Synthesis, characterization and application aspects of barium titanate-based ceramic samples with graphene nanostructures introduced Georgieva, Yovkova, Panayotova Bulgarian Chemical Communications, 2025 The share of research work aimed at finding innovative approaches to the synthesis of new porous ceramic products to be applied as filters for purification of waste waters, as adsorbents, heat-insulation materials and other components with high thermal resistance, as well as biomedical and catalytic substrates has recently increased.The present paper reports for the preparation of barium titanate-based ceramic samples containing up to 2 mass % of graphene nanostructures (graphene nanoplatelets GnP), synthesized by the method of solid-state sintering.The methods of X-ray diffraction, FT-IR spectroscopy, scanning electron microscopy and light microscopy were used for the characterization of the initial blends and the titanate ceramic samples obtained from them.The results of the analyses showed that the introduced nanoadditive initiated the formation of fine-grain porous structure with grain sizes from 0.5 to 1 m.Some basic physicomechanical properties of the samples synthesized were determined, e.g., water absorption (, %), apparent density ( , , / 3 ) and apparent (open) porosity ( , %).The apparent density was close to the theoretical one -5.51/ 3 , the open porosity was 2.04 % and the minimal water absorption -0.37 %.Some aspects of application are proposed.
Synthesis of Ceramic Pigments from the System Al2O2-SiO2 by Utilization of Rice Husk Ash as Silica Source Adriana Georgieva, Mariela Minova, Irena Markovska, Fila Yovkova, Georgi Avdeev, et al. Wseas Transactions on Environment and Development, 2025 In this work, the synthesis of ceramic pigments from the system Al2O3 - SiO2 by utilization of rice husk ash (RHA) as a silica source is considered. For comparison, pigments from pure raw materials were also synthesized. All compositions were synthesized at 1450°С. The amount of chromophore in the compositions was 5%. Co, Cu, and Ni were used as chromophore elements, introduced respectively as Co2O3, CuO, or NiO. The pigments were studied by several methods - XRD, FT-IR, EPR, and spectral colour determination. By Xray diffraction, a qualitative and quantitative analysis of the synthesized pigments was made. The colour characteristics are determined spectrally by a tintometer of Lovibond Tintometer RT 100 Color. The pigments with cobalt chromophore have the best indicators, in which (b) = - 24.1 when using SiO2.nH2O and (b) = -27.4 when using RHA. The possibility of replacing pure silica with one obtained from oxidized rice husks was proven.
LOW-TEMPERATURE SYNTHESIS OF FINE-POROUS CORUNDUM BASED ON INCORPORATED GRAPHENE NANOSTRUCTURES Adriana Asenova Georgieva, Fila Slavova Yovkova, Margarita Anatolievna Georgieva, Irena Georgieva Markovska Journal of Chemical Technology and Metallurgy, 2024 In the present paper, the effect of the addition of graphene nanostructures and 3 mass % TiO2 on the microstructure and properties of sintered corundum ceramics were studied. Fine-porous corundum ceramics were obtained by the method of solid-phase sintering at relatively low temperatures of 1450oC, by adding graphene nanostructures in an amount of 2 % or 20 %. To lower the synthesis temperature, 3 mass % TiO2 was added to the initial ceramic blends. As a result of the solid solution formed between Al2O3 and TiO2, a well-sintered corundum ceramic is obtained at synthesis temperature lower than that of pure corundum - 1450oС. For the characterization of the initial blends and the ceramic samples, the methods of X-ray phase analysis, infrared spectroscopy, SEM, TEM EDS and visual microscopy were used. Besides, the basic physicochemical properties of the samples synthesized based on corundum were determined, e.g. water absorption (WA, %), apparent density (AD, %) and apparent (open) porosity (Pa, %).
OBTAINING OF GARNET CERAMIC MATERIALS BY UTILIZATION OF RICE HUSK ASH AS SILICA SOURCE Mariela Ganeva Minova, Adriana Asenova Georgieva, Tsvetan Ivanov Dimitrov, Fila Slavova Yovkova, Irena Georgieva Markovska Journal of Chemical Technology and Metallurgy, 2024 The current research aims at the obtaining of new type pigments from the garnet mineral group by utilizationof rice husk ash as silica source (RHA). At the beginning, the mixtures prepared from the starting raw materials areground in a ball mill and then subjected to high temperature treatment. Green pigments were synthesized at twotemperatures: 1000°C and 1100°C. Using the tintometer RT 100 Lovibond the colour characteristics were measuredspectrophotometrically. The rice husk ash was investigated using scanning electron microscopy. The conducted hot-stage microscopic studies show that the pigments remain thermally stable when heated. The highest fire resistance - upto temperatures of 1380°C - 1400°C show the uvarovite pigments with main phase 3CaO.Cr2O3.3SiO2 or by a generalformula Ca3Cr2[SiO4 ]3. They are suitable for inserting into ceramic glazes without danger of decomposition or reaction.Keywords: ceramic pigments, SEM, colour determination, Hot-stage microscopy.
USING THE ADVANTAGES OF NANOTECHNOLOGY FOR THE PRODUCTION OF COMPOSITE MATERIALS OF THE TYPE NGO/CERAMIC MATRIX Adriana Asenova Georgieva, Margarita Anatolievna Georgieva, Fila Slavova Yovkova, Krasi Zlatinova Panayotova, Irena Georgieva Markovska Journal of Chemical Technology and Metallurgy, 2024 Using the advantages of nanotechnology, composite ceramic materials of the type of graphene oxide nanocolloid/ceramic matrix were obtained in two stages. First, finely porous corundum (1500ºC) and barium titanate (1300ºC)ceramic samples containing 2 mass % graphene structures nanoplatelets were synthesized. The next stage of the study involved the preparation of graphene oxide in nanocolloid form (2 mg/ml, dispersion in H2O) which was impregnated in the solid porous ceramic samples to obtain composite materials. For the characterization of the ceramic samples, mainly infrared spectroscopy, X-ray phase analysis, scanning electron microscopy and light microscopy were used. The results obtained from the studies carried out showed that with the introduction of small amount of graphene nanoplatelets in the initial blends followed by solid state sintering, part of the added graphene is burned out which imparts significant porosity to the ceramics obtained. On the other hand, the addition of graphene initiates the formation of well-shaped fine-grain structure of the ceramic samples, and they had sufficient porosity.
OBTAINMENT OF BARIUM TITANATE CERAMIC SAMPLES AND DETERMINATION OF THEIR BASIC PHYSICOCHEMICAL PROPERTIES Oxidation Communications, 2023
Preparation and characterization of NGO/Al2O3 composite ceramic materials Georgieva, A. Georgieva, Panayotova, Yovkova, Markovska Bulgarian Chemical Communications, 2023 The present paper reports on the application of a two-stage technology for the preparation of composite ceramic material of the graphene/ceramic matrix type.Firstly, finely porous corundum ceramic material was obtained using the solid-state sintering method at comparatively low temperatures for corundum materials -1500C -by adding graphene at a concentration of 2 mass %, as well as 3 mass % TiO2.In the second stage of the experiment, graphene oxide was obtained in nano colloid form (2 mg/ml, dispersed in H2O) which was impregnated into the solid porous corundum samples synthesized to obtain a composite ceramic material of the NGO/Al2O3 type.In the characterization of the ceramic samples, mainly infrared spectroscopy, X-ray phase analysis, scanning and transmission electron microscopy, and light microscopy were used.Some important physicochemical properties of the synthesized samples were determined: water absorption (WA, %), apparent density (app, g/cm 3 ), and apparent (open) porosity (Papp, %).The samples were found to have homogeneous, fine-grain, and finely porous structure.
SYNTHESIS AND PROPERTIES OF CHROMIUM-BASED GARNET PIGMENTS Journal of Chemical Technology and Metallurgy, 2023
Experimental determination of mass transfer coefficient by rectification in a laboratory column equipped with three sieve trays Oxidation Communications, 2019
Obtaining nanostructured catalyst systems and study of catalytic efficiency Oxidation Communications, 2019
Determination of Interphase surface by rectification process in a laboratory column Oxidation Communications, 2018
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