticancer activities
    R. Surendra K, Aseer Manilal, A. Jamal Abdu, Behailu Merdekios, Xiangxiong Chen, A. Idhayadhul
    Journal of Pharmacology and Toxicology, 2014
  • Synthesis of some new pyrrole and pyridine derivatives and their antimicrobial, anticancer activities
    Akbar Idhayadhul, Radhakrishnan Surend Kumar, Abdul Jamal Abdul Nasser, Aseer Manilal
    International Journal of Biological Chemistry, 2013
  • Synthesis and anticonvulsant activity of some new series of pyrrole derivatives
    A. Idhayadhulla, R. Surendra Kumar, A. Jamal Abdul Nasser, S. Kavimani, S. Indumathy
    Medicinal Chemistry Research, 2012
  • Synthesis and antimicrobial activity of some new pyrrole derivatives
    A Idhayadhulla, R Surendra Kumar, AJ Abdul Nasser, A Manilal
    Bulletin of the Chemical Society of Ethiopia, 2012
  • Synthesis of new series of pyrazole and imidazole derivatives and their antimicrobial activity
    Acta Chimica Slovenica, 2012
  • Synthesis of some pyrrole derivatives and their anticoagulant activity
    A. Idhayadhul, R. Surendra Kumar, A. Jamal Abdul Nasser, Aseer Manilal
    American Journal of Drug Discovery and Development, 2012
  • Synthesis, characterization and antimicrobial activity of new pyrrole derivatives
    Journal of the Mexican Chemical Society, 2011
  • Synthesis of some new pyrrole derivatives and their antimicrobial activity
    Der Pharma Chemica, 2011
  • Synthesis and antimicrobial activity of some new mannich base derivatives
    Journal of Chemical and Pharmaceutical Research, 2011
  • Synthesis and anticancer activity of some new series of 1, 4-dihydropyridine derivatives
    Indian Journal of Chemistry Section B Organic and Medicinal Chemistry, 2011
  • Adsorption and corrosion inhibition effect of N-(l-morpholinobenzyl)urea on mild steel in acidic medium
    M. Anwar Sathiq, A. Jamal Abdul Nasser, P. Mohamed Sirajudeen
    E Journal of Chemistry, 2011
  • Synthesis and antimicrobial activity of a new series of 1,4-dihydropyridine derivatives
    Surendra Kumar, A. Idhayadhulla, Abdul Nasser, J. Selvin
    Journal of the Serbian Chemical Society, 2011
  • Synthesis and anticonvulsant activity of a new series of 1,4-dihydropyridine derivatives
    AJamal Abdul Nasser, S Indumathy, RSurendra Kumar, A Idhayadhulla, S Kavimani
    Indian Journal of Pharmaceutical Sciences, 2010
  • Synthesis and characterization of new series of imidazolidin-2,4-dione derivatives and its antimicrobial activity
    Oriental Journal of Chemistry, 2010
  • Ethyl 3,5-dimethyl-4-[(4-phenyl-1,3-thiazol-2-yl)carbamoyl]-1H-pyrrole-2-carboxylate
    Akbar Idhayadhulla, Radhakrishnan Surendra Kumar, Abdul Jamal Abdul Nasser
    Molbank, 2010
  • Synthesis and biological activities of new series of Imidazolidin-2,4-dione Derivatives
    Asian Journal of Chemistry, 2010
  • Synthesis of some 2-Thioxo-imidazolidin-4-one derivatives and its antimicrobial activity
    A. Jamal Abdul Nasser, A. Idhayadhulla, R. Surendra Kumar, J. Selvin
    E Journal of Chemistry, 2010
  • Synthesis and antimicrobial activity of some 2-thioxo-imidazolidin-4-onesa
    Indian Journal of Heterocyclic Chemistry, 2009
  • Synthesis and biological activity of some 3, 1-substituted-2-thioxo- imidazolin-4-one, imidazoline-2.4-dione derivatives
    Indian Journal of Heterocyclic Chemistry, 2008
  • Aliphatic sulfides: Effective corrosion inhibitors for mild steel in sulfuric acid
    Bulletin of Electrochemistry, 2005